Synthesis
ChemicalBook > CAS DataBase List > (1S)-(+)-Camphor-10-sulphonic acid

(1S)-(+)-Camphor-10-sulphonic acid

Synthesis
Product Name
(1S)-(+)-Camphor-10-sulphonic acid
CAS No.
3144-16-9
Chemical Name
(1S)-(+)-Camphor-10-sulphonic acid
Synonyms
CSA;CaMsylate;MOT;D-CAMPHOR-10-SULFONIC ACID;camphersulfosaeure;camphorsulfonicacid;D-CAMPHORSULPHONIC ACID;D-10-CAMPHORSULFONIC ACID;D(-)-CAMPHORSULFONIC ACID;MOT2
CBNumber
CB0395928
Molecular Formula
C10H16O4S
Formula Weight
232.3
MOL File
3144-16-9.mol
More
Less

(1S)-(+)-Camphor-10-sulphonic acid Property

Melting point:
196-200 °C (dec.)(lit.)
alpha 
22 º (589nm, c=20, H2O 25 ºC)
Boiling point:
344.46°C (rough estimate)
Density 
1.2981 (rough estimate)
refractive index 
21.5 ° (C=5, H2O)
storage temp. 
Store below +30°C.
solubility 
Exhibit moderate solubility in HCCl.
form 
Crystalline Powder
pka
1.17±0.50(Predicted)
color 
White to off-white
PH
0.3 (200g/l, H2O)
optical activity
[α]20/D +21.5±1°, c = 10% in H2O
Water Solubility 
SOLUBLE
Sensitive 
Hygroscopic
Merck 
14,1734
BRN 
2809675
Stability:
Stable. Protect from moisture. Incompatible with strong oxidizing agents, strong bases.
InChIKey
MIOPJNTWMNEORI-GMSGAONNSA-N
CAS DataBase Reference
3144-16-9(CAS DataBase Reference)
EPA Substance Registry System
Bicyclo[2.2.1]heptane-1-methanesulfonic acid, 7,7-dimethyl-2-oxo-, (1S,4R)- (3144-16-9)
More
Less

Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45-25-27
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
RTECS 
ED1550000
F 
3-10
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
29147090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H290May be corrosive to metals

H314Causes severe skin burns and eye damage

Precautionary statements

P234Keep only in original container.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
SRP5102
Product name
Mortalin (47-end), GST tagged human
Purity
recombinant, expressed in baculovirus infected Sf9 cells, ≥70% (SDS-PAGE), buffered aqueous glycerol solution
Packaging
50μG
Price
$360
Updated
2024/03/01
Sigma-Aldrich
Product number
21360
Product name
(+)-Camphor-10-sulfonic acid
Purity
purum, ≥98.0% (T)
Packaging
100g
Price
$55.3
Updated
2024/03/01
Sigma-Aldrich
Product number
8.22311
Product name
(1S)-(+)-Camphor-10-sulfonic acid
Purity
for resolution of racemates for synthesis
Packaging
100g
Price
$56.7
Updated
2024/03/01
Sigma-Aldrich
Product number
21360
Product name
(+)-Camphor-10-sulfonic acid
Purity
purum, ≥98.0% (T)
Packaging
500g
Price
$125
Updated
2024/03/01
Sigma-Aldrich
Product number
1087520
Product name
(+)-Camphor-10-sulfonic acid
Purity
United States Pharmacopeia (USP) Reference Standard
Packaging
100mg
Price
$472
Updated
2024/03/01
More
Less

(1S)-(+)-Camphor-10-sulphonic acid Chemical Properties,Usage,Production

Synthesis

(1S)-(+)-Camphor-10-sulphonic acid can be obtained from natural camphor by brominated sulfonation .

Chemical Properties

white to light beige powder

Uses

Used as a resolving agent, and as a catalyst for coupling dipeptides.

Uses

(1S)-(+)-Camphor-10-sulfonic acid is used as stabilizer. (+)-(1S)-camphor-10-sulfonic acid being a very effective resolving agent. . Chiral polyaniline(PANI) nanofibers were synthesized via facilely potentiostatic electropolymerization method without template in the presence of(1S)-(+)camphor-10-sulfonic acid(D-CSA) or(1R)-(-)camphor-10-sulfonic acid(L-CSA) as the dopant. Synthesis of QUATs derived from (1S)-(+)camphor-10-sulfonic acid.

Definition

ChEBI: (S)-camphorsulfonic acid is the S enantiomer of camphorsulfonic acid. It is a conjugate acid of a (S)-camphorsulfonate. It is an enantiomer of a (R)-camphorsulfonic acid.

Purification Methods

Crystallise the acid from ethyl acetate and dry it under vacuum (deliquescent). [Loudon J Chem Soc 823 1933, Komppa J Prakt Chem 162 19 1943, Beilstein 11 IV 642.] See above for RS-isomer.

