5-Aminoindan

Product Name: 5-Aminoindan
CAS No.: 24425-40-9
Chemical Name: 5-Aminoindan
Synonyms: Aminoindan;AKOS 91137;5-AMINOINDAN;5-INDANAMINE;indan-5-amine;5-AMINOINDANE;5-Indanylamine;indan-5-ylamine;5-Aminoindan,97%;5-AMinoindan 95%
CBNumber: CB1160736
Molecular Formula: C9H11N
Formula Weight: 133.19
MOL File: 24425-40-9.mol

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5-Aminoindan Property

Melting point:: 34-36 °C(lit.)
Boiling point:: 247-249 °C745 mm Hg(lit.)
Density: 0.9222 (rough estimate)
refractive index: 1.4600 (estimate)
Flash point:: >230 °F
storage temp.: 0-10°C
pka: 5.17±0.20(Predicted)
form: Crystalline Solid
color: Brown
Water Solubility: SLIGHTLY SOLUBLE
BRN: 2082278
InChI: InChI=1S/C9H11N/c10-9-5-4-7-2-1-3-8(7)6-9/h4-6H,1-3,10H2
InChIKey: LEWZOBYWGWKNCK-UHFFFAOYSA-N
SMILES: C1C2=C(C=C(N)C=C2)CC1
CAS DataBase Reference: 24425-40-9(CAS DataBase Reference)
NIST Chemistry Reference: 5-Aminoindan(24425-40-9)

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Safety

Hazard Codes: Xn
Risk Statements: 20/21/22
Safety Statements: 36-36/37
WGK Germany: 3
PackingGroup: III
HS Code: 29214900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 130877
Product name: 5-Aminoindan
Purity: 95%
Packaging: 10g
Price: $115
Updated: 2025/07/31

TCI Chemical

Product number: A0991
Product name: 5-Aminoindan
Purity: >98.0%(GC)(T)
Packaging: 10g
Price: $103
Updated: 2025/07/31

TRC

Product number: A611885
Product name: 5-Aminoindan
Packaging: 10g
Price: $140
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FA04021
Product name: 5-Aminoindane
Packaging: 10g
Price: $55
Updated: 2021/12/16

AK Scientific

Product number: V1271
Product name: 5-Aminoindan
Packaging: 1g
Price: $77
Updated: 2021/12/16

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5-Aminoindan Chemical Properties,Usage,Production

Chemical Properties

brown crystalline mass

Uses

5-Aminoindan was used in the synthesis of ligand 18/18 (2-(5-aminoindan)-6-(5-aminoindan)-4-chloro-s-triazine).

Synthesis

41734-55-8

24425-40-9

General procedure for the synthesis of 5-aminoindan from 5-nitroindene: To a solution of EtOAc (20 mL) of 5-nitroindene (80.5 mg, 0.5 mmol) was added 10% Pd/C (catalyst dosage of 20% by mass of 5-nitroindene). The mixture was stirred overnight at room temperature in a hydrogen atmosphere. Upon completion of the reaction, the insoluble material was removed by filtration and washed with EtOAc. The filtrate was concentrated to dryness under reduced pressure to give 5-aminoindene (65 mg, 98% yield) as a brown oil. To a solution of 5-aminoindene (150 mg, 0.8 mmol) in thionyl chloride (4 mL) was added a drop of pyridine followed by reflux for 24 hours. At the end of the reaction, the thionyl chloride was removed by distillation to give 5-aminoindene chloride as a light yellow solid, and the product was used directly in the next step of the reaction. A dichloromethane (2 mL) solution of 5-aminoindene chloride was added dropwise to an anhydrous pyridine (2 mL) solution of 5-aminoindene (65 mg, 0.5 mmol) at 0°C. The mixture was stirred at room temperature for 7 h. Methanol was subsequently removed by distillation. The organic layer was treated sequentially with 1N HCl until acidic. The mixture was partitioned between water and EtOAc. The organic layer was washed with saturated brine, dried over anhydrous Na2SO4 and concentrated in vacuum. The residue was purified by silica gel column chromatography (eluent: hexane/EtOAc = 3/1) to afford the target compound 5-aminoindan (118 mg, 80% yield) as a light yellow solid. Melting point 138~142°C; 1H-NMR: δ8.15 (d, J=6.9Hz, 2H), 7.93 (d, J=8.1Hz, 2H), 7.60 (s, 1H), 7.30 (d, J=8.1Hz, 1H), 7.22 (d, J=7.9Hz, 1H), 3.96 (s, 3H), 2.95-2.89 (m. 4H), 2.13-2.07 (m, 2H); ESI-MS: m/z [M+H]+ 296.

Purification Methods

Distil the indane and then crystallise it from pet ether. [Beilstein 12 I 511, 12 III 2798.]

References

[1] Molecules, 2017, vol. 22, # 1,
[2] Justus Liebigs Annalen der Chemie, 1953, vol. 579, p. 133,151
[3] Journal of the Chemical Society, 1947, p. 95

5-Aminoindan Preparation Products And Raw materials

Raw materials

Preparation Products

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5-Aminoindan Suppliers

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View Lastest Price from 5-Aminoindan manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: 5-Aminoindan 24425-40-9
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

Career Henan Chemical Co

Product: 5-Aminoindan 24425-40-9
Price: US $10.00/KG/Tin
Min. Order: 1KG
Purity: 99%
Supply Ability: 100
Release date: 2019-06-27

24425-40-9, 5-AminoindanRelated Search:

Acetaminophen 4,4'-Methylenedianiline Glucosamine 2,3-DIAMINOTOLUENE AMINOACETONITRILE HYDROGEN SULFATE Diaminomaleonitrile Aminopyrine Iminodiacetonitrile EC 2.6.1.2 Iminodiacetic acid Sulfamic acid 5-AMINOINDAN-1-ONE,5-Aminoindan-1-one, 95+% 6-Aminoindanone 4(5)-NITROINDAN N1-(1-OXO-2,3-DIHYDRO-1H-INDEN-5-YL)ACETAMIDE 1,1,3,3,5-PENTAMETHYL-4,6-DINITROINDANE Diethylaminoethanol N1-(2,3-DIHYDRO-1H-INDEN-5-YL)ACETAMIDE

LABOTEST-BB LT00080766

Aminoindan

indan-5-amine

1H-Inden-5-amine, 2,3-dihydro-

2,3-Dihydro-1H-inden-5-ylamine

[2-[oxo(1-piperidinyl)methyl]cyclohexyl]-(1-piperidinyl)methanone

5-Aminoindan,98+%

5-Aminoindane, 98+%

5-Indanylamine

5-Amino-2,3-dihydro-1H-indene

5-Aminoindan,97%

5-AMinoindan, 97% 10GR

5-AMinoindan 95%

5-AMINOINDAN

5-AMINOINDANE

5-AMINOHYDRINDENE

5-INDANAMINE

AKOS 91137

3-dihydro-1H-inden-5-amine

5-Aminoindan &gt

indan-5-ylamine

24425-40-9

24425040-9

Amines

Building Blocks

Nitrogen Compounds

Organic Building Blocks

C9 to C10

Indane/Indanone and Derivatives