Dess-Martin periodinane

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Dess-Martin periodinane

Product Name: Dess-Martin periodinane
CAS No.: 87413-09-0
Chemical Name: Dess-Martin periodinane
Synonyms: DESS-MARTIN;Dess-Martin periodane;DESS-MARTIN REAGENT;PERIODINANE;DESS-MARTINE;1,1,1-TRIACETOXY-1,1-DIHYDRO-1,2-BENZIODOXOL-3(1H)-ONE;Dess-Martin periodinane,D M P, TAPI;3-oxo-1l5-benzo[d][1,2]iodaoxole-1,1,1(3H)-triyl triacetate;1,1,1-TRIS(ACETYLOXY)-1,1-DIHYDRO-1,2-BENZIODOXOL-3-(1H)-ONE;Martin's reagent
CBNumber: CB0776475
Molecular Formula: C13H13IO8
Formula Weight: 424.14
MOL File: 87413-09-0.mol

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Dess-Martin periodinane Property

Melting point:: 130-133 °C (lit.)
Boiling point:: 40 °C
Density: 1.369 g/mL at 25 °C
Flash point:: >221 °F
storage temp.: -20°C
solubility: Soluble in chloroform, acetone, acetonitrile and methylene chloride. Slightly soluble in ether and hexane.
form: Liquid
color: Colorless to light yellow
Sensitive: Light Sensitive
Merck: 14,2933
BRN: 4548207
Stability:: Light Sensitive
InChI: InChI=1S/C13H13IO8/c1-8(15)19-14(20-9(2)16,21-10(3)17)12-7-5-4-6-11(12)13(18)22-14/h4-7H,1-3H3
InChIKey: NKLCNNUWBJBICK-UHFFFAOYSA-N
SMILES: I1(OC(=O)C)(OC(=O)C)(OC(=O)C)OC(=O)C2C=CC=CC1=2
CAS DataBase Reference: 87413-09-0(CAS DataBase Reference)

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Safety

Hazard Codes: Xn,O,Xi
Risk Statements: 22-36/37/38-40-8-20/21/22-44
Safety Statements: 26-36-36/37-24/25-23-17-45-36/37/39
RIDADR: UN 1593 6.1/PG 3
WGK Germany: 3
Hazard Note: Harmful/Light sensitive
TSCA: No
HazardClass: 5.1
PackingGroup: Ⅲ
HS Code: 29349990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H272May intensify fire; oxidizer

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P220Keep/Store away from clothing/…/combustible materials.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 274623
Product name: Dess-Martin periodinane
Purity: 97%
Packaging: 5g
Price: $136
Updated: 2024/03/01

Sigma-Aldrich

Product number: 274623
Product name: Dess-Martin periodinane
Purity: 97%
Packaging: 25g
Price: $648
Updated: 2024/03/01

TCI Chemical

Product number: D2045
Product name: Dess-Martin Periodinane
Purity: >95.0%(T)
Packaging: 1g
Price: $35
Updated: 2024/03/01

TCI Chemical

Product number: D2045
Product name: Dess-Martin Periodinane
Purity: >95.0%(T)
Packaging: 5g
Price: $106
Updated: 2024/03/01

Alfa Aesar

Product number: L15779
Product name: Dess-Martin periodinane
Packaging: 1g
Price: $39.3
Updated: 2024/03/01

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Dess-Martin periodinane Chemical Properties,Usage,Production

Description

Dess-Martin periodinane (DMP) is a hypervalent iodine compound widely used as a mild reagent for the oxidation of primary/secondary alcohols to aldehydes/ketones; oxidation of amides into imides; the dehydrogenation of amines to nitriles, and disulfides to sulfones. It is also used to selectively oxidize alkenes to epoxides. This is a useful reaction for generating three-membered cyclic ethers. Additionally, DMP is used to oxidatively cleave 1,2-diols to form aldehydes or ketones and in the synthesis of lactones.

Chemical Properties

White Crystalline powder

Uses

Dess-Martin Periodinaneis a very usefulreagent used in the oxidation of primary alcohols to aldehydes and secondary alcohols to ketones.

Uses

Dess Martin periodinane is used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. It is also used as an oxidant for complexes with multifunctional alcohols. It is actively involved in the oxidation of N-protected-amino alcohols without epimerization and allylic alcohols.

Uses

Oxidizing reagent.

Advantages

Benefits of using Dess-Martin periodinane (DMP) as an oxidizing reagent:
milder reaction conditions (room temperature, neutral pH)
shorter reaction times and higher yields
high chemoselectivity
tolerance of sensitive functional groups, and a long shelf life
simplified workups

Dess-Martin periodinane Preparation Products And Raw materials

Raw materials

2-Iodobenzoic acid p-Toluenesulfonic acid Acetic anhydride 2-Iodoxybenzoic acid Potassium bromate Acetic acid

Preparation Products

C-(3,4-DIHYDRO-2H-BENZO[1,4]OXAZIN-3-YL)-METHYLAMINE

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View Lastest Price from Dess-Martin periodinane manufacturers

Hunan aslsen technology co.,ltd

Product: 2-benziodoxol-(1H)-one 87413-09-0
Price: US $10.00/kg
Min. Order: 1kg
Purity: 99.99%
Supply Ability: 1000000000 ton
Release date: 2024-04-10

ANHUI WITOP BIOTECH CO., LTD

Product: Dess-Martin periodinane 87413-09-0
Price: US $1.00/g
Min. Order: 1g
Purity: 99%
Supply Ability: 10 tons
Release date: 2021-03-23

Zhuozhou Wenxi import and Export Co., Ltd

Product: Dess-Martin periodinane 87413-09-0
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

87413-09-0, Dess-Martin periodinaneRelated Search:

