Overview Applications Mode of action Warning and Risk References
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Fenthion

Overview Applications Mode of action Warning and Risk References
Product Name
Fenthion
CAS No.
55-38-9
Chemical Name
Fenthion
Synonyms
MPP;oms2;Entex;FENTANYLCITRATE;OMS 2;BAYCID;FASTER;S 1752;Baycin;Bayten
CBNumber
CB1129166
Molecular Formula
C10H15O3PS2
Formula Weight
278.33
MOL File
55-38-9.mol
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Fenthion Property

Melting point:
7.5°C
Boiling point:
87°C (0.01 mmHg)
Density 
1.25
vapor pressure 
7.4 x 10-4 Pa (20 °C)
refractive index 
nD20 1.5698
Flash point:
>100 °C
storage temp. 
2-8°C
solubility 
Chloroform (Sparingly), DMSO (Sparingly)
form 
liquid
Water Solubility 
0.0055 g/100 mL
Merck 
13,4030
BRN 
1974129
Exposure limits
OSHA PEL: TWA 0.2 mg/m3; ACGIH TLV: TWA 0.2 mg/m3
Stability:
Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference
55-38-9(CAS DataBase Reference)
NIST Chemistry Reference
Fenthion(55-38-9)
EPA Substance Registry System
Fenthion (55-38-9)
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Safety

Hazard Codes 
T;N,N,T,Xn,F
Risk Statements 
21/22-23-48/25-50/53-68-67-65-38-11
Safety Statements 
36/37-45-60-61-62
RIDADR 
UN 2810/3017
WGK Germany 
3
RTECS 
TF9625000
HazardClass 
6.1(b)
PackingGroup 
III
HS Code 
29309090
Hazardous Substances Data
55-38-9(Hazardous Substances Data)
Toxicity
LD50 in male, female rats (mg/kg): 215, 245 orally (Gaines)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H330Fatal if inhaled

H341Suspected of causing genetic defects

H372Causes damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
36552
Product name
Fenthion
Purity
PESTANAL
Packaging
250mg
Price
$35.3
Updated
2024/03/01
TRC
Product number
F278000
Product name
Fenthion
Packaging
10g
Price
$285
Updated
2021/12/16
TRC
Product number
F278000
Product name
Fenthion
Packaging
100g
Price
$2060
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
PST0000152
Product name
FENTHION
Purity
95.00%
Packaging
50G
Price
$3418.8
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
PST0000152
Product name
FENTHION
Purity
95.00%
Packaging
5G
Price
$889.35
Updated
2021/12/16
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Fenthion Chemical Properties,Usage,Production

Overview

Fenthion is an organothiophosphate insecticide, avicide, and acaricide. Like most other organophosphates, it acts as a cholinesterase inhibitor[1, 2]. It has relatively low toxicity towards humans and mammals and is listed as moderately toxic compound in U.S. Environmental Protection Agency and World Health Organization toxicity class. However, it is highly toxic to birds. It can be used in agriculture and against mosquito larvae in tropical fresh waters[2, 3].
Fenthion is a contact and stomach insecticide, which can be used for the treatment of many sucking, biting pests, especially mosquitoes, fruit flies, stem borers, and Eurygaster cereal bugs. Specially, it is toxic to both the adult and immature forms[larvae] of the mosquitoes. Due to that it has been used extensively in the U.S. for controlling intestinal worms, fenthion no longer has FDA approval due to an excess number of poisoning deaths. Fenthion is available in dust, emulsifiable concentrate, granular, liquid concentrate, spray concentrate, ULV and wettable powder formulations[4].

