D(+)-10-Camphorsulfonyl chloride
- Product Name
- D(+)-10-Camphorsulfonyl chloride
- CAS No.
- 21286-54-4
- Chemical Name
- D(+)-10-Camphorsulfonyl chloride
- Synonyms
- Camphor-10-suL;D(+)CAMPHOR SULFONYL CHLORIDE;D-CAMPHOR-10-SULFONYL CHLORIDE;S-(+)-caMphorsulfonyl chloride;(+)-10-CAMPHORSULFONYL CHLORIDE;D(+)-1-CaMphorsulfonyl chloride;(+)-10-Camphorsulfonyl Chloride;(+)-CAMPHOR-10-SULFONYL CHLORIDE;D(+)-10-CAMPHORSULFONYL CHLORIDE;D-CAMPHOR-10-SULFONYL CHLORIDE 96%
- CBNumber
- CB5775185
- Molecular Formula
- C10H15ClO3S
- Formula Weight
- 250.74
- MOL File
- 21286-54-4.mol
D(+)-10-Camphorsulfonyl chloride Property
- Melting point:
- 67-68 °C
- alpha
- 33 º (c=1, CHCl3 22 ºC)
- Boiling point:
- 349.4±15.0 °C(Predicted)
- Density
- 1.2078 (estimate)
- refractive index
- 32 ° (C=1, CHCl3)
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- solubility
- Chloroform (Slightly), Ethyl Acetate (Slightly)
- form
- Crystalline Powder
- color
- Off-white to beige
- optical activity
- [α]22/D +33°, c = 1 in chloroform
- Sensitive
- Moisture Sensitive
- BRN
- 3205974
- InChIKey
- BGABKEVTHIJBIW-UHFFFAOYSA-N
- CAS DataBase Reference
- 21286-54-4(CAS DataBase Reference)
- NIST Chemistry Reference
- (+)-Camphor-10-sulfonyl chloride(21286-54-4)
Safety
- Hazard Codes
- C
- Risk Statements
- 34
- Safety Statements
- 26-36/37/39-45
- RIDADR
- UN 3261 8/PG 2
- WGK Germany
- 3
- F
- 10-21
- HazardClass
- 8
- PackingGroup
- II
- HS Code
- 29147000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P363Wash contaminated clothing before reuse.
N-Bromosuccinimide Price
- Product number
- 219576
- Product name
- (1S)-(+)-10-Camphorsulfonyl chloride
- Purity
- 97%
- Packaging
- 5g
- Price
- $43.7
- Updated
- 2024/03/01
- Product number
- 219576
- Product name
- (1S)-(+)-10-Camphorsulfonyl chloride
- Purity
- 97%
- Packaging
- 25g
- Price
- $159
- Updated
- 2024/03/01
- Product number
- C0998
- Product name
- (+)-10-Camphorsulfonyl Chloride
- Purity
- >97.0%(GC)(T)
- Packaging
- 5g
- Price
- $26
- Updated
- 2024/03/01
- Product number
- C0998
- Product name
- (+)-10-Camphorsulfonyl Chloride
- Purity
- >97.0%(GC)(T)
- Packaging
- 25g
- Price
- $77
- Updated
- 2024/03/01
- Product number
- 219576
- Product name
- (1S)-(+)-10-Camphorsulfonyl chloride
- Purity
- 97%
- Packaging
- 100g
- Price
- $587
- Updated
- 2024/03/01
D(+)-10-Camphorsulfonyl chloride Chemical Properties,Usage,Production
Chemical Properties
white to light yellow crystal powde
Uses
A chiral derivative of Camphor.
Uses
As a useful synthetic intermediate, D(+)-10-Camphorsulfonyl chloride can be used for asymmetric hydroxylation
Purification Methods
If free from OH bands in the IR, then recrystallise it from Et2O or pet ether; otherwise treat it with SOCl2 at 50o for 30minutes, evaporate, dry the residue over KOH in a vacuum and recrystallise it. The (±)-acid chloride has m 85o [Bartlett & Knox Org Synth 45 14 1965]. Itis characterised as the amide (prisms from EtOH) m 132o, [ ] 17 (+) and (-) 1.5o (EtOH). On repeated recrystallisation from EtOH the anilide has m 120.5-121o, [] 25 +76o (c 1, CHCl3). [Read & Storey J Chem Soc 2761 1930, Sutherland & Shriner J Am Chem Soc 58 62 1936, Halterman et al. J Am Chem Soc 109 8105 1987, Bartlet & Knox Org Synth 45 55 1945, Beilstein 11 IV 650.]
D(+)-10-Camphorsulfonyl chloride Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from D(+)-10-Camphorsulfonyl chloride manufacturers
- Product
- D(+)-10-Camphorsulfonyl chloride 21286-54-4
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 50000kg/month
- Release date
- 2024-08-28
- Product
- D(+)-10-Camphorsulfonyl chloride 21286-54-4
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 50000kg/month
- Release date
- 2024-08-28
- Product
- D(+)-10-Camphorsulfonyl chloride 21286-54-4
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98.9%
- Supply Ability
- 100 tons
- Release date
- 2022-01-26