BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL

Product Name: BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL
CAS No.: 13007-90-4
Chemical Name: BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL
Synonyms: phosphine)dicarbonyL;BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL;BIS(TRIPHENYLPHOSPHINE)NICKEL &;DICARBONYL-BIS(TRIPHENYLPHOSPHINE)NICKEL;BIS(TRIPHENYLPHOSPHINE)NICKEL DICARBONYL;NICKEL-BIS(TRIPHENYLPHOSPHINE) DICARBONYL;Bis-(triphenylphosphino)-nickel dicarbonyl;dicarbonylbis(triphenylphosphine)nickel(0);Bis(triphenylphosphine)nickel(0)dicarbonyl;Bis(triphenylphosphine)nickeldicarbonyl,98%
CBNumber: CB0687047
Molecular Formula: C38H30NiO2P2
Formula Weight: 639.28
MOL File: 13007-90-4.mol

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BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL Property

Melting point:: 206-209 °C (lit.)
storage temp.: 2-8°C
solubility: Soluble in HMPA, THF, diglyme, triglyme, benzene, acetonitrile, ethanol, and cyclohexane.
form: crystal
color: light yellow
Sensitive: air sensitive
Merck: 14,1304
Exposure limits: NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
CAS DataBase Reference: 13007-90-4

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Safety

Hazard Codes: T
Risk Statements: 45-42/43
Safety Statements: 53-22-36/37-45
RIDADR: 3281
WGK Germany: 3
HazardClass: 6.1
PackingGroup: II

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H317May cause an allergic skin reaction

H350May cause cancer

Precautionary statements

P201Obtain special instructions before use.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 213934
Product name: Bis(triphenylphosphine)dicarbonylnickel
Packaging: 10g
Price: $52
Updated: 2024/03/01

Alfa Aesar

Product number: 039242
Product name: Bis(triphenylphosphine)dicarbonylnickel, 98%
Packaging: 2.5g
Price: $27.65
Updated: 2024/03/01

Alfa Aesar

Product number: 039242
Product name: Bis(triphenylphosphine)dicarbonylnickel, 98%
Packaging: 10g
Price: $91.65
Updated: 2024/03/01

Strem Chemicals

Product number: 28-0100
Product name: Bis(triphenylphosphine)nickel dicarbonyl, 98%
Packaging: 5g
Price: $43
Updated: 2024/03/01

Strem Chemicals

Product number: 28-0100
Product name: Bis(triphenylphosphine)nickel dicarbonyl, 98%
Packaging: 25g
Price: $165
Updated: 2024/03/01

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BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL Chemical Properties,Usage,Production

Chemical Properties

light yellow crystals or crystalline powder

Uses

Catalyst for:

Cyclotrimerization reactions
Cyclooligomerization reactions

Uses

Catalyst in polymerization of acetylene to benzene and styrene, trimerization of ethynyl Compounds, cyclization of butadiene.

Synthesis

The preparative method of Bis(triphenylphosphine)dicarbonylnickel: by treating Tetracarbonylnickel with 2 equiv of Triphenylphosphine or by dissolving Dichlorobis(triphenylphosphine)nickel(II) in ethanol and treating it with CO in the presence of MeSNa. Purification: recrystallize from benzene.

Precautions

Catalytic activity decreases with storage. It is likely to be toxic, similar to nickel carbonyl, but its low volatility makes it easy to avoid ingestion. Use in a fume hood.

BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL Preparation Products And Raw materials

Raw materials

Preparation Products

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BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL Suppliers

China 34 Germany 2 Japan 1 Switzerland 1 United Kingdom 1 United States 6 Global 45

Aladdin Scientific

Tel: +1-+1(833)-552-7181
Email: sales@aladdinsci.com
Country: United States
ProdList: 57505
Advantage: 58

Strem Chemicals, Inc.

Tel: --
Fax: --
Email: info@strem.com
Country: United States
ProdList: 4910
Advantage: 86

Riedel-de Haen AG

Tel: --
Fax: --
Country: United States
ProdList: 6773
Advantage: 87

Alfa Aesar

Tel: --
Fax: --
Email: tech@alfa.com
Country: United States
ProdList: 6814
Advantage: 81

HONEST JOY HOLDINGS LIMITED

Tel: --
Fax: --
Email: sales@honestjoy.cn
Country: United States
ProdList: 6675
Advantage: 54

Pfaltz & Bauer, Inc.

Tel: --
Fax: --
Email: sales@pfaltzandbauer.com
Country: United States
ProdList: 6828
Advantage: 72

13007-90-4, BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKELRelated Search:

BIS(TRIPHENYLPHOSPHINE)NICKEL(II) BROMIDE Bis-(triphenylphosphino)-cuprous borohydride [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 1,2-Dimethoxyethane Bis(tri-tert-butylphosphine)palladium(0) Bis(tricyclohexylphosphine)nickel(II) chloride, 99% Bis(triphenylphosphine)palladium(II) chloride Bis(triphenylphosphine)nickel(II)chloride Triphenylphosphine CARBON MONOXIDE Diphenylphosphine (FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE Nickel sulfate hexahydrate BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL

NICKEL-BIS(TRIPHENYLPHOSPHINE) DICARBONYL

BIS(TRIPHENYLPHOSPHINE)NICKEL DICARBONYL

BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL

DICARBONYL-BIS(TRIPHENYLPHOSPHINE)NICKEL

BIS(TRIPHENYLPHOSPHINE)NICKEL &

Bis(triphenylphosphine)nickel(0)dicarbonyl

Bis(triphenylphosphine)nickeldicarbonyl,98%

Nickel, dicarbonylbis(triphenylphosphine)-, (T-4)-

dicarbonylbis(triphenylphosphine)nickel(0)

Bis-(triphenylphosphino)-nickel dicarbonyl

Dicarbonylbis(triphenylphosphine)nickel(0), Nickel(0)bis(triphenylphosphine) dicarbonyl

Bis(triphenylphosphine)nickel(0)dicarbonyl, Dicarbonylbis(triphenylphosphine)nickel(0), Nickel(0)bis(triphenylphosphine) dicarbonyl

Bis(triphenylphosphine)dicarbonylnickel,98%

Nickel(0)bis(triphenylphosphine) dicarbonyl

phosphine)dicarbonyL

BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL ISO 9001：2015 REACH

13007-90-4

C6H53P2NiCO2

C38H30NiO2P2

Catalysis and Inorganic Chemistry

metal carbonyl complexes