Applications

Fenthion is used for field and post-harvest treatment of various fruits, vegetables, and ornamentals[including sugar cane, rice, field corn, beets, pome and stone fruits, citrus fruits, pistachio, cotton, olives, coffee, cocoa and vines], for mosquito control in water and septic tanks, for pest control in commercial and domestic areas and as an ectoparasiticide in cattle[1, 2,5]. Fenthion is also used for quarantine control of Queensland fruit fly and other fruit flies through post-harvest treatments[dipping, flood sprays and non-recirculating low volume sprays]. It is highly effective in the treatment of various pests including fruit flies, leafhoppers, cereal bugs, stem borers, mosquitoes, animal parasites, mites, aphids, codling moths, and weaverbirds[6].
While it is effective as an insecticide, it is also moderately toxic to mammals, and highly toxic to birds. Based on its high toxicity to birds, fenthion is used in various parts of the world for weaverbird control. Pest control operators have used it to control pigeons around public buildings, as well. Once contacting bird, fenthion can subject to rapid absorption through the skin and killing birds. Acute symptoms of fenthion poisoning in birds include tearing of the eyes, foamy salivation, lack of movement, tremors, congestion of the windpipe, lack of coordination in walking, and an abnormally rapid rate of breathing or difficult breathing. It is usually applied as a paste to roosting areas when utilized for such purposes[6, 7]. Fenthion has also been tested in dogs and cows for possible control of parasites[8].

Mode of action

Fenthion belongs to one of a class of insecticides referred to as organophosphates[1,9]. These chemicals act by interfering with the activities of cholinesterase, an esterase that lyses choline-based esters, several of which serve as neurotransmitters. Thus, it is either of two enzymes that catalyze the hydrolysis of these cholinergic neurotransmitters, such as breaking acetylcholine into choline and acetic acid. These reactions are necessary to allow a cholinergic neuron to return to its resting state after activation. Therefore, it is essential for the proper working of the nervous systems of both humans and insects[10, 11].

Warning and Risk

Fenthion can provide both acute toxicity and chronic toxicity.
Acute toxicity[12]
It is moderately toxic if ingested, inhaled, or absorbed through the skin. It affects the central nervous, cardiovascular, and respiratory systems, and may irritate eyes and mucous membranes. When inhaled, the first effects may include bloody or runny nose, coughing, chest discomfort, difficult or short breath, and wheezing due to constriction or excess fluid in the bronchial tubes. Skin contact with organophosphates may cause localized sweating and involuntary muscle contractions. Eye contact will cause bleeding, tears, pupil constriction, pain, and blurred vision. Symptoms of acute exposure to organophosphate or cholinesterase-inhibiting compounds may also include the following: dizziness, tremor, nausea, abdominal cramps, sweating, blurred vision, headache, numbness, tingling sensations, incoordination, difficulty breathing or respiratory depression, and slow heartbeat. Very high doses may result in unconsciousness, incontinence, and convulsions or fatality[12].
Chronic toxicity
Carcinogenic effectsThe National Cancer Institute performed carcinogenicity tests on fenthion that indicated that this insecticide might be a carcinogen in male mice. However, no carcinogenic effects were observed in other two-year feeding studies of rats and mice[13].
Reproductive effects-Single injections of 40 or 80 mg/kg of fenthion into the abdominal cavities of pregnant female mice caused poisoning in the developing fetuses, particularly when administered on days 10 through 12 of gestation. There were significantly more abnormalities in the offspring of female mice that had received 40 mg/kg on days 8 or 10 of pregnancy[14, 15].
Teratogenicity effects-Some reduction in fetal weight occurred, but no defects were found in mice that were given intraperitoneal doses of up to 80 mg/kg of fenthion in single day or 3-day periods during the period of gestation in which organs are formed[16].

