Furaneol
- Product Name
- Furaneol
- CAS No.
- 3658-77-3
- Chemical Name
- Furaneol
- Synonyms
- 4-HYDROXY-2,5-DIMETHYL-3(2H)-FURANONE;2,5-DIMETHYL-4-HYDROXY-3(2H)-FURANONE;HDMF;STRAWBERRY FURANONE;4-HYDROXY-2,5-DIMETHYLFURAN-3(2H)-ONE;Furaneo;Pineapple ketone;2,5-dimethyl-4-hydroxy-2H-furan-3-one;2,5-dimethyl-4-hydroxy-3(2H)-furanone (Furaneol);CARMELAN
- CBNumber
- CB1205015
- Molecular Formula
- C6H8O3
- Formula Weight
- 128.13
- MOL File
- 3658-77-3.mol
Furaneol Property
- Melting point:
- 73-77 °C(lit.)
- Boiling point:
- 188 °C
- Density
- 1.049 g/mL at 25 °C
- vapor pressure
- 0.81Pa at 25℃
- refractive index
- n20/D 1.439
- FEMA
- 3174 | 4-HYDROXY-2,5-DIMETHYL-3(2H)-FURANONE
- Flash point:
- >230 °F
- storage temp.
- 2-8°C
- solubility
- Chloroform (Slightly), Methanol (Slightly)
- pka
- 9.62±0.40(Predicted)
- form
- Solid
- color
- White
- Odor
- at 1.00 % in propylene glycol. sweet cotton candy caramel strawberry sugar
- Odor Type
- caramellic
- Water Solubility
- 176g/L at 20℃
- JECFA Number
- 1446
- BRN
- 1281357
- Stability:
- Light Sensitive, Temperature Sensitive
- InChIKey
- INAXVXBDKKUCGI-UHFFFAOYSA-N
- LogP
- 0.95 at 20℃
- CAS DataBase Reference
- 3658-77-3(CAS DataBase Reference)
- NIST Chemistry Reference
- 2,5-Dimethyl-4-hydroxy-3(2h)-furanone(3658-77-3)
- EPA Substance Registry System
- 4-Hydroxy-2,5-dimethyl-3(2H)furanone (3658-77-3)
Safety
- Hazard Codes
- Xn
- Risk Statements
- 22
- Safety Statements
- 36-24/25
- WGK Germany
- 3
- RTECS
- LU3990000
- F
- 10-23
- HS Code
- 29321900
- Hazardous Substances Data
- 3658-77-3(Hazardous Substances Data)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H302Harmful if swallowed
H314Causes severe skin burns and eye damage
H317May cause an allergic skin reaction
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P270Do not eat, drink or smoke when using this product.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- W317454
- Product name
- 4-Hydroxy-2,5-dimethyl-3(2H)-furanone
- Purity
- natural, ≥98%, FG
- Packaging
- 100g
- Price
- $223
- Updated
- 2024/03/01
- Product number
- W317454
- Product name
- 4-Hydroxy-2,5-dimethyl-3(2H)-furanone
- Purity
- natural, ≥98%, FG
- Packaging
- 1kg
- Price
- $1200
- Updated
- 2024/03/01
- Product number
- W317403
- Product name
- 4-Hydroxy-2,5-dimethyl-3(2H)-furanone
- Purity
- ≥98%, FCC, FG
- Packaging
- 100g
- Price
- $130
- Updated
- 2024/03/01
- Product number
- W317403
- Product name
- 4-Hydroxy-2,5-dimethyl-3(2H)-furanone
- Purity
- ≥98%, FCC, FG
- Packaging
- 1kg
- Price
- $787
- Updated
- 2024/03/01
- Product number
- 44869
- Product name
- 4-Hydroxy-2,5-dimethyl-3(2H)-furanone
- Purity
- analytical standard
- Packaging
- 100mg
- Price
- $175
- Updated
- 2024/03/01
Furaneol Chemical Properties,Usage,Production
Description
Furaneol is a very important aroma chemical and is a key flavoring compound found in many kinds of fruits. It can be chemically formed through different carbohydrates during the Mainlard reaction. It can also be synthesized by yeast, bacteria and plants and play some physiological effects. Study has shown that it can suppress the phosphorylation of cAMP response element binding protein, underlying its potential role as an effective inhibitor of hyperpigmentation. It also has the potential to become an effective antimicrobial agent for human beings.
Chemical Properties
Furaneol is a constituent of pineapple and strawberry aroma and is also found in other foods. It forms colorless crystals (mp 77–79°C) with a relatively weak, nonspecific odor. Dilute solutions develop a pineapple, strawberrylike odor.
Chemical Properties
Furaneol has a sweet, fruity, strawberry, hot sugar, fruity caramel or “burnt pineapple” aroma.
Chemical Properties
white to light yellow crystal powde
Chemical Properties
4-Hydroxy-2,5-dimethyl-3(2H)-furanone has a fruity caramel or "burnt pineapple" aroma. May be synthesized from dimethyl- 3,4-dihyroxyfuran-2,5-dicarboxylate.
Occurrence
Reported found in guava, grapes, pineapple, raspberry, strawberry fruit and jam, rye bread, Swiss cheese, boiled beef, beer, cocoa, coffee, tea, filberts, almonds, oatmeal, Arctic bramble, yellow passion fruit, mango, shoyu, fermented soy sauce, litchi, malt and Cape gooseberry.
Uses
2,5-Dimethyl-4-hydroxy-3(2H)-furanone is a component of meat essence composition. 2,5-Dimethyl-4-hydroxy-3(2H)-furanone is used in the flavor and perfume industry due to its sweet strawberry aroma.
Preparation
Furaneol can be prepared by cyclization of hexane-2,5-diol-3,4-dione in the presence of an acidic catalyst.The dione is the ozonization product of 2,5- hexynediol, which is obtained by ethynylation of acetaldehyde.
In another process, a dialkyl ??-methyldiglycolate (formed from an alkyl lactate and an alkyl monochloroacetate) is reacted with dialkyl oxalate in the presence of a sodium alkoxide and dimethylformamide. The reaction product is cyclized, alkylated, hydrolyzed, and decarboxylated.In another process, a dialkyl ??-methyldiglycolate (formed from an alkyl lactate and an alkyl monochloroacetate) is reacted with dialkyl oxalate in the presence of a sodium alkoxide and dimethylformamide. The reaction product is cyclized, alkylated, hydrolyzed, and decarboxylated .
Definition
ChEBI: A member of the class of furans that is 2,5-dimethylfuran carrying additional oxo and hydroxy groups at positions 3 and 4 respectively. It has been found particularly in strawberries and other such fruits.
Aroma threshold values
Detection: 0.03 to 60 ppb; aroma characteristics at 0.1%: sweet, slightly burnt brown caramellic, cotton candy with a savory nuance
Taste threshold values
Taste characteristics at 0.10 to 1.0 ppm: sweet caramellic cooked meaty and fruity nuances
Synthesis Reference(s)
The Journal of Organic Chemistry, 57, p. 5023, 1992 DOI: 10.1021/jo00044a047
Synthesis, p. 377, 1987
General Description
4-Hydroxy-2,5-dimethyl-3(2H)-furanone (HDMF, DMHF) is a caramel-like smelling compound, identified in Maillard reaction systems based on pentoses by GC-MS and GCMS/MS. Solubility data of DMHF in six different solvents over the temperature range from 283.15K to 313.15K under atmospheric pressure of 0.10 MPa has been examined by dynamic method. Separation of the enantiomers of DMHF by capillary electrophoretic method has been reported. Commercially it is synthesized from L-rhamnose. DMHF has been identified as acidic odorant in Thai premium fish sauce samples by aroma extract dilution analysis (AEDA). It is identified as key aroma compound in the distiller′s grains (DG) from wheat. It is reported as the main flavor compound in strawberries and its biosynthesis has been reported. HDMF has been found in various fruits such as pineapples strawberries and grapes, as well as in beef broth , roasted coffee, bread crust, roasted beef, roasted sesame seeds and stewed beef.
Flammability and Explosibility
Not classified
Trade name
Furaneol® (Firmenich).
Biochem/physiol Actions
Taste at 0.10 to 1.0 ppm
Synthesis
From dimethyl-3,4-dihydroxyfuran-2,5-dicarboxylate
References
Pickenhagen, Wilhelm, et al. "Estimation of 2,5-dimethyl-4-hydroxy-3(2H)-furanone (FURANEOLA®) in cultivated and wild strawberries, pineapples and mangoes." Journal of the Science of Food & Agriculture 32.11(2010):1132-1134.
Farine, Jean Pierre, et al. "4-Hydroxy-5-methyl-3(2H)-furanone and 4-Hydroxy-2,5-dimethyl-3(2H)-furanone, Two Components of the Male Sex Pheromone of Eurycotis floridana (Walker) (Insecta, Blattidae, Polyzosteriinae)." Bioscience Biotechnology & Biochemistry 57.12(2014):2026-2030.
Schwab, W. "Natural 4-hydroxy-2,5-dimethyl-3(2H)-furanone (Furaneol®). " Molecules 18.6(2013):6936-51.
Furaneol Preparation Products And Raw materials
Raw materials
Preparation Products
Furaneol Suppliers
- Tel
- 0632-5953999 13906375582
- 13906375582@139.com
- Country
- China
- ProdList
- 1
- Advantage
- 58
- Tel
- 15063396929; 15063396929
- 978101703@qq.com
- Country
- China
- ProdList
- 59
- Advantage
- 58
- Tel
- 022-83946278 13820503911
- Fax
- 022-83945176
- sales@creasyn.com
- Country
- China
- ProdList
- 993
- Advantage
- 68
- Tel
- 010-82848833 400-666-7788
- Fax
- 86-10-82849933
- jkinfo@jkchemical.com
- Country
- China
- ProdList
- 96815
- Advantage
- 76
- Tel
- 400-0066400 13621662912
- Fax
- 021-55660885
- sales@jonln.com
- Country
- China
- ProdList
- 1995
- Advantage
- 65
- Tel
- 021-67121386
- Fax
- 021-67121385
- Sales-CN@TCIchemicals.com
- Country
- China
- ProdList
- 24529
- Advantage
- 81
- Tel
- 021-021-58432009 400-005-6266
- Fax
- 021-58436166
- sales8178@energy-chemical.com
- Country
- China
- ProdList
- 44688
- Advantage
- 61
- Tel
- +86 (0) 571 85 58 67 18
- Fax
- 0086-571-85864795
- sales@capotchem.com
- Country
- China
- ProdList
- 18207
- Advantage
- 66
- Tel
- 021-58099652-8005 13585536065
- Fax
- 021-58099609
- bin.wu@shlschem.com
- Country
- China
- ProdList
- 9810
- Advantage
- 59
- Tel
- 021-54306202 13764082696
- info@hanhongsci.com
- Country
- China
- ProdList
- 42958
- Advantage
- 64
- Tel
- 21-62165282 15801962796;
- Fax
- 021 61153784
- bidingchem@163.com
- Country
- China
- ProdList
- 1199
- Advantage
- 60
- Tel
- 15527768850
- 1791901229@qq.com
- Country
- China
- ProdList
- 8836
- Advantage
- 52
- Tel
- 4009903999 13355009207
- Fax
- 0539-6365991
- 3007715519@qq.com
- Country
- China
- ProdList
- 18738
- Advantage
- 57
- Tel
- Fax
- E-Mail Inquiry
- info@syntechem.com
- Country
- China
- ProdList
- 12984
- Advantage
- 57
- Tel
- 400-1166-196 18981987031
- Fax
- 028-84555506 800101999
- cdhxsj@163.com
- Country
- China
- ProdList
- 11707
- Advantage
- 57
- Tel
- 0571-82693216
- Fax
- +86-571-82880190
- info@yuhaochemical.com
- Country
- China
- ProdList
- 9387
- Advantage
- 52
- Tel
- 021-33690831-8001 13552411790
- Fax
- 021-33690831
- postmaster@tyjchem.cn
- Country
- China
- ProdList
- 1541
- Advantage
- 55
- Tel
- 021-61312847 13636370518
- Fax
- 021-55068248
- shyysw007@163.com
- Country
- China
- ProdList
- 4940
- Advantage
- 60
- Tel
- 021-61551611 13296011611
- Fax
- ＋86 21-50676805
- contact@trustwe.com
- Country
- China
- ProdList
- 9895
- Advantage
- 58
- Tel
- 0532-83893697 18561902820
- Fax
- 83893695
- sissili@unitedint.com
- Country
- China
- ProdList
- 352
- Advantage
- 58
- Tel
- 86-21-34053660
- Fax
- 86-21-34053661
- sale@labgogo.com
- Country
- China
- ProdList
- 9865
- Advantage
- 52
- Tel
- 025-66099280 17798518460
- Fax
- (1)02557626880
- cfzhang@aikonchem.com
- Country
- China
- ProdList
- 19915
- Advantage
- 55
- Tel
- 4009209199
- Fax
- 86-021-52271987
- sales@9dingchem.com
- Country
- China
- ProdList
- 22514
- Advantage
- 55
- Tel
- 400-400-6206333 18521732826
- Fax
- 021-50323701
- market@aladdin-e.com
- Country
- China
- ProdList
- 25003
- Advantage
- 65
- Tel
- 021-61552785
- Fax
- 021-55660885
- sales@shshiji.com
- Country
- China
- ProdList
- 9545
- Advantage
- 55
- Tel
- 021-62960152
- Fax
- 021-52212593
- 934678158@qq.com
- Country
- China
- ProdList
- 9899
- Advantage
- 55
- Tel
- +86-28-85122536 85324413
- Fax
- +86-28-85326443
- market@astatech.cn
- Country
- China
- ProdList
- 8026
- Advantage
- 55
- Tel
- 86-13605431940 13605431940
- Fax
- 0086-0543-2240079
- zpmxchemical@126.com
- Country
- China
- ProdList
- 1401
- Advantage
- 62
- Tel
- 021-021-33632979 15002134094
- Fax
- 021-33632979
- marketing@targetmol.com
- Country
- China
- ProdList
- 7783
- Advantage
- 58
- Tel
- 400-0066400 13621662912
- Fax
- 021-55660885
- 422131432@qq.com
- Country
- China
- ProdList
- 9978
- Advantage
- 55
- Tel
- 400-164-7117 13681763483
- Fax
- +86-21-61629029
- product02@bidepharm.com
- Country
- China
- ProdList
- 41462
- Advantage
- 60
- Tel
- 021-54359730 400-008-9730
- Fax
- 021-54353864
- info@chemxyz.com
- Country
- China
- ProdList
- 3991
- Advantage
- 60
- Tel
- 0371-13526885213 15637198702
- Fax
- 0371-63709726
- xpkchem@163.com
- Country
- China
- ProdList
- 3978
- Advantage
- 58
- Tel
- 15523000485
- xingcanyaoye@sina.com
- Country
- China
- ProdList
- 1687
- Advantage
- 58
- Tel
- 400-1166-196 13458535857
- Fax
- QQ：800101999
- cdhxsj@163.com
- Country
- China
- ProdList
- 13350
- Advantage
- 58
- Tel
- 400-821-5857 021-64326257
- Fax
- 021-64393586 QQ;2798200800
- credit-chem@foxmail.com
- Country
- China
- ProdList
- 5219
- Advantage
- 58
- Tel
- 021-60345187 13671753212
- Fax
- 021-34702061
- lzz841106@aliyun.com
- Country
- China
- ProdList
- 10274
- Advantage
- 55
- Tel
- 17501653715
- xingui2022@126.com
- Country
- China
- ProdList
- 10015
- Advantage
- 58
- Tel
- 15221275939 15221275939
- Fax
- 021-50706099
- shenlinxing@macklin.cn
- Country
- China
- ProdList
- 16166
- Advantage
- 55
- Tel
- 0571-+86-571-87396432
- Fax
- 0571-87396431
- sales@jhechem.com
- Country
- China
- ProdList
- 11578
- Advantage
- 59
- Tel
- 021-61478794
- Fax
- 021-61478794
- sales@hcshhai.com
- Country
- China
- ProdList
- 9793
- Advantage
- 50
- Tel
- 18905173768
- Fax
- 025-83263139
- sales@dolonchem.com
- Country
- China
- ProdList
- 2331
- Advantage
- 50
- Tel
- +86 (21) 61124340
- Fax
- +86 (21) 6129-4103
- Country
- China
- ProdList
- 9756
- Advantage
- 58
- Tel
- 027-59599241 18871490274
- Fax
- 027-59599241
- 1400878000@qq.com
- Country
- China
- ProdList
- 9958
- Advantage
- 58
- Tel
- 0731-85118349 18874718518
- Fax
- 0731-85118349
- ma_haihong@sina.com
- Country
- China
- ProdList
- 1595
- Advantage
- 50
- Tel
- 021-61415566 800-8193336
- orderCN@merckgroup.com
- Country
- China
- ProdList
- 51456
- Advantage
- 80
- Tel
- 86(21)68097365
- Fax
- 86(21)33321566
- sales@anpharma.net
- Country
- China
- ProdList
- 4891
- Advantage
- 55
- Tel
- 027-59207879 1972026995 18140587686
- Fax
- QQ：1972026995
- sales@3600chem.com
- Country
- China
- ProdList
- 4660
- Advantage
- 55
- Tel
- 0531-88817695
- Fax
- 0531-88817695
- Country
- China
- ProdList
- 423
- Advantage
- 68
- Tel
- 18620099427
- Fax
- +86-20-62619665
- amy@howeipharm.com
- Country
- China
- ProdList
- 17687
- Advantage
- 55
View Lastest Price from Furaneol manufacturers
- Product
- Strawberry Flavor Furanone 3658-77-3
- Price
- US $120.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20ton
- Release date
- 2024-05-15
- Product
- Furaneol 3658-77-3
- Price
- US $76.00/KG
- Min. Order
- 25KG
- Purity
- 98%
- Supply Ability
- 1-10mt
