3-Buten-1-ol
Description- Product Name
- 3-Buten-1-ol
- CAS No.
- 627-27-0
- Chemical Name
- 3-Buten-1-ol
- Synonyms
- 3-Butenol;3-BUTENE-1-OL;3-Butenyl alcohol;Homoallyl alcohol;NSC 60194;3-Buten-1-O1;3-buten-1-0l;1-Buten-4-ol;3-BUTEN-1-OL;3-butene-1-0l
- CBNumber
- CB1172076
- Molecular Formula
- C4H8O
- Formula Weight
- 72.11
- MOL File
- 627-27-0.mol
3-Buten-1-ol Property
- Melting point:
- -31.44°C (estimate)
- Boiling point:
- 112-114 °C (lit.)
- Density
- 0.838 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.421(lit.)
- Flash point:
- 90 °F
- storage temp.
- Sealed in dry,Store in freezer, under -20°C
- solubility
- soluble in Chloroform, Methanol
- pka
- 15.04±0.10(Predicted)
- form
- Liquid
- color
- Clear colorless to slightly yellow
- Specific Gravity
- 0.843
- explosive limit
- 2-28%(V)
- Water Solubility
- SOLUBLE
- BRN
- 1633504
- Stability:
- Stable. Incompatible with acids, acid chlorides, acid anhydrides, oxidizing agents. Flammable.
- InChIKey
- ZSPTYLOMNJNZNG-UHFFFAOYSA-N
- LogP
- 0.679 (est)
- CAS DataBase Reference
- 627-27-0(CAS DataBase Reference)
- NIST Chemistry Reference
- 3-Buten-1-ol(627-27-0)
- EPA Substance Registry System
- 3-Buten-1-ol (627-27-0)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 10-36/37/38
- Safety Statements
- 16-26-36
- RIDADR
- UN 1987 3/PG 3
- WGK Germany
- 3
- TSCA
- Yes
- HazardClass
- 3
- PackingGroup
- II
- HS Code
- 29052990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H226Flammable liquid and vapour
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233Keep container tightly closed.
P240Ground/bond container and receiving equipment.
P241Use explosion-proof electrical/ventilating/lighting/…/equipment.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 19170
- Product name
- 3-Buten-1-ol
- Purity
- purum, ≥98.0% (GC)
- Packaging
- 25ml
- Price
- $154
- Updated
- 2024/03/01
- Product number
- 19170
- Product name
- 3-Buten-1-ol
- Purity
- purum, ≥98.0% (GC)
- Packaging
- 5ml
- Price
- $62.1
- Updated
- 2023/06/20
- Product number
- B0236
- Product name
- 3-Buten-1-ol
- Purity
- >98.0%(GC)
- Packaging
- 10mL
- Price
- $48
- Updated
- 2024/03/01
- Product number
- B0236
- Product name
- 3-Buten-1-ol
- Purity
- >98.0%(GC)
- Packaging
- 25mL
- Price
- $82
- Updated
- 2024/03/01
- Product number
- L00767
- Product name
- 3-Buten-1-ol, 98+%
- Packaging
- 5g
- Price
- $33.65
- Updated
- 2024/03/01
3-Buten-1-ol Chemical Properties,Usage,Production
Description
3-Buten-1-ol(627-27-0) is a homoallyl alcohol. It is employed in a study of the Mn-catalyzed hydrohydrazination of olefins. It is also used in a study of the conversion of propargylic acetates to ethers catalyzed by ferric chloride1. It can also be used as a starting reagent in asymmetric total synthesis of natural seimatopolide B. It was also used in the synthesis of catalytic bimetallic nanoparticles2.
Chemical Properties
liquid
Uses
3-Buten-1-ol is an aliphatic primary alcohol used as a reagent in organic synthesis.
Uses
3-Buten-1-ol is employed in a study of the Mn-catalyzed hydrohydrazination of olefins. Also used in a study of the conversion of propargylic acetates to ethers catalyzed by ferric chloride.
Uses
Employed in a study of the Mn-catalyzed hydrohydrazination of olefins. Also used in a study of the conversion of propargylic acetates to ethers cataylzed by ferric chloride.
Definition
ChEBI: 3-Buten-1-ol is a primary alcohol.
General Description
3-Buten-1-ol is a homoallyl alcohol that can be prepared by the dehydration of 1,4-butanediol using cerium catalyst. The intramolecular hydrogen bonding of 3-buten-1-ol has been studied using FT-IR and 1H NMR spectroscopic data. Its microwave spectrum has been recorded and analyzed. The alkylation reaction of 3-buten-1-ol using titanium-organoaluminum system has been studied. Its gas-phase enthalpy of formation has been reported to be -147.3 ± 1.8kJ mol-1.
Hazard
3-Buten-1-ol is strongly irritating to the skin and eyes. it may cause respiratory irritation. it is toxic to aquatic organisms and has long lasting effects.
Synthesis
The synthesis of 3-Buten-1-ol is as follows:After adding 24.3 g (1 mol) of magnesium turnings, 50 g of diethyl ether and 1 ml of dibromoethane in a 500 mL four-necked flask,A solution of 62.5 g of vinyl chloride (1 mol) dissolved in 200 g of diethyl ether was added dropwise to magnesium and diethyl ether, and the micro reflux was controlled, and the dropwise addition was completed, and the mixture was kept under a micro reflux for 2 hours, and the temperature was lowered to -5 °C;Then 44 g (1 mol) of ethylene oxide was dissolved in 60 g of diethyl ether. Ethylene oxide is added dropwise to the vinylmagnesium chloride solution prepared above, control the temperature -5-5 degrees, and stir at this temperature for 1 hour. Sampling gas phase analysis until the reaction is complete; pour the reaction solution into a 1000 mL beaker, Add 200mL of ice water and add ammonium chloride until the residual magnesium disappears. Control the temperature 0-10 ° C, stir for 1 hour after the addition, add salt to saturation, static layering. The organic layer was separated and washed twice with 100 ml of saturated brine, and a polymerization inhibitor was added. The product is subjected to rectification to obtain 53 g of 3-buten-1-ol, and the content is 99.2%. The yield was 73.6%.
3-Buten-1-ol Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 3-Buten-1-ol manufacturers
- Product
- 3-Buten-1-ol 627-27-0
- Price
- US $280.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 10t
- Release date
- 2023-07-21
- Product
- 3-Buten-1-ol 627-27-0
- Price
- US $100.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-24
- Product
- 3-Buten-1-ol 627-27-0
- Price
- US $10.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 5000 Ton
- Release date
- 2023-01-11