ChemicalBook > CAS DataBase List > METHOXYCARBONYLSULFENYL CHLORIDE

METHOXYCARBONYLSULFENYL CHLORIDE

Product Name: METHOXYCARBONYLSULFENYL CHLORIDE
CAS No.: 26555-40-8
Chemical Name: METHOXYCARBONYLSULFENYL CHLORIDE
Synonyms: methylchlorosulfanylformate;Methoxycarbonylthio chloride;S-CHLORO O-METHYL THIOCARBONATE;5-CHLORO O-METHYL THIOCARBONATE;METHOXYCARBONYLSULFENYL CHLORIDE;METHOXYCARBONYLSULPHENYL CHLORIDE;MethoxycarbonylsulfenylChloride>(Chlorosulfanyl)(methoxy)oxomethane;Methoxycarbonylsulfenylchloride,95%;Methoxycarbonylsulfenyl chloride,97%
CBNumber: CB1179484
Molecular Formula: C2H3ClO2S
Formula Weight: 126.56
MOL File: 26555-40-8.mol

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METHOXYCARBONYLSULFENYL CHLORIDE Property

Boiling point:: 133-134 °C(lit.)
Density: 1.399 g/mL at 25 °C(lit.)
refractive index: n20/D 1.481(lit.)
Flash point:: 130 °F
storage temp.: 2-8°C
solubility: Miscible with dichlormethane.
form: Liquid
Specific Gravity: 1.399
color: Clear bright yellow
Sensitive: Moisture Sensitive
BRN: 1849908
InChIKey: TXJXPZVVSLAQOQ-UHFFFAOYSA-N
CAS DataBase Reference: 26555-40-8(CAS DataBase Reference)

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Safety

Hazard Codes: C
Risk Statements: 10-34
Safety Statements: 26-36/37/39-45
RIDADR: UN 2920 8/PG 2
WGK Germany: 3
F: 10-21
HazardClass: 8
PackingGroup: II
HS Code: 29309099

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H226Flammable liquid and vapour

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 359408
Product name: Methoxycarbonylsulfenyl chloride
Purity: 97%
Packaging: 5ml
Price: $356
Updated: 2023/01/07

Sigma-Aldrich

Product number: 359408
Product name: Methoxycarbonylsulfenyl chloride
Purity: 97%
Packaging: 1ml
Price: $87.2
Updated: 2022/05/15

TCI Chemical

Product number: M0979
Product name: Methoxycarbonylsulfenyl Chloride
Purity: >96.0%(T)
Packaging: 5g
Price: $112
Updated: 2025/07/31

TCI Chemical

Product number: M0979
Product name: Methoxycarbonylsulfenyl Chloride
Purity: >96.0%(T)
Packaging: 25g
Price: $520
Updated: 2025/07/31

TRC

Product number: M220610
Product name: Methoxycarbonylsulfenyl chloride
Packaging: 500mg
Price: $110
Updated: 2021/12/16

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METHOXYCARBONYLSULFENYL CHLORIDE Chemical Properties,Usage,Production

Chemical Properties

CLEAR BRIGHT YELLOW LIQUID

Uses

Methoxycarbonylsulfenyl chloride is used to prepare 3-[(methoxycarbonyl)dithio]-L-alanine by reacting with L-cysteine. Further, it is used in the synthesis of 3-2 pyridinyldithio propanoic acid hydrazide (PDPH). It serves as an important heterobifunctional crosslinker, which is a crosslinker used to make macromolecule-drug conjugates.

Uses

Methoxycarbonylsulfenyl chloride may be used to prepare 3-[(methoxycarbonyl)dithio]-L-alanine, via reaction with L-cysteine. It is suitable for use in the synthesis of 3-2 pyridinyldithio propanoic acid hydrazide (PDPH), an important heterobifunctional crosslinker widely used in bioconjugate techniques for making macromolecule-drug conjugates.

General Description

Methoxycarbonylsulfenyl chloride is a sulfenyl carbonyl compound. Photoinduced fragmentations of methoxycarbonylsulfenyl chloride is investigated in the gaseous phase by using synchrotron radiation and multicoincidence techniques. The molecular structure and conformational properties of methoxycarbonylsulfenyl chloride is studied in the gas and solid phases by gas electron diffraction, low-temperature X-ray diffraction and vibrational spectroscopy. The anomeric and mesomeric effects in methoxycarbonylsulfenyl chloride is reported.

METHOXYCARBONYLSULFENYL CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHOXYCARBONYLSULFENYL CHLORIDE Suppliers

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View Lastest Price from METHOXYCARBONYLSULFENYL CHLORIDE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: METHOXYCARBONYLSULFENYL CHLORIDE 26555-40-8
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

26555-40-8, METHOXYCARBONYLSULFENYL CHLORIDERelated Search:

Potassium chloride Nickle chloride Magnesium chloride Lithium chloride Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) Palladium chloride Choline chloride CERIUM(III) CHLORIDE HEPTAHYDRATE Zinc chloride Lithium chloride monohydrate Allylpalladium(II) Chloride Dimer Sodium chloride Calcium chloride Lanthanum(III) chloride Bismuth trichloride CARBONYL SULFIDE METHOXYCARBONYLSULFENYL CHLORIDE

S-CHLORO O-METHYL THIOCARBONATE

(Chlorothio)formic acid methyl ester

(Chlorothio)methanoic acid methyl ester

Methoxycarbonylthio chloride

Methoxycarbonylsulfenyl chloride,97%

METHOXYCARBONYLSULFENYL CHLORIDE

METHOXYCARBONYLSULPHENYL CHLORIDE

5-CHLORO O-METHYL THIOCARBONATE

thiocarbonic acid, anhydrosulphide with methyl thiohypochlorite

Methoxycarbonylsulfenylchloride,95%

(Chlorosulfanyl)(methoxy)oxomethane

Carbonothioic acid, anhydrosulfide with thiohypochlorous acid, methyl ester

1-methyl-4-imidazolesulfonic acid [4-[[2-[2-(4-aminophenyl)ethyl]-6-hydroxy-4-oxo-2-propan-2-yl-3H-pyran-5-yl]thio]-5-tert-butyl-2-methylphenyl] ester

MethoxycarbonylsulfenylChloride&gt

Carbonothioic acid, anhydrosulfide with thiohypochlorous acid (1:1), methyl ester

methylchlorosulfanylformate

Hypochlorous (methyl carbonic) thioanhydride

thiocarbonic acid, anhydrosulphide with methyl thiohypochlor...

26555-40-8

C2H3ClO2S

CH3OCOSCl

Building Blocks

Sulfur Compounds (for Synthesis)

Protection & Derivatization Reagents (for Synthesis)

Organic Building Blocks

Sulfur Compounds

Sulfenyl Halides

Protection & Derivatization Reagents (for Synthesis)

Sulfur Compounds (for Synthesis)

Synthetic Organic Chemistry