2-Amino-5-chloro-3-methylbenzoic acid
- Product Name
- 2-Amino-5-chloro-3-methylbenzoic acid
- CAS No.
- 20776-67-4
- Chemical Name
- 2-Amino-5-chloro-3-methylbenzoic acid
- Synonyms
- 2-aMino-3-Methyl-5-chlorobenzoic acid;2-Amino-5-chloro-m-toluic Acid;Chlorantraniliprole intermediate;2-Amino-5-chloro-3-methylbenzene;5-Chloro-3-methylanthranilic Acid;3-METHYL-5-CHLORO-ANTHRANILIC ACID;2-Amino-5-chloro-3-methylbenzoicaci;-Amino-5-chloro-3-methylbenzoic acid;2-AMINO-5-CHLORO-3-METHYLBENZOIC ACID;2-Amino-5-chloro-3-methylbenzoicAcid>
- CBNumber
- CB0446000
- Molecular Formula
- C8H8ClNO2
- Formula Weight
- 185.61
- MOL File
- 20776-67-4.mol
2-Amino-5-chloro-3-methylbenzoic acid Property
- Melting point:
- 239-243 °C (lit.)
- Boiling point:
- 348.4±42.0 °C(Predicted)
- Density
- 1.401±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- solubility
- very slightly in Methanol
- form
- powder to crystal
- pka
- 4?+-.0.10(Predicted)
- color
- White to Light yellow to Light red
- InChI
- InChI=1S/C8H8ClNO2/c1-4-2-5(9)3-6(7(4)10)8(11)12/h2-3H,10H2,1H3,(H,11,12)
- InChIKey
- KOPXCQUAFDWYOE-UHFFFAOYSA-N
- SMILES
- C(O)(=O)C1=CC(Cl)=CC(C)=C1N
- CAS DataBase Reference
- 20776-67-4(CAS DataBase Reference)
N-Bromosuccinimide Price
- Product number
- 643513
- Product name
- 2-Amino-5-chloro-3-methylbenzoic acid
- Purity
- 97%
- Packaging
- 25g
- Price
- $120.35
- Updated
- 2025/07/31
- Product number
- 643513
- Product name
- 2-Amino-5-chloro-3-methylbenzoic acid
- Purity
- 97%
- Packaging
- 5g
- Price
- $36.8
- Updated
- 2023/06/20
- Product number
- A2399
- Product name
- 2-Amino-5-chloro-3-methylbenzoic Acid
- Purity
- >98.0%(HPLC)(T)
- Packaging
- 5g
- Price
- $25
- Updated
- 2025/07/31
- Product number
- A2399
- Product name
- 2-Amino-5-chloro-3-methylbenzoic Acid
- Purity
- >98.0%(HPLC)(T)
- Packaging
- 25g
- Price
- $97
- Updated
- 2025/07/31
- Product number
- A617373
- Product name
- 2-Amino-5-chloro-3-methylbenzoic Acid
- Packaging
- 10g
- Price
- $75
- Updated
- 2021/12/16
2-Amino-5-chloro-3-methylbenzoic acid Chemical Properties,Usage,Production
Chemical Properties
Light yellow crystalline powder
Uses
2-Amino-5-chloro-3-methylbenzoic Acid is a useful research chemical for the preparation of benzoyl urea containing anthranillic acid groups with insecticidal activity.
reaction suitability
reaction type: solution phase peptide synthesis
Synthesis
4389-45-1
20776-67-4
General procedure for the synthesis of 2-amino-5-chloro-3-methylbenzoic acid from 2-amino-3-methylbenzoic acid: In a 100 mL round-bottomed flask, 20 mL of 2-amino-3-methylbenzoic acid, 50 mL of N,N-dimethylformamide (DMF), and 30 mmol of N-chlorosuccinimide (or N-bromosuccinimide) were added. The mixture was stirred under reflux conditions for 3 hours. After the reaction was completed, the reaction solution was poured into ice water. The pH was adjusted to 6 with dilute hydrochloric acid and then filtered. The resulting solid was washed with a small amount of ethanol to give a gray solid 2-amino-5-halogeno-3-methylbenzoic acid (halogen was chlorine or bromine). The yield was 83%.
References
[1] Journal of Agricultural and Food Chemistry, 2012, vol. 60, # 44, p. 10942 - 10951
[2] Australian Journal of Chemistry, 2014, vol. 67, # 10, p. 1491 - 1503
[3] Patent: CN103450154, 2016, B. Location in patent: Paragraph 0063-0065
[4] Patent: CN104031026, 2017, B. Location in patent: Paragraph 0051; 0052; 0053; 0054
[5] Journal of Chemical Research, 2008, # 9, p. 530 - 533
2-Amino-5-chloro-3-methylbenzoic acid Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2-Amino-5-chloro-3-methylbenzoic acid manufacturers
- Product
- 2-amino-5-chloro-3-methylbenzoic acid 20776-67-4
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- Customise
- Release date
- 2025-08-22
- Product
- 2-Amino-5-chloro-3-methylbenzoic acid 20776-67-4
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1000kg
- Release date
- 2025-06-21
- Product
- 2-Amino-5-chloro-3-methylbenzoic acid 20776-67-4
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98%min
- Supply Ability
- 30tons/month
- Release date
- 2025-05-07