ChemicalBook > CAS DataBase List > 2-Morpholinopyrimidin-5-ylboronic acid

2-Morpholinopyrimidin-5-ylboronic acid

Product Name
2-Morpholinopyrimidin-5-ylboronic acid
CAS No.
870521-33-8
Chemical Name
2-Morpholinopyrimidin-5-ylboronic acid
Synonyms
2-Morpholinopyrimidine-5-boronic acid;2-morpholino-5-pyrimidineboronic acid;2-morpholinopyrimidin-5-ylboronic acid;(2-(Morpholin-4-yl)pyrimidin-5-yl)boronic;2-Morpholinopyrimidin-5-ylboronic acid 95%;2-(Morpholine-4-yl)pyrimidine-5-boronic acid;[2-(4-Morpholinyl)-5-pyrimidinyl]boronic acid;Boronic acid,B-[2-(4-morpholinyl)-5-pyrimidinyl]-;2-Morpholinopyrimidine-5-boronic acid(contains varying amounts of Anhydride)
CBNumber
CB11502708
Molecular Formula
C8H12BN3O3
Formula Weight
209.01
MOL File
870521-33-8.mol
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2-Morpholinopyrimidin-5-ylboronic acid Property

Boiling point:
484.0±55.0 °C(Predicted)
Density 
1.37
storage temp. 
Inert atmosphere,2-8°C
pka
3.02±0.19(Predicted)
form 
solid
Appearance
White to yellow Solid
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Safety

HS Code 
2934999090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
M733128
Product name
2-Morpholinopyrimidin-5-ylboronicAcid
Packaging
5g
Price
$60
Updated
2021/12/16
AK Scientific
Product number
X1399
Product name
2-(Morpholine-4-yl)pyrimidine-5-boronicacid
Packaging
250mg
Price
$105
Updated
2021/12/16
Matrix Scientific
Product number
093052
Product name
2-Morpholinopyrimidin-5-ylboronic acid
Purity
95+%
Packaging
250mg
Price
$182
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
BOR0005496
Product name
2-MORPHOLINOPYRIMIDIN-5-YL BORONIC ACID
Purity
95.00%
Packaging
1G
Price
$401.1
Updated
2021/12/16
Matrix Scientific
Product number
093052
Product name
2-Morpholinopyrimidin-5-ylboronic acid
Purity
95+%
Packaging
1g
Price
$404
Updated
2021/12/16
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2-Morpholinopyrimidin-5-ylboronic acid Chemical Properties,Usage,Production

Synthesis

110-91-8

1003845-06-4

870521-33-8

The reaction was carried out with 2-chloropyrimidin-5-ylboronic acid (1 g, 6.32 mmol), morpholine (2.19 mL, 25.26 mmol) and triethylamine (0.88 mL, 6.32 mmol) in ethanol (25 mL) with stirring for 1 hour at 20 °C. After completion of the reaction, water (50 mL) was slowly added to the reaction mixture. The resulting precipitate was collected by filtration and washed with water to finally obtain 2-morpholinopyrimidin-5-ylboronic acid (950 mg, 70% yield) as a milky white solid. The NMR hydrogen spectrum (250 MHz, DMSO-d6) data were as follows: δ 8.63 (s, 2H), 8.05 (s, 2H), 3.68 (ddd, J=23.4,5.7,3.9Hz, 8H).

References

[1] Patent: WO2015/86506, 2015, A1. Location in patent: Page/Page column 131
[2] Patent: WO2015/86512, 2015, A1. Location in patent: Page/Page column 102
[3] Patent: WO2015/86527, 2015, A1. Location in patent: Page/Page column 114; 115
[4] Patent: WO2015/86526, 2015, A1. Location in patent: Page/Page column 147
[5] Patent: WO2015/86525, 2015, A1. Location in patent: Page/Page column 121; 122

2-Morpholinopyrimidin-5-ylboronic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 2-Morpholinopyrimidin-5-ylboronic acid manufacturers

Career Henan Chemical Co
Product
2-Morpholinopyrimidin-5-ylboronic acid 870521-33-8
Price
US $7.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
JD 815
Release date
2019-09-02

870521-33-8, 2-Morpholinopyrimidin-5-ylboronic acidRelated Search:

Folic acid Moroxydine Tridemorph Ethyl 2-(Chlorosulfonyl)acetate Moroxydine hydrochloride Dimethomorph Ascoric Acid 2-Amino-pyrimidine-5-boronic acid flumorph Boronic acid, [2-(dimethylamino)-5-pyrimidinyl]- (9CI) phosphoric acid [2-(2,6-DIMETHYLMORPHOLIN-4-YL)PYRIMIDIN-5-YL]BORONIC ACID 2-(4-MORPHOLINO)PYRIMIDINE-5-BORONIC ACID PINACOL ESTER 2-Morpholinopyrimidin-5-ylboronic acid

  • 2-morpholinopyrimidin-5-ylboronic acid
  • [2-(4-Morpholinyl)-5-pyrimidinyl]boronic acid
  • 2-Morpholinopyrimidine-5-boronic acid
  • Boronic acid,B-[2-(4-morpholinyl)-5-pyrimidinyl]-
  • 2-(Morpholine-4-yl)pyrimidine-5-boronic acid
  • 2-morpholino-5-pyrimidineboronic acid
  • 2-Morpholinopyrimidin-5-ylboronic acid 95%
  • (2-(Morpholin-4-yl)pyrimidin-5-yl)boronic
  • 2-Morpholinopyrimidine-5-boronic acid(contains varying amounts of Anhydride)
  • 870521-33-8
  • C8H12BN3O3