References

  1. Thomson, W. T. 1976. Insecticides, acaricides and avicides. Agricultural Chemicals, Book I. Fresno, CA: Thomson Publications.
  2. EXTOXNET.[2003]. Pesticide information Profile for Fenthion. Cooperative Extension Offices of Cornell University, Michigan State University, Oregon State University, and University of California at Davis.
  3. Meister, R.T.[ed.]. 1992. Farm Chemicals Handbook '92. Meister Publishing Company, Willoughby, OH.
  4. Occupational Health Services, Inc. 1986. Material safety data sheet. Secaucus, NJ: OHS, Inc.
  5. https://sitem.herts.ac.uk/aeru/ppdb/en/Reports/310.htm
  6. Tucker, R. and D. G. Crabtree. 1970. Handbook of toxicity of pesticides to wildlife. U.S. Department of Agriculture, Fish and Wildlife Service. Bureau of Sport Fisheries and Wildlife.
  7. McEwen, F. L. and G. R. Stephenson. 1979. The use and significance of pesticides in the environment. NY: John Wiley and Sons, Inc.
  8. Hayes, W.J. and E.R. Laws[ed.]. 1990. Handbook of Pesticide Toxicology, Vol. 3, Classes of Pesticides. Academic Press, Inc., NY.
  9. Sakaguchi, K., Akahori, F., Shirai, M., Masaoka, T., Arishima, K., & Kounenis, G.[1998]. Effect of combined fenthion and cimetidine use in rats on lethality, blood cholinesterase activities, and serum cholinesterase isoenzymes. Veterinary & Human Toxicology, 40(2], 77-82.
  10. Macqueen, J, and D. Plaut. "A review of clinical applications and methods for cholinesterase. " American Journal of Medical Technology 39.7(1973]: 279-287.
  11. Corbel, V., Stankiewicz, M., Pennetier, C., Fournier, D., Stojan, J., & Girard, E., et al.[2009]. Evidence for inhibition osnsect and mammalian nervous systems by the insect repellent deet. Bmc Biology, 10(1], 86-86.
  12. Occupational Health Services, Inc. 1991[Sept. 16]. MSDS for Fenthion. OHS Inc., Secaucus, NJ.
  13. National Cancer Institute. 1979. Bioassay of fenthion for possible carcinogenicity. Technical report series no. 103. U.S. Department of Health, Education, and Welfare. Publication No.[NIH] 791353. Washington, DC: U.S. Government Printing Office.
  14. ACGIH. 1986. Documentation of threshold limit values and biological exposure indices. Cincinnati, OH: Publications Office, ACGIH.
  15. Hayes, W. J. 1982. Pesticides studied in man. Baltimore, MD: Williams and Wilkins.
  16. Shepard, T. H. 1986. Catalog of teratogenic agents. Fifth edition. Baltimore, MD: The Johns Hopkins University Press.

Description

Fenthion is a colorless oily liquid (technical grade, brown oily liquid with a mercaptan-like odor).

Chemical Properties

yellow brown oily liquid

Chemical Properties

Pure fenthion is a colorless liquid. Technical fenthion is a yellow or brown oily liquid with a weak garlic odor. It is insoluble or very sparingly soluble in water, but soluble in all organic solvents, alcohols, ethers, esters, halogenated aromatics, and petroleum ethers. It is grouped by the US EPA under RUP and hence requires handling by qualifi ed, certifi ed, and trained workers. Fenthion is used for the control of sucking and biting pests, i.e., fruit fl ies, stem borers, mosquitoes, and cereal bugs. In mosquitoes, it is toxic to both the adult and immature forms (larvae). The formulations of fenthion include dust, emulsifi able concentrate, granular, liquid concentrate, spray concentrate, ULV, and wettable powder.

Chemical Properties

Fenthion is a colorless liquid (when pure) with a weak, garlic-like odor. The technical grade is a yellow-to-brown oil.

Uses

Insecticide for control of fruit ?ies, leaf hoppers and cereal bugs. Fenthion is also used as an acaracide.

Uses

antihypertensive

Uses

Fenthion is an organothiophosphate used as an insecticide. Fenthion is also a potent acaricide.

Uses

Insecticide; acaricide.

Definition

ChEBI: An organic thiophosphate that is O,O-dimethyl hydrogen phosphorothioate in which the hydrogen atom of the hydroxy group is replaced by a 3-methyl-4-(methylsulfanyl)phenyl group. It exhibits acaricidal and insecticidal activities.

General Description

Yellow to tan oily liquid with a slight odor of garlic.

Reactivity Profile

Fenthion may react with strong reducing agents such as hydrides to generate highly toxic and flammable phosphine gas. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.

Hazard

Toxic by ingestion, inhalation, and skin absorption; use may be restricted, cholinesterase inhibitor. Toxic by skin absorption; questionable carcinogen.

