ChemicalBook > CAS DataBase List > Dess-Martin periodinane

Dess-Martin periodinane

Product Name
Dess-Martin periodinane
CAS No.
87413-09-0
Chemical Name
Dess-Martin periodinane
Synonyms
DESS-MARTIN;Dess-Martin periodane;DESS-MARTIN REAGENT;PERIODINANE;DESS-MARTINE;1,1,1-TRIACETOXY-1,1-DIHYDRO-1,2-BENZIODOXOL-3(1H)-ONE;Dess-Martin periodinane,D M P, TAPI;3-oxo-1l5-benzo[d][1,2]iodaoxole-1,1,1(3H)-triyl triacetate;1,1,1-TRIS(ACETYLOXY)-1,1-DIHYDRO-1,2-BENZIODOXOL-3-(1H)-ONE;Martin's reagent
CBNumber
CB0776475
Molecular Formula
C13H13IO8
Formula Weight
424.14
MOL File
87413-09-0.mol
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Dess-Martin periodinane Property

Melting point:
130-133 °C (lit.)
Boiling point:
40 °C
Density 
1.369 g/mL at 25 °C
Flash point:
>221 °F
storage temp. 
-20°C
solubility 
Soluble in chloroform, acetone, acetonitrile and methylene chloride. Slightly soluble in ether and hexane.
form 
Liquid
color 
Colorless to light yellow
Sensitive 
Light Sensitive
Merck 
14,2933
BRN 
4548207
Stability:
Light Sensitive
InChI
InChI=1S/C13H13IO8/c1-8(15)19-14(20-9(2)16,21-10(3)17)12-7-5-4-6-11(12)13(18)22-14/h4-7H,1-3H3
InChIKey
NKLCNNUWBJBICK-UHFFFAOYSA-N
SMILES
I1(OC(=O)C)(OC(=O)C)(OC(=O)C)OC(=O)C2C=CC=CC1=2
CAS DataBase Reference
87413-09-0(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn,O,Xi
Risk Statements 
22-36/37/38-40-8-20/21/22-44
Safety Statements 
26-36-36/37-24/25-23-17-45-36/37/39
RIDADR 
UN 1593 6.1/PG 3
WGK Germany 
3
Hazard Note 
Harmful/Light sensitive
TSCA 
No
HazardClass 
5.1
PackingGroup 
Ⅲ
HS Code 
29349990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H272May intensify fire; oxidizer

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P220Keep/Store away from clothing/…/combustible materials.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
274623
Product name
Dess-Martin periodinane
Purity
97%
Packaging
5g
Price
$136
Updated
2024/03/01
Sigma-Aldrich
Product number
274623
Product name
Dess-Martin periodinane
Purity
97%
Packaging
25g
Price
$648
Updated
2024/03/01
TCI Chemical
Product number
D2045
Product name
Dess-Martin Periodinane
Purity
>95.0%(T)
Packaging
1g
Price
$35
Updated
2024/03/01
TCI Chemical
Product number
D2045
Product name
Dess-Martin Periodinane
Purity
>95.0%(T)
Packaging
5g
Price
$106
Updated
2024/03/01
Alfa Aesar
Product number
L15779
Product name
Dess-Martin periodinane
Packaging
1g
Price
$39.3
Updated
2024/03/01
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Dess-Martin periodinane Chemical Properties,Usage,Production

Description

Dess-Martin periodinane (DMP) is a hypervalent iodine compound widely used as a mild reagent for the oxidation of primary/secondary alcohols to aldehydes/ketones; oxidation of amides into imides; the dehydrogenation of amines to nitriles, and disulfides to sulfones. It is also used to selectively oxidize alkenes to epoxides. This is a useful reaction for generating three-membered cyclic ethers. Additionally, DMP is used to oxidatively cleave 1,2-diols to form aldehydes or ketones and in the synthesis of lactones.

Chemical Properties

White Crystalline powder

Uses

Dess-Martin Periodinaneis a very usefulreagent used in the oxidation of primary alcohols to aldehydes and secondary alcohols to ketones.

Uses

Dess Martin periodinane is used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. It is also used as an oxidant for complexes with multifunctional alcohols. It is actively involved in the oxidation of N-protected-amino alcohols without epimerization and allylic alcohols.

Uses

Oxidizing reagent.

Advantages

Benefits of using Dess-Martin periodinane (DMP) as an oxidizing reagent:
milder reaction conditions (room temperature, neutral pH)
shorter reaction times and higher yields
high chemoselectivity
tolerance of sensitive functional groups, and a long shelf life
simplified workups

Dess-Martin periodinane Preparation Products And Raw materials

Raw materials

2-Iodobenzoic acid p-Toluenesulfonic acid Acetic anhydride 2-Iodoxybenzoic acid Potassium bromate Acetic acid

Preparation Products

C-(3,4-DIHYDRO-2H-BENZO[1,4]OXAZIN-3-YL)-METHYLAMINE
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View Lastest Price from Dess-Martin periodinane manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd
Product
Dess-Martin periodinane 87413-09-0
Price
US $79.00-38.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-11-21
R&D Scientific Inc.
Product
1,1,1-triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H)-one 87413-09-0
Price
US $786.00/g
Min. Order
1g
Purity
98
Supply Ability
500 Kg
Release date
2024-11-12
ANHUI WITOP BIOTECH CO., LTD
Product
Dess-Martin periodinane 87413-09-0
Price
US $1.00/g
Min. Order
1g
Purity
99%
Supply Ability
10 tons
Release date
2021-03-23

87413-09-0, Dess-Martin periodinaneRelated Search:

ACETYLTHIOCHOLINE IODIDE 4-Acetoxystyrene Dihydromyrcenol Sodium triacetoxyborohydride ACETYLCHOLINE IODIDE Benzyloxyacetyl chloride (1S,2S,3S,5S)-5-(2-Amino-6-(benzyloxy)-9H-purin-9-yl)-3-(benzyloxy)-2-(benzyloxymethyl)cyclopentanol 2-Amino-1,9-dihydro-9-[(1S,3R,4S)-4-(benzyloxy)-3-(benzyloxymethyl)-2-methylenecyclopentyl]-6H-purin-6-one Entecavir 6-(Benzyloxy)-9-((1S,3S)-4-(benzyloxy)-3-((benzyloxy)methyl)-2-methylenecyclopentyl)-N-((4-methoxyphenyl)diphenylmethyl)-9H-purin-2-amine Methyl (R)-2-(Benzylamino)-3-hydroxypropanoate N-Benzyl-DL-serine Methyl Ester HATU Dichloromethane (Diacetoxyiodo)benzene 2-Iodobenzoic acid Dess-Martin periodinane

  • Dess-Martin periodinane,D M P, TAPI
  • dess-martin periodinate
  • 1,1,1-Triacetoxy-1,2-benziodoxole-IV-3(1H)-one
  • 1,1,1-Triacetoxy-1,3-dihydro-3-oxo-1,2-benziodoxole-IV
  • 1,1,1-Triacetoxy-3H-1,2-benziodoxole-IV-3-one
  • Martin's reagent
  • 1,1-Dihydro-1,1,1-triacetoxy-1,2-benzoiodooxol-3(1H)-one (Dess-M
  • Dess-Martin periodinane solution
  • Dess-Martin periodinane,1,1,1-Tris(acetyloxy)-1,1-dihydro-1,2-benziodoxol-3-(1H)-one
  • Acetic acid, 1,1',1''-(3-oxo-1.lambda.5-1,2-benziodoxol-1(3H)-ylidyne) ester
  • Dess-Martin periodinane, 15 wt.% solution in dichloromethane, AcroSeal
  • 1,1-dihydro-1,1,1-triacetoxy-1,2-benziodoxol-3(1H)-one
  • 1,1,1-Triacetoxy-1,2-benziodoxol-3(1H)-one(Dess-Martin periodinane)
  • Dess-Martin periodinane, 15 wt.% solution in dichloroMethane 50ML
  • Dess-Martin Periodinane (Technical Grade)
  • Dess-Martin periodinane, 15 wt.% solution in CH2Cl2, J&KSeal
  • Dess-Martin periodinane 97%
  • Dess-Martin periodinane solution 0.3 M in Methylene chloride
  • Dess-Martin periodinane, 15 wt.% solution in CH2Cl2, SpcSeal
  • Deiss Martin reagent
  • DESS-MARTIN
  • DESS-MARTIN PERIODINANE
  • DESS-MARTIN REAGENT
  • DESSS-MARTIN PERIODINANE
  • 1,1-DIHYDRO-1,1,1-TRIACETOXY-1,2-BENZOIODOOXOL-3(1H)-ONE
  • 1,1,1-TRIACETOXY-1,1-DIHYDRO-1,2-BENZIODOXOL-3(1H)-ONE
  • 1,1,1-TRIS(ACETYLOXY)-1,1-DIHYDRO-1,2-BENZIODOXOL-3-(1H)-ONE
  • ACETIC ACID 1,1-DIACETOXY-3-OXO-1L5-IODA-2-OXA-INDAN-1-YL ESTER
  • TRIACETOXYPERIODINANE
  • Dess-Martinperiodinane,97%
  • Dess-Martin periodane
  • 3-oxo-1l5-benzo[d][1,2]iodaoxole-1,1,1(3H)-triyl triacetate
  • 1,1,1-TRIACETOXY-1,1-DIHYDRO-1,2-BENZIODOXOL-3(1H)-ONE(DESSMARTINE)
  • 1,1-DIHYDRO-1,1,1-TRIACETOXY-1,2-BENZOIODOOXOL-3(1H)-ONE (DESS-MARTIN PERIODINANE)
  • DESS-MARTIN(1,1,1-TRIACETOXY-1,1-DIHYDRO-1,2-BENZIODOXOL-3(1H)-ONE)
  • Dess Martin Periodinane 0.3M in DCM
  • Dess-Martin Periodinane (8-12% in Dichloromethane)
  • (1,1-diacetyloxy-3-oxo-1λ5,2-benziodoxol-1-yl) Acetate
  • RARECHEM AR PA 0035
  • Triacetoxyperiodinane (Dess-Martin periodinane)
  • DESS-MARTIN PERIODINANE, 0.3M SOLUTION &
  • (7,7-DIACETYLOXY-9-OXO-7$L^{5}-IODA-8-OXABICYCLO[4.3.0]NONA-1,3,5-TRIEN-7-YL) ACETATE
  • DesmartinPeriodinane
  • DmpDess-MartinPeriodinane
  • Dess-Martin periodinane, 15 wt.% solution in dichloromethane
  • 1,2-Benziodoxol-3(1H)-one, 1,1,1-tris(acetyloxy)-1,1-dihydro-
  • 1,1,1-TRIACETOXY-1,1-DIHYDRO-1,2-BENZIODOXOL-3-(1H)-ONE(DESS-MARTINPERIODINANE)
  • DESS-MARTINE
  • DMP DESS-MARTIN PERIODINANE TRIACETOXYPERIODINANE
  • Dess-Martin Periodinane Triacetoxyperiodinane
  • Dess-martin oxidizer
  • PERIODINANE
  • 1,1-bis(acetyloxy)-3-oxo-3H-1λ,2-benziodaoxol-1-yl acetate
  • Dess-Martin Periodinane (DMP)
  • Aceticacid,1,1',1''-(3-oxo-1λ5-1,2-benziodoxol-1(3H)-ylidyne)ester
  • Dess-Martin periodinane, 15 wt.% solution in CH2Cl2
  • Days Martin oxidant
  • Dess-MartinPeriodinane&gt