ChemicalBook > CAS DataBase List > 1-(2'-BROMOPHENYL)ETHYLAMINE

1-(2'-BROMOPHENYL)ETHYLAMINE

Product Name
1-(2'-BROMOPHENYL)ETHYLAMINE
CAS No.
113899-55-1
Chemical Name
1-(2'-BROMOPHENYL)ETHYLAMINE
Synonyms
1-(2-BROMOPHENYL)ETHANAMINE;1-(2'-BROMOPHENYL)ETHYLAMINE;2-bromo-α-methylBenzenemethanamine;Benzenemethanamine, 2-bromo-α-methyl-;2-Bromo-alpha-methylbenzenemethanamine;Benzenemethanamine, 2-bromo-.alpha.-methyl-
CBNumber
CB0699897
Molecular Formula
C8H10BrN
Formula Weight
200.08
MOL File
113899-55-1.mol
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1-(2'-BROMOPHENYL)ETHYLAMINE Property

Boiling point:
248.5±15.0 °C(Predicted)
Density 
1.400±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
pka
8.50±0.10(Predicted)
Appearance
Colorless to yellow Liquid
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Matrix Scientific
Product number
132428
Product name
1-(2-Bromophenyl)ethanamine
Packaging
250.00mg
Price
$33
Updated
2026/05/18
Matrix Scientific
Product number
132428
Product name
1-(2-Bromophenyl)ethanamine
Packaging
1.00g
Price
$76
Updated
2026/05/18
Matrix Scientific
Product number
132428
Product name
1-(2-Bromophenyl)ethanamine
Packaging
5.00g
Price
$216
Updated
2026/05/18
ACHEMBLOCK
Product number
O34378
Product name
1-(2-Bromophenyl)ethanamine
Purity
95%
Packaging
5G
Price
$240
Updated
2026/05/27
ACHEMBLOCK
Product number
O34378
Product name
1-(2-Bromophenyl)ethanamine
Purity
95%
Packaging
25G
Price
$960
Updated
2026/05/27
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1-(2'-BROMOPHENYL)ETHYLAMINE Chemical Properties,Usage,Production

Synthesis

27760-49-2

113899-55-1

Under nitrogen protection, sodium borohydride (3.1 g, 86 mmol) and titanium tetrachloride (1 M in toluene, 43 mL, 43 mmol) were dissolved in 40 mL of anhydrous 1,2-dimethoxyethane and the solution was cooled to 0 °C. Subsequently, 1-(2-bromophenyl)ethanone oxime (4.6 g, 21.5 mmol) was slowly added dropwise to the above cooled solution. After the dropwise addition was completed, the reaction mixture was stirred at room temperature overnight. Upon completion of the reaction, the reaction was quenched with 200 mL of water and the mixture was adjusted to alkaline with ammonium hydroxide. The crude product was extracted with a solvent mixture of toluene and ethyl acetate to separate the organic and aqueous layers. The organic layer was dried with anhydrous sodium sulfate and subsequently concentrated under reduced pressure to give the crude product 1-(2-bromophenyl)ethylamine (4.0 g, 100% yield). Mass spectrum (electrospray ionization) m/z 200/202 [M + 1]+.

References

[1] Patent: WO2008/144223, 2008, A2. Location in patent: Page/Page column 11

1-(2'-BROMOPHENYL)ETHYLAMINE Preparation Products And Raw materials

Raw materials

Preparation Products

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1-(2'-BROMOPHENYL)ETHYLAMINE Suppliers

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