Health Hazard

Fenthion is moderately toxic to mammals, and highly toxic to birds. Exposures to fenthion cause poisoning with symptoms among occupational workers as observed with organophosphate pesticide-induced toxicity. These include, but are not limited to, numbness, tingling sensations, incoordination, headache, dizziness, tremor, nausea, abdominal cramps, sweating, blurred vision, diffi culty breathing or respiratory depression, and slow heart beat. Very high doses may result in unconsciousness, incontinence, and convulsions or fatality. Reports have indicated that exposures to fenthion cause adverse effects on the central and peripheral nervous systems, and the heart of exposed workers.

Fire Hazard

Fenthion is probably combustible.

Agricultural Uses

Insecticide, Larvicide, Veterinary medicine: Not registered for use in the U.S. Not approved for use in EU countries. Used in 20 countries including Australia. There are 23 global suppliers.

Trade name

B 29493®; BACID®; BAY 29493®; BAYCID®; BAYER 29493®; BAYER 9007®; BAYER S-1752®; BAYTEX®; ENTEX®; LEBAYCID®; MPP®; MPP (pesticide) OMS 2®; PHENTHION®; PILARTEX®; QUELETOX®; S 1752®; SPOTTON®; SULFIDOPHOS®; TALODEX®; TIGUVON®

Potential Exposure

A potential danger to those involved in the manufacture, formulation, or application of this agricultural chemical and pesticide; insecticide

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Speed in removing material from skinis of extreme importance. Shampoo hair promptly if contaminated. Seek medical attention immediately. If thischemical has been inhaled, remove from exposure, beginrescue breathing (using universal precautions, includingresuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit. Ifexposure and/or symptoms have occurred, the person shouldbe under medical observation for several days, as somesymptoms may be delayed.

Environmental Fate

Biological. From the first-order biotic and abiotic rate constants of fenthion in estuarine water and sediment/water systems, the estimated biodegradation half-lives were 22.4 and 3.9–14.5 days, respectively (Walker et al., 1988).
Surface Water. In estuarine water, the half-life of fenthion was 4.6 days (Lacorte et al., 1995).
Plant. In plants, fenthion oxidizes to the mesulfenfos and sulfone which further degrades to the sulfone phosphate before undergoing hydrolysis (Hartley and Kidd, 1987).
Photolytic. Fenthion was oxidized to the corresponding sulfoxide and trace amounts (<5% yield) of sulfone when sorbed on soil and exposed to sunlight. The photosensitized oxidation was probably due to the presence of singlet oxygen. The degradation rate was higher in soils containing the lowest organic carbon (Gohre and Miller, 1986).
Chemical/Physical. Stable at temperatures below 210°C (Worthing and Hance, 1991). Emits very toxic fumes of phosphorus and sulfur oxides when heated to decomposition (Sax and Lewis, 1987; Lewis, 1990).

Metabolic pathway

The major route of fenthion metabolism is by oxidation to the sulfoxide which has a higher insecticidal activity than the parent compound. The subsequent oxidation of the sulfoxide to fenthion sulfone, the biological activity of which is considerably lower, is slow in plants but of major significance in animals. An additional route of bioactivation is through oxidative desulfuration to form fenoxon and, in all, five oxidative metabolites (fenthion sulfoxide, fenthon sulfone, fenoxon, fenoxon sulfoxide and fenoxon sulfone) have been detected in most biological systems. Hydrolysis, in contrast to most insecticidal phosphorothioates, appears to proceed via direct hydrolysis of fenthion rather than its oxon. The phenolic leaving group (3-methyl-4-thiomethylphenol) is identical to that of fenamiphos and although no studies have described the fate of the phenolic moiety for fenthion, it is likely that it will be metabolised by similar routes to those described for fenamiphos.

storage

: Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Prior to working with thischemical you should be trained on its proper handling andstorage. Store in tightly closed containers in a cool, wellventilated area away from oxidizers, alkalies and alkalinepesticides. A regulated, marked area should be establishedwhere this chemical is handled, used, or stored in compliance with OSHA Standard 1910.1045.

Shipping

UN3018 Organophosphorus pesticides, liquid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN2810 Toxic liquids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.