ACETYLTHIOCHOLINE IODIDE 4-Acetoxystyrene Dihydromyrcenol Sodium triacetoxyborohydride ACETYLCHOLINE IODIDE Benzyloxyacetyl chloride (1S,2S,3S,5S)-5-(2-Amino-6-(benzyloxy)-9H-purin-9-yl)-3-(benzyloxy)-2-(benzyloxymethyl)cyclopentanol 2-Amino-1,9-dihydro-9-[(1S,3R,4S)-4-(benzyloxy)-3-(benzyloxymethyl)-2-methylenecyclopentyl]-6H-purin-6-one Entecavir 6-(Benzyloxy)-9-((1S,3S)-4-(benzyloxy)-3-((benzyloxy)methyl)-2-methylenecyclopentyl)-N-((4-methoxyphenyl)diphenylmethyl)-9H-purin-2-amine Methyl (R)-2-(Benzylamino)-3-hydroxypropanoate N-Benzyl-DL-serine Methyl Ester HATU Dichloromethane (Diacetoxyiodo)benzene 2-Iodobenzoic acid Dess-Martin periodinane

Dess-Martin periodinane,D M P, TAPI

dess-martin periodinate

1,1,1-Triacetoxy-1,2-benziodoxole-IV-3(1H)-one

1,1,1-Triacetoxy-1,3-dihydro-3-oxo-1,2-benziodoxole-IV

1,1,1-Triacetoxy-3H-1,2-benziodoxole-IV-3-one

Martin's reagent

1,1-Dihydro-1,1,1-triacetoxy-1,2-benzoiodooxol-3(1H)-one (Dess-M

Dess-Martin periodinane solution

Dess-Martin periodinane,1,1,1-Tris(acetyloxy)-1,1-dihydro-1,2-benziodoxol-3-(1H)-one

Acetic acid, 1,1',1''-(3-oxo-1.lambda.5-1,2-benziodoxol-1(3H)-ylidyne) ester

Dess-Martin periodinane, 15 wt.% solution in dichloromethane, AcroSeal

1,1-dihydro-1,1,1-triacetoxy-1,2-benziodoxol-3(1H)-one

1,1,1-Triacetoxy-1,2-benziodoxol-3(1H)-one(Dess-Martin periodinane)

Dess-Martin periodinane, 15 wt.% solution in dichloroMethane 50ML

Dess-Martin Periodinane (Technical Grade)

Dess-Martin periodinane, 15 wt.% solution in CH2Cl2, J&KSeal

Dess-Martin periodinane 97%

Dess-Martin periodinane solution 0.3 M in Methylene chloride

Dess-Martin periodinane, 15 wt.% solution in CH2Cl2, SpcSeal

Deiss Martin reagent

DESS-MARTIN

DESS-MARTIN PERIODINANE

DESS-MARTIN REAGENT

DESSS-MARTIN PERIODINANE

1,1-DIHYDRO-1,1,1-TRIACETOXY-1,2-BENZOIODOOXOL-3(1H)-ONE

1,1,1-TRIACETOXY-1,1-DIHYDRO-1,2-BENZIODOXOL-3(1H)-ONE

1,1,1-TRIS(ACETYLOXY)-1,1-DIHYDRO-1,2-BENZIODOXOL-3-(1H)-ONE

ACETIC ACID 1,1-DIACETOXY-3-OXO-1L5-IODA-2-OXA-INDAN-1-YL ESTER

TRIACETOXYPERIODINANE

Dess-Martinperiodinane,97%

Dess-Martin periodane

3-oxo-1l5-benzo[d][1,2]iodaoxole-1,1,1(3H)-triyl triacetate

1,1,1-TRIACETOXY-1,1-DIHYDRO-1,2-BENZIODOXOL-3(1H)-ONE(DESSMARTINE)

1,1-DIHYDRO-1,1,1-TRIACETOXY-1,2-BENZOIODOOXOL-3(1H)-ONE (DESS-MARTIN PERIODINANE)

DESS-MARTIN(1,1,1-TRIACETOXY-1,1-DIHYDRO-1,2-BENZIODOXOL-3(1H)-ONE)

Dess Martin Periodinane 0.3M in DCM

Dess-Martin Periodinane (8-12% in Dichloromethane)

(1,1-diacetyloxy-3-oxo-1λ5,2-benziodoxol-1-yl) Acetate

RARECHEM AR PA 0035

Triacetoxyperiodinane (Dess-Martin periodinane)

DESS-MARTIN PERIODINANE, 0.3M SOLUTION &

(7,7-DIACETYLOXY-9-OXO-7$L^{5}-IODA-8-OXABICYCLO[4.3.0]NONA-1,3,5-TRIEN-7-YL) ACETATE

DesmartinPeriodinane

DmpDess-MartinPeriodinane

Dess-Martin periodinane, 15 wt.% solution in dichloromethane

1,2-Benziodoxol-3(1H)-one, 1,1,1-tris(acetyloxy)-1,1-dihydro-

1,1,1-TRIACETOXY-1,1-DIHYDRO-1,2-BENZIODOXOL-3-(1H)-ONE(DESS-MARTINPERIODINANE)

DESS-MARTINE

DMP DESS-MARTIN PERIODINANE TRIACETOXYPERIODINANE

Dess-Martin Periodinane Triacetoxyperiodinane

Dess-martin oxidizer

PERIODINANE

1,1-bis(acetyloxy)-3-oxo-3H-1λ,2-benziodaoxol-1-yl acetate

Dess-Martin Periodinane (DMP)

Aceticacid,1,1',1''-(3-oxo-1λ5-1,2-benziodoxol-1(3H)-ylidyne)ester

Dess-Martin periodinane, 15 wt.% solution in CH2Cl2

Days Martin oxidant

Dess-MartinPeriodinane&gt