Ethyl carbazate

Product Name: Ethyl carbazate
CAS No.: 4114-31-2
Chemical Name: Ethyl carbazate
Synonyms: ETHYL HYDRAZINECARBOXYLATE;HYDRAZINOCARBOXYLIC ACID ETHYL ESTER;AKOS 90785;ETHYL CARBAZATE;ethylecarbazate;ethylcarbazinate;Ethyl carbazinate;Ethyl Carbazatecas;Carbethoxyhydrazine;Ethyl carbazate 97%
CBNumber: CB0697565
Molecular Formula: C3H8N2O2
Formula Weight: 104.11
MOL File: 4114-31-2.mol

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Ethyl carbazate Property

Melting point:: 44-47 °C (lit.)
Boiling point:: 108-110 °C/22 mmHg (lit.)
Density: 1.2719 (rough estimate)
refractive index: 1.4715 (estimate)
Flash point:: 187 °F
storage temp.: Keep in dark place,Inert atmosphere,Store in freezer, under -20°C
pka: 10.72±0.20(Predicted)
form: Powder
color: White to cream
Water Solubility: Very soluble in water.
Sensitive: Moisture Sensitive
BRN: 878265
InChIKey: VYSYZMNJHYOXGN-UHFFFAOYSA-N
CAS DataBase Reference: 4114-31-2(CAS DataBase Reference)
NIST Chemistry Reference: Hydrazinecarboxylic acid, ethyl ester(4114-31-2)
EPA Substance Registry System: Hydrazinecarboxylic acid, ethyl ester (4114-31-2)

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Safety

Hazard Codes: Xi,T
Risk Statements: 36/37/38-25
Safety Statements: 26-36-45
RIDADR: 2811
WGK Germany: 3
RTECS: FE2545000
TSCA: Yes
HazardClass: 6.1
PackingGroup: III
HS Code: 29280090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: E16503
Product name: Ethyl carbazate
Purity: 97%
Packaging: 25g
Price: $76.1
Updated: 2024/03/01

TCI Chemical

Product number: C1097
Product name: Ethyl Carbazate
Purity: >99.0%(T)
Packaging: 25g
Price: $79
Updated: 2024/03/01

TCI Chemical

Product number: C1097
Product name: Ethyl Carbazate
Purity: >99.0%(T)
Packaging: 500g
Price: $944
Updated: 2024/03/01

Alfa Aesar

Product number: A13860
Product name: Ethyl carbazate, 97%
Packaging: 50g
Price: $48.65
Updated: 2024/03/01

Alfa Aesar

Product number: A13860
Product name: Ethyl carbazate, 97%
Packaging: 250g
Price: $195
Updated: 2024/03/01

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Ethyl carbazate Chemical Properties,Usage,Production

Chemical Properties

Off-white crystals.

Uses

Synthetic intermediate.

Uses

Prepare 4-phenylurazole from ethyl carbazate and then oxidize the urazole with gaseous dinitrogen tetroxide to yield 4-phenyl-1,2,4-tri- azoline-3,5-dione la. Modification of the ethyl carbazate procedure in which analytically pure monoalkylhydrazine hydrochlorides were isolated in greater than 90% yield, starting from a ketone or aldehyde. Treatment of primary amines is with chloroamine or hydroxylamine-0-sulfonic acid and the condensation of a carbonyl compound with ethyl carbazate. The FeCl 3 -catalyzed reaction of ethyl carbazate (2 b) proceeded readily to give β-hydroxyester 3 b in better yield. A new one-pot neat synthesis of some 5-aryl-2,4-dihydro-3H-1,2,4-triazol-3-ones through cyclocondensation of ethyl carbazate with aryl nitriles catalyzed by DMAP as an efficient and basic nucleophilic catalyst is described.

Hazard

Irritant.

Purification Methods

Fractionate the carbazate using a Vigreux column (p 11) until the distillate crystallises [Allen & Bell Org Synth Coll Vol III 404 1955, Beilstein 3 IV 174].