Toxicity evaluation

Acute oral LD50 for rats: ca. 250 mg /kg

Degradation

Fenthion is stable in light, stable to acid and moderately stable to alkaline conditions. The DT50s at pH 4, 7 and 9 were 223, 151 and 151 days respectively (PM).
The effect of the cuticular waxes of fruit upon the photodegradation of fenthion was studied by Cabras et al. (1997). Waxes were extracted with acetone and the fenthion added to the solution. The wax plus fenthion was applied as a film which was irradiated by natural sunlight. The analysis of fenthion and its metabolites was by GLC-FID (Cabras and Plumitallo, 1991). The potential metabolites synthesised were fenthion sulfoxide (2), fenthion sulfone (3), fenoxon (4), fenoxon sulfoxide (5) and fenoxon sulfone (6). Waxes from different fruits affected the decay rate, with wax from oranges and nectarines increasing the rate of decomposition but cuticular wax from olives retarding the rate. In all cases the products of photodegradation were fentluon sulfoxide (2), which steadily increased with time, and fenthion sulfone (3), which remained at a low but detectable level throughout the experiment. Minelli et al. (1996) exposed fenthion in glass jars to natural sunlight and analysed the photodegradation products by GLC-FID. The major product was fenthion sulfoxide (2) which very slowly degraded to the sulfone (3). This in turn was even more slowly photo-oxidised to fenoxon sulfone (6). The routes for the photodegradation of fenthion are shown in Scheme 1.

Incompatibilities

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, alkaline insecticides. Organothiophosphates are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrideds and active metals. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.

Waste Disposal

Hydrolysis and landfill for small quantities; incineration with flue gas scrubbing for large amounts. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office

Fenthion Preparation Products And Raw materials

Raw materials

Preparation Products

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Fenthion Suppliers

Chemsky(shanghai)International Co.,Ltd.
Tel
021-50135380
Email
shchemsky@sina.com
Country
China
ProdList
32344
Advantage
50
BEST-REAGENT
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11726
Advantage
57
Chengdu Ai Keda Chemical Technology Co., Ltd.
Tel
4008-755-333 18080918076
Fax
028-86757656
Email
800078821@qq.com
Country
China
ProdList
9725
Advantage
55
9ding chemical ( Shanghai) Limited
Tel
4009209199
Fax
86-021-52271987
Email
sales@9dingchem.com
Country
China
ProdList
22519
Advantage
55
UHN Shanghai Research & Development Co., Ltd.
Tel
021-58958002 18930822973
Fax
+86 (21) 5895-8628
Email
SALES@UHNSHANGHAI.COM
Country
China
ProdList
977
Advantage
58
Shanghai Aladdin Bio-Chem Technology Co.,LTD
Tel
400-6206333 18521732826;
Fax
021-50323701
Email
market@aladdin-e.com
Country
China
ProdList
24835
Advantage
65
Shanghai TaoSu Biochemical Technology Co., Ltd.
Tel
021-33632979
Fax
021-34692979
Email
info@tsbiochem.com
Country
China
ProdList
8073
Advantage
58
Wuhan DKY Technology Co.,Ltd.
Tel
27-81302488 18007166089
Fax
027-81302088
Email
info@dkybpc.com
Country
China
ProdList
2024
Advantage
58
TianJin Alta Scientific Co., Ltd.
Tel
022-65378550-8551
Fax
+86-022-2532-9655
Email
contact@altascientific.com
Country
China
ProdList
2773
Advantage
58
HBCChem, Inc.
Tel
+1-510-219-6317
Fax
+1-650-486-1361
Email
sales@hbcchem.com
Country
United States
ProdList
10658
Advantage
60
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View Lastest Price from Fenthion manufacturers

Hebei Duling International Trade Co. LTD
Product
Fenthion 55-38-9
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000 Ton
Release date
2023-01-13
Zhuozhou Wenxi import and Export Co., Ltd
Product
Fenthion 55-38-9
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11
Dideu Industries Group Limited
Product
Fenthion 55-38-9
Price
US $1.10/g
Min. Order
1g
Purity
99.9%
Supply Ability
100 Tons Min
Release date
2021-07-09

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