(1S)-(+)-Camphor-10-sulphonic acid Preparation Products And Raw materials

Raw materials

Preparation Products

(S)-(+)-3-Quinuclidinol Levamisole hydrochloride Seratrodast
More
Less

(1S)-(+)-Camphor-10-sulphonic acid Suppliers

Americas 1 Australia 1 Austria 1 Belgium 5 Canada 4 China 455 Czech 1 Europe 4 France 2 Germany 9 India 47 Japan 9 South Korea 1 Spain 1 Switzerland 6 The Netherlands 2 Ukraine 1 United Kingdom 28 United States 75 Global 653
More
Less

View Lastest Price from (1S)-(+)-Camphor-10-sulphonic acid manufacturers

Hebei Yime New Material Technology Co., Ltd.
Product
(1S)-(+)-Camphor-10-sulphonic acid 3144-16-9
Price
US $100.00-95.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
EX:20T
Release date
2023-03-03
airuikechemical co., ltd.
Product
d-camphorsulfonic acid 3144-16-9
Price
US $0.00-0.00/Kg
Min. Order
1Kg
Purity
99.9%
Supply Ability
200tons
Release date
2024-03-29
Henan Fengda Chemical Co., Ltd
Product
(1S)-(+)-Camphor-10-sulphonic acid 3144-16-9
Price
US $10.00-0.10/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-03-22

3144-16-9, (1S)-(+)-Camphor-10-sulphonic acidRelated Search:

D-CAMPHOR Sodium 1-heptanesulfonate L-(+)-CAMPHORSULFONIC ACID Pefloxacin mesylate Ethyl 2-(Chlorosulfonyl)acetate Heptane Methanesulfonic acid Glycine Folic acid Citric acid 1-DODECANESULFONIC ACID SODIUM SALT Camphor p-Toluenesulfonic acid Gatifloxacin mesylate Taurine D(+)-10-Camphorsulfonyl chloride (S)-(+)-2-Chlorophenylglycine methyl ester Allethrin

  • D-CAMPHORSULFONIC ACID
  • D(-)-CAMPHORSULPHONIC ACID
  • D-CAMPHORSULPHONIC ACID
  • CSA
  • D-REYCHLER'S ACID
  • D-OXO-10-BORNANESULFONIC ACID
  • (+)-BETA-CAMPHORSULFONIC ACID
  • (+)-CAMPHOR-10-SULFONIC ACID
  • (+)-CAMPHOR-10-SULFONIC ACID (BETA)
  • (1S)-(+)-CAMPHOR-10-SULFONIC ACID
  • (1S)-CAMPHOR-10-SULFONIC ACID
  • (1S)-(+)-CAMPHOR-10-SULPHONIC ACID
  • (1S)-BETA-CAMPHOR-10-SULFONIC ACID
  • (1S,4R)-2-OXO-10-BORNANESULFONIC ACID
  • (1S)-(+)-10-CAMPHORSULFONIC ACID
  • 2-Oxobornane-10-sulphonic acid
  • (+)-10-CAMPHORSULFONIC ACID
  • (S)-(+)-CAMPHOR-10-SULFONIC ACID
  • (S)-7,7-DIMETHYL-2-OXOBICYCLO[2.2.1]HEPTANE-1-METHANESULFONIC ACID
  • 2-oxo-,(1s,4r)-(+)-10-bornanesulfonicaci
  • 7,7-dimethyl-2-oxo-,(1S)-Bicyclo[2.2.1]heptane-1-methanesulfonicacid
  • 7-dimethyl-2-oxo-(1s)-bicyclo(2.2.1)heptane-1-methanesulfonicaci
  • 7-dimethyl-2-oxo-(1s)-bicyclo[2.2.1]heptane-1-methanesulfonicaci
  • camphersulfosaeure
  • (+)-camphorsulfonicacid
  • (1s)-(+)-10-camphorsulfonic
  • camphorsulfonicacid
  • D-Camphor-10-surfonicacid
  • reychler’sacid
  • (+)-β-camphorsulfonic acid,(1S)-camphor-10-sulfonic acid
  • D-(+)-CAMPHOR-10-SULFONIC ACID 99%
  • (1S)-(+)-CAMPHOR-10-SULPHONIC ACIDCaMphorSulfonic Acid
  • D(+)-10-Camphorsulfonic acid,99%
  • (S)-(+)-Camphor-10-sulfonice Acid
  • Camphor-beta-d-sulfonic acid
  • (1S)-(+)-Camphor-10-Sulfonic Acid(Dry wt.), Water <2%
  • (1S)-(+)-10-Camphorsulfonic acid ,99%
  • (+)-Camphor-10-sulfonic acid,(+)-β-Camphorsulfonic acid, (1S)-(+)-Camphor-10-sulfonic acid
  • (1S)-(+)-10-Camphorsulfonic acid,(+)-Camphor-10-sulfonic acid (β), (1S)-Camphor-10-sulfonic acid
  • (1S)-(+)-10-Camphors
  • ((1S,4R)-7,7-diMethyl-2-oxobicyclo[2.2.1]heptan-1-yl)Methanesulfonic acid
  • GRP75
  • HSPA9
  • HSPA9B
  • MGC4500
  • Mortalin (47-end), GST tagged human
  • D(+)-10-CaMphorsulfonic acid, 99% 100GR
  • D(+) CeMphor Sulfonic Acid
  • (+)-CaMphor-10-sulfonic acid puruM, >=98.0% (T)
  • D- caMphorsulfonic acid (caMsylate)
  • D-Camphorsulfonic acid 2-Oxobornane-10-sulphonic acid
  • CaMsylate
  • [(1R,4S)-7,7-dimethyl-3-oxo-4-bicyclo[2.2.1]heptanyl]methanesulfonate
  • (1S)-(+)-Camphor-10-sulfonic acid(dry wt.), water
  • [(1R,4S)-7,7-dimethyl-3-oxo-4-bicyclo[2.2.1]heptanyl]methanesulfonic acid
  • MOT
  • MOT2
  • mot-2