Ethyl carbazate Preparation Products And Raw materials

Raw materials

Methyl carbazate HYDRAZINE Diethyl carbonate

Preparation Products

4-[4-(BROMOMETHYL)PHENYL]-1,2,3-THIADIAZOLE 4-METHYL-1,2,3-THIADIAZOLE-5-CARBOXAMIDE 1,2,3-THIADIAZOLE-4-CARBOXYLIC ACID 4-(1,2,3-THIADIAZOL-4-YL)PHENOL Cadralazine 4-(1,2,3-THIADIAZOL-4-YL)BENZOIC ACID 4-(4-METHOXYPHENYL)-1,2,3-THIADIAZOLE 4-(1,2,3-THIADIAZOL-4-YL)ANILINE 4-(4-NITROPHENYL)-1,2,3-THIADIAZOLE 4-(1,2,3-THIADIAZOL-4-YL)BENZALDEHYDE 4-PHENYL-1,2,3-THIADIAZOL-5-AMINE 4-(4-METHYLPHENYL)-1,2,3-THIADIAZOLE Thidiazuron 1,2,3-Thiadiazole-4-carbonyl chloride (6CI,7CI,8CI,9CI) 4-(4-CHLOROPHENYL)-1,2,3-THIADIAZOLE 4-(1,2,3-THIADIAZOL-4-YL)BENZOYL CHLORIDE ETHYL 1,2,3-THIADIAZOLE-4-CARBOXYLATE 4-(1,2,3-THIADIAZOL-4-YL)BENZONITRILE 4-[4-(TRIFLUOROMETHYL)PHENYL]-1,2,3-THIADIAZOL-5-AMINE 4-(4-METHOXYPHENYL)-1,2,3-THIADIAZOL-5-AMINE 4-(1,2,3-THIADIAZOL-4-YL)BENZYLAMINE HYDROCHLORIDE ETHYL 4-METHYL-1,2,3-THIADIAZOLE-5-CARBOXYLATE 4-ISOPROPYL-1,2,3-THIADIAZOLE-5-CARBOXYLIC ACID 4-(4-CHLOROPHENYL)-1,2,3-THIADIAZOL-5-AMINE 4-METHYL-1,2,3-THIADIAZOLE-5-CARBONYL CHLORIDE ETHYL 4-ISOPROPYL-1,2,3-THIADIAZOLE-5-CARBOXYLATE 4-(4-BROMOPHENYL)-1,2,3-THIADIAZOLE 5-CYANO-4-METHYL-1,2,3-THIADIAZOLE (1,2,3-THIADIAZOL-4-YL)METHANOL 4-Methyl-1,2,3-thiadiazole-5-carboxylic acid

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Ethyl carbazate Suppliers

Americas 1 Belgium 1 China 222 Europe 3 Germany 8 India 15 Italy 1 Japan 3 Slovakia 1 South Korea 1 Switzerland 2 United Kingdom 12 United States 35 Global 305

Alchem Pharmtech,Inc.

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View Lastest Price from Ethyl carbazate manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Ethyl carbazate 4114-31-2
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-01-11

Hebei Chuanghai Biotechnology Co,.LTD

Product: Ethyl Carbazatecas 4114-31-2
Price: US $5.70/KG
Min. Order: 10KG
Purity: 99%
Supply Ability: 10000kg
Release date: 2024-08-21

Hebei Weibang Biotechnology Co., Ltd

Product: Ethyl carbazate 4114-31-2
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2021-08-03

4114-31-2, Ethyl carbazateRelated Search:

Urethane 1,5-Diphenylcarbazide Adipic dihydrazide Tebufenozide DIPHENYLCARBAZONE Carbohydrazide Benzocaine Ethyl cyanoacetate ISOXADIFEN-ETHYL Ethyl oleate HYDRAZINE Ethyl formate Ethanol Ethyl acetate Ethyl acrylate Ethyl pyruvate METHOXYFENOZIDE Ethylparaben

(Ethoxycarbonyl)hydrazide

(Monocarbethoxy)hydrazine

1-(Carbethoxy)hydrazine

1-(Ethoxycarbonyl)hydrazine

AKOS 90785

Ethoxycarbonylhydrazine~Ethyl hydrazinocarboxylate

ETHOXY CARBONYLHYDRAZINE

ETHOXY FORMHYDRAZINE

ETHYL CARBAZATE

ETHYL HYDRAZINECARBOXYLATE

ETHYL HYDRAZINE-1-CARBOXYLATE

HYDRAZINOCARBOXYLIC ACID ETHYL ESTER

HYDRAZINOFORMIC ACID ETHYL ESTER

CARBAZIC ACID ETHYL ESTER

CARBOETHOXY HYDRAZINE

Ethyl N-aminocarbamate

Ethyl carbazate ,97%

Carbazinic acid ethyl

Hydrazinecarboxylic acid ethyl

N-Aminocarbamic acid ethyl ester

ETHOXY FORMYL HYDRAZINE

Ethoxycarbonylhydrazine Carbazic Acid Ethyl Ester

1-carbethoxyhydrazine

Carbethoxyhydrazine

ethoxycarbonylhydrazide

Ethyl carbazinate

ethylcarbazinate

ethylhydrazinocarboxylate

hydrazinecarboxylicacid,ethylester

monocarbethoxyhydrazine

N-(Carbethoxy)hydrazine

N-(Ethoxycarbonyl)hydrazine

Ethyl carbazate 97%

Hydrazine ethyl forMate

ethylecarbazate

Ethyl Carbazate &gt

Ethyl Carbazatecas

4114-31-2 Hydrazinecarboxylicacid, ethyl ester

Ethyl hydrazine formate

4114-31-2

H2NNHCO2C2H5

ACETATE

Building Blocks

Carbonyl Compounds

Nitrogen Compounds

Protected Amines

Organic Building Blocks

Hydrazides

Pharmaceutical Intermediates

Miscellaneous

Building Blocks

Chemical Synthesis

Nitrogen Compounds

Organic Building Blocks

Protected Amines

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