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D(+)-10-Camphorsulfonyl chloride

Product Name
D(+)-10-Camphorsulfonyl chloride
CAS No.
21286-54-4
Chemical Name
D(+)-10-Camphorsulfonyl chloride
Synonyms
Camphor-10-suL;D(+)CAMPHOR SULFONYL CHLORIDE;D-CAMPHOR-10-SULFONYL CHLORIDE;S-(+)-caMphorsulfonyl chloride;(+)-10-CAMPHORSULFONYL CHLORIDE;D(+)-1-CaMphorsulfonyl chloride;(+)-10-Camphorsulfonyl Chloride;(+)-CAMPHOR-10-SULFONYL CHLORIDE;D(+)-10-CAMPHORSULFONYL CHLORIDE;D-CAMPHOR-10-SULFONYL CHLORIDE 96%
CBNumber
CB5775185
Molecular Formula
C10H15ClO3S
Formula Weight
250.74
MOL File
21286-54-4.mol
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D(+)-10-Camphorsulfonyl chloride Property

Melting point:
67-68 °C
alpha 
33 º (c=1, CHCl3 22 ºC)
Boiling point:
349.4±15.0 °C(Predicted)
Density 
1.2078 (estimate)
refractive index 
32 ° (C=1, CHCl3)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
Chloroform (Slightly), Ethyl Acetate (Slightly)
form 
Crystalline Powder
color 
Off-white to beige
optical activity
[α]22/D +33°, c = 1 in chloroform
Sensitive 
Moisture Sensitive
BRN 
3205974
InChIKey
BGABKEVTHIJBIW-UHFFFAOYSA-N
CAS DataBase Reference
21286-54-4(CAS DataBase Reference)
NIST Chemistry Reference
(+)-Camphor-10-sulfonyl chloride(21286-54-4)
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Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
F 
10-21
HazardClass 
8
PackingGroup 
II
HS Code 
29147000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
219576
Product name
(1S)-(+)-10-Camphorsulfonyl chloride
Purity
97%
Packaging
5g
Price
$43.7
Updated
2024/03/01
Sigma-Aldrich
Product number
219576
Product name
(1S)-(+)-10-Camphorsulfonyl chloride
Purity
97%
Packaging
25g
Price
$159
Updated
2024/03/01
TCI Chemical
Product number
C0998
Product name
(+)-10-Camphorsulfonyl Chloride
Purity
>97.0%(GC)(T)
Packaging
5g
Price
$26
Updated
2024/03/01
TCI Chemical
Product number
C0998
Product name
(+)-10-Camphorsulfonyl Chloride
Purity
>97.0%(GC)(T)
Packaging
25g
Price
$77
Updated
2024/03/01
Sigma-Aldrich
Product number
219576
Product name
(1S)-(+)-10-Camphorsulfonyl chloride
Purity
97%
Packaging
100g
Price
$587
Updated
2024/03/01
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D(+)-10-Camphorsulfonyl chloride Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powde

Uses

A chiral derivative of Camphor.

Uses

As a useful synthetic intermediate, D(+)-10-Camphorsulfonyl chloride can be used for asymmetric hydroxylation

Purification Methods

If free from OH bands in the IR, then recrystallise it from Et2O or pet ether; otherwise treat it with SOCl2 at 50o for 30minutes, evaporate, dry the residue over KOH in a vacuum and recrystallise it. The (±)-acid chloride has m 85o [Bartlett & Knox Org Synth 45 14 1965]. Itis characterised as the amide (prisms from EtOH) m 132o, [ ] 17 (+) and (-) 1.5o (EtOH). On repeated recrystallisation from EtOH the anilide has m 120.5-121o, [] 25 +76o (c 1, CHCl3). [Read & Storey J Chem Soc 2761 1930, Sutherland & Shriner J Am Chem Soc 58 62 1936, Halterman et al. J Am Chem Soc 109 8105 1987, Bartlet & Knox Org Synth 45 55 1945, Beilstein 11 IV 650.]

D(+)-10-Camphorsulfonyl chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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D(+)-10-Camphorsulfonyl chloride Suppliers

Americas 1 Austria 1 Belgium 2 Canada 1 China 130 Europe 3 France 2 Germany 4 India 10 Japan 4 Switzerland 2 The Netherlands 1 United Kingdom 15 United States 35 Global 211
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View Lastest Price from D(+)-10-Camphorsulfonyl chloride manufacturers

Honest Joy Holdings Limited
Product
D(+)-10-Camphorsulfonyl chloride 21286-54-4
Price
US $0.00/KG
Min. Order
1KG
Purity
98.9%
Supply Ability
100 tons
Release date
2022-01-26
Career Henan Chemical Co
Product
D(+)-10-Camphorsulfonyl chloride 21286-54-4
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kg
Release date
2020-01-08

21286-54-4, D(+)-10-Camphorsulfonyl chlorideRelated Search:

4-Nitrobenzenesulfonyl chloride N-Acetylsulfanilyl chloride D-CAMPHOR Sodium chloride Benzenesulfonyl chloride Zinc chloride Potassium chloride Camphor Oxalyl chloride Choline chloride Ethanesulfonyl chloride Tosyl chloride Thionyl chloride Calcium chloride Ammonium chloride Sulfuryl chloride (1S)-(+)-Camphor-10-sulphonic acid (+)-GALLOCATECHIN

  • (+)-10-CAMPHORSULFONYL CHLORIDE
  • d-2-oxobornane-10-sulphonyl chloride
  • (1S)-(+)-10-CAMPHORSULFONYL CHLORIDE
  • (1S)-CAMPHOR-10-SULFONIC ACID CHLORIDE
  • (1S)-(+)-CAMPHOR-10-SULFONYL CHLORIDE
  • (1S)-(+)-CAMPHOR-10-SULPHONYL CHLORIDE
  • D-CAMPHOR-10-SULFONYL CHLORIDE
  • D(+)-10-CAMPHORSULFONYL CHLORIDE
  • (+) CAMPHOR-10-SULFONIC ACID CHLORIDE
  • (+)-CAMPHOR-10-SULFONYL CHLORIDE
  • (1S)-(+)-10-CAMPHORSULFONYL CHLORIDE, 97 %
  • D-CAMPHOR-10-SULFONYL CHLORIDE 96%
  • (S)-(+)-Camphor-10-SulfonylChloride
  • D(+)CAMPHOR SULFONYL CHLORIDE
  • [(1R,4S)-7,7-dimethyl-3-oxo-4-bicyclo[2.2.1]heptanyl]methanesulfonyl chloride
  • (7,7-dimethyl-3-oxo-4-bicyclo[2.2.1]heptanyl)methanesulfonyl chloride
  • (1S)-(+)-10-Camphorsulphonyl Chloride
  • (+)-Camphor-10-sulfonyl chloride, (1S)-Camphor-10-sulfonic acid chloride
  • Bicyclo[2.2.1]heptane-1-methanesulfonyl chloride, 7,7-dimethyl-2-oxo-
  • D-2-Oxobornane-10-sulfonyl chloride
  • D(+)-1-CaMphorsulfonyl chloride
  • (1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-methanesulfochloride
  • [1S,4R,(+)]-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-methanesulfonic acid chloride
  • D(+)-10-Camphorsulfonyl chloride,97%
  • (+)-10-CaMphorsulfonic Acid Chloride
  • (1S,4R)-7,7-DiMethyl-2-oxo-bicyclo[2.2.1]heptane-1-Methanesulfonyl Chloride
  • S-(+)-caMphorsulfonyl chloride
  • ((1S,4R)-7,7-DiMethyl-2-oxobicyclo[2.2.1]heptan-1-yl)Methanesulfonyl chloride
  • Bicyclo[2.2.1]heptane-1-methanesulfonyl chloride, 7,7-dimethyl-2-oxo-, (1S)-
  • Dextro-10-camphorsulfonyl chloride
  • D(+)-10-CaMphorsulfonyl chloride, 97% 5GR
  • (1S)-(+)-10-Camphorsulfonyl chloride 97%
  • Camphor-10-suL
  • Bicyclo[2.2.1]heptane-1-methanesulfonyl chloride, 7,7-dimethyl-2-oxo-, (1S,4R)-
  • (+)-10-Camphorsulfonyl Chloride
  • 21286-54-4
  • 2186-54-4
  • C10H15ClO3S
  • UV-VIS
  • Chiral Resolving Reagents
  • Chiral Resolution Reagents
  • Optical Resolution
  • Asymmetric Synthesis
  • for Resolution of Alcohols & Thiols
  • Bicyclic Monoterpenes
  • Terpenes
  • for Resolution of Bases
  • chiral
  • Chiral Reagents
  • Bicyclic Monoterpenes
  • Biochemistry
  • for Resolution of Alcohols & Thiols
  • for Resolution of Bases
  • Optical Resolution
  • Synthetic Organic Chemistry
  • Terpenes
  • Intermediates & Fine Chemicals
  • Pharmaceuticals