ChemicalBook > CAS DataBase List > METHOXYCARBONYLSULFENYL CHLORIDE

METHOXYCARBONYLSULFENYL CHLORIDE

Product Name
METHOXYCARBONYLSULFENYL CHLORIDE
CAS No.
26555-40-8
Chemical Name
METHOXYCARBONYLSULFENYL CHLORIDE
Synonyms
methylchlorosulfanylformate;Methoxycarbonylthio chloride;S-CHLORO O-METHYL THIOCARBONATE;5-CHLORO O-METHYL THIOCARBONATE;METHOXYCARBONYLSULFENYL CHLORIDE;METHOXYCARBONYLSULPHENYL CHLORIDE;MethoxycarbonylsulfenylChloride>(Chlorosulfanyl)(methoxy)oxomethane;Methoxycarbonylsulfenylchloride,95%;Methoxycarbonylsulfenyl chloride,97%
CBNumber
CB1179484
Molecular Formula
C2H3ClO2S
Formula Weight
126.56
MOL File
26555-40-8.mol
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METHOXYCARBONYLSULFENYL CHLORIDE Property

Boiling point:
133-134 °C(lit.)
Density 
1.399 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.481(lit.)
Flash point:
130 °F
storage temp. 
2-8°C
solubility 
Miscible with dichlormethane.
form 
Liquid
Specific Gravity
1.399
color 
Clear bright yellow
Sensitive 
Moisture Sensitive
BRN 
1849908
InChIKey
TXJXPZVVSLAQOQ-UHFFFAOYSA-N
CAS DataBase Reference
26555-40-8(CAS DataBase Reference)
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Safety

Hazard Codes 
C
Risk Statements 
10-34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 2920 8/PG 2
WGK Germany 
3
F 
10-21
HazardClass 
8
PackingGroup 
II
HS Code 
29309099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H226Flammable liquid and vapour

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
359408
Product name
Methoxycarbonylsulfenyl chloride
Purity
97%
Packaging
5ml
Price
$356
Updated
2023/01/07
Sigma-Aldrich
Product number
359408
Product name
Methoxycarbonylsulfenyl chloride
Purity
97%
Packaging
1ml
Price
$87.2
Updated
2022/05/15
TCI Chemical
Product number
M0979
Product name
Methoxycarbonylsulfenyl Chloride
Purity
>96.0%(T)
Packaging
5g
Price
$112
Updated
2024/03/01
TCI Chemical
Product number
M0979
Product name
Methoxycarbonylsulfenyl Chloride
Purity
>96.0%(T)
Packaging
25g
Price
$520
Updated
2024/03/01
Alfa Aesar
Product number
L04350
Product name
Methoxycarbonylsulfenyl chloride, 95%
Packaging
1g
Price
$51.65
Updated
2024/03/01
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METHOXYCARBONYLSULFENYL CHLORIDE Chemical Properties,Usage,Production

Chemical Properties

CLEAR BRIGHT YELLOW LIQUID

Uses

Methoxycarbonylsulfenyl chloride is used to prepare 3-[(methoxycarbonyl)dithio]-L-alanine by reacting with L-cysteine. Further, it is used in the synthesis of 3-2 pyridinyldithio propanoic acid hydrazide (PDPH). It serves as an important heterobifunctional crosslinker, which is a crosslinker used to make macromolecule-drug conjugates.

Uses

Methoxycarbonylsulfenyl chloride may be used to prepare 3-[(methoxycarbonyl)dithio]-L-alanine, via reaction with L-cysteine. It is suitable for use in the synthesis of 3-2 pyridinyldithio propanoic acid hydrazide (PDPH), an important heterobifunctional crosslinker widely used in bioconjugate techniques for making macromolecule-drug conjugates.

General Description

Methoxycarbonylsulfenyl chloride is a sulfenyl carbonyl compound. Photoinduced fragmentations of methoxycarbonylsulfenyl chloride is investigated in the gaseous phase by using synchrotron radiation and multicoincidence techniques. The molecular structure and conformational properties of methoxycarbonylsulfenyl chloride is studied in the gas and solid phases by gas electron diffraction, low-temperature X-ray diffraction and vibrational spectroscopy. The anomeric and mesomeric effects in methoxycarbonylsulfenyl chloride is reported.

METHOXYCARBONYLSULFENYL CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHOXYCARBONYLSULFENYL CHLORIDE Suppliers

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View Lastest Price from METHOXYCARBONYLSULFENYL CHLORIDE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
METHOXYCARBONYLSULFENYL CHLORIDE 26555-40-8
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11

26555-40-8, METHOXYCARBONYLSULFENYL CHLORIDERelated Search:

Magnesium chloride Lithium chloride Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) Potassium chloride Palladium chloride Choline chloride CERIUM(III) CHLORIDE HEPTAHYDRATE Zinc chloride Lithium chloride monohydrate Allylpalladium(II) Chloride Dimer Sodium chloride Calcium chloride Lanthanum(III) chloride Bismuth trichloride Nickel chloride CARBONYL SULFIDE METHOXYCARBONYLSULFENYL CHLORIDE

  • S-CHLORO O-METHYL THIOCARBONATE
  • (Chlorothio)formic acid methyl ester
  • (Chlorothio)methanoic acid methyl ester
  • Methoxycarbonylthio chloride
  • Methoxycarbonylsulfenyl chloride,97%
  • METHOXYCARBONYLSULFENYL CHLORIDE
  • METHOXYCARBONYLSULPHENYL CHLORIDE
  • 5-CHLORO O-METHYL THIOCARBONATE
  • thiocarbonic acid, anhydrosulphide with methyl thiohypochlorite
  • Methoxycarbonylsulfenylchloride,95%
  • (Chlorosulfanyl)(methoxy)oxomethane
  • Carbonothioic acid, anhydrosulfide with thiohypochlorous acid, methyl ester
  • 1-methyl-4-imidazolesulfonic acid [4-[[2-[2-(4-aminophenyl)ethyl]-6-hydroxy-4-oxo-2-propan-2-yl-3H-pyran-5-yl]thio]-5-tert-butyl-2-methylphenyl] ester
  • MethoxycarbonylsulfenylChloride&gt
  • Carbonothioic acid, anhydrosulfide with thiohypochlorous acid (1:1), methyl ester
  • methylchlorosulfanylformate
  • Hypochlorous (methyl carbonic) thioanhydride
  • thiocarbonic acid, anhydrosulphide with methyl thiohypochlor...
  • 26555-40-8
  • C2H3ClO2S
  • CH3OCOSCl
  • Building Blocks
  • Sulfur Compounds (for Synthesis)
  • Protection & Derivatization Reagents (for Synthesis)
  • Organic Building Blocks
  • Sulfur Compounds
  • Sulfenyl Halides
  • Protection & Derivatization Reagents (for Synthesis)
  • Sulfur Compounds (for Synthesis)
  • Synthetic Organic Chemistry