(+)-N,N'-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE)

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Product Name: (+)-N,N'-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE)
CAS No.: 172138-95-3
Chemical Name: (+)-N,N'-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE)
Synonyms: (S,S)-DACH-pyridyl Trost ligand;(S,S)-DACH-pyridyl Trost ligand 95%;2,6-Bis[(4S)-benzyl-2-oxazolin-2-yl]-pyridine;N,N'-((1S,2S)-Cyclohexane-1,2-diyl)dipicolinaMide;(1S,2S)-1,2-Bis(2-pyridinecarboxamido)cyclohexane;N,N'-((1S,2S)-Cyclohexane-1,2-diyl)dipicolinamide;N-((1S,2S)-2-(picolinamido)cyclohexyl)picolinamide;(1R,2R)-(-)-1,2-Bis[(2-pyridinylcarbonyl)amino]cyclohexane;2-Pyridinecarboxamide, N,N'-(1S,2S)-1,2-cyclohexanediylbis-;1S,2S- N,N’-1,2-Diaminocyclohexanediylbis (2-pyridinecarboxamide)
CBNumber: CB1119961
Molecular Formula: C18H20N4O2
Formula Weight: 324.38
MOL File: 172138-95-3.mol

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(+)-N,N'-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) Property

Melting point:: 170°C
Boiling point:: 663.4±50.0 °C(Predicted)
alpha: +95° (c 1, CH3OH)
Density: 1.25±0.1 g/cm3(Predicted)
storage temp.: Inert atmosphere,2-8°C
pka: 12.51±0.40(Predicted)
form: Powder
color: off-white
CAS DataBase Reference: 172138-95-3

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Safety

Hazard Codes: Xn
Risk Statements: 36/37/38-22
Safety Statements: 26-36/37/39-36/37
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Strem Chemicals

Product number: 07-0341
Product name: (+)-N,N'-(1S,2S)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide), min. 98% (S,S)-DACH-Pyridyl Trost Ligand
Packaging: 1g
Price: $108
Updated: 2024/03/01

Strem Chemicals

Product number: 07-0341
Product name: (+)-N,N'-(1S,2S)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide), min. 98% (S,S)-DACH-Pyridyl Trost Ligand
Packaging: 5g
Price: $427
Updated: 2024/03/01

Biosynth Carbosynth

Product number: FD149625
Product name: (+)-N,N'-(1S,2S)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide)
Packaging: 1g
Price: $86
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FD149625
Product name: (+)-N,N'-(1S,2S)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide)
Packaging: 2g
Price: $150
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FD149625
Product name: (+)-N,N'-(1S,2S)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide)
Packaging: 5G
Price: $300
Updated: 2021/12/16

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(+)-N,N'-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) Chemical Properties,Usage,Production

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Ligands for Mo catalyzed asymmetric allylic substitutions. Especially useful for the synthesis of tertiary and quaternary stereocenters. Exclusive license for this technology acquired by ChiroTech and is protected by pending Stanford University patents.
Dynamic kinetic asymmetric formation of tertiary and quaternary stereogenic centers

Uses

Trost Ligands for Asymmetric Allylic Alkylation

(+)-N,N'-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) Preparation Products And Raw materials

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Preparation Products

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(+)-N,N'-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) Suppliers

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172138-95-3, (+)-N,N'-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE)Related Search:

2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine N-Acetyl-L-cysteine N-CARBAMYL-L-GLUTAMIC ACID 1,2-Diaminocyclohexane PYRIDINE-2-CARBOXAMIDE (-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) N,N'-BIS-2-PYRIDYLMETHYL ETHYLENEDIAMINE (+/-)-trans-1,2-Diaminocyclohexane (1S,2S)-N,N'-Dimethyl-1,2-cyclohexanediamine (1S,2S)-(+)-1,2-Diaminocyclohexane 2-(CYCLOHEXYLAMINOMETHYL)PYRIDINE (+)-N,N'-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE)

1S,2S- N,N’-1,2-Diaminocyclohexanediylbis (2-pyridinecarboxamide)

2,6-Bis[(4S)-benzyl-2-oxazolin-2-yl]-pyridine

(+)-N,N'-(1S,2S)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide),min.98%

(+)-N,N''-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE), MIN. 98%

N-((1S,2S)-2-(picolinamido)cyclohexyl)picolinamide

(1S,2S)-N,Nμ-1,2-Cyclohexanediylbis(2-pyridinecarboxamide), (+)-N,Nμ-(1S,2S)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide), (1S,2S)-(+)-1,2-Bis[(2-pyridinylcarbonyl)amino]cyclohexane, (1S,2S)-1,2-Bis(2-pyridinecarboxamido)cyclohexane

(S,S)-DACH-pyridyl Trost ligand

(1R,2R)-(-)-1,2-Bis[(2-pyridinylcarbonyl)amino]cyclohexane

(1R,2R)-N,Nμ-1,2-Cyclohexanediylbis(2-pyridinecarboxamide), (1R,2R)-1,2-Bis(2-pyridinecarboxamido)cyclohexane

N,N'-((1S,2S)-Cyclohexane-1,2-diyl)dipicolinaMide

(S,S)-DACH-pyridyl Trost ligand 95%

(+)-N,N'-(1S,2S)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide),98%

(1S,2S)-N,N'-1,2-Diaminocyclohexanediylbis(2- pyridinecarboxamide),99%e.e.

(+)-N,N'-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE),MIN.98%(S,S)-DACH-PYRIDYLTROSTLIGAND

(+)-N,N'-(1S,2S)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide), min. 98% (S,S)-DACH-Pyridyl Trost Ligand

N-[(1S,2S)-2-(pyridine-2-carbonylamino)cyclohexyl]pyridine-2-carboxamide

(+)-N,N'-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE)

(1S,2S)-1,2-Bis(2-pyridinecarboxamido)cyclohexane

2-Pyridinecarboxamide, N,N'-(1S,2S)-1,2-cyclohexanediylbis-

(+)-N,N'-(1S,2S)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide)

(+)-N,N'-(1S,2S)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide),98%

N,N'-((1S,2S)-Cyclohexane-1,2-diyl)dipicolinamide

(+)-N,N'-(1S,2S)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide)

(+)-N,N'-(1S,2S)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide),98%

172138-95-3

C18H20N4O2

Chiral Nitrogen

DACH&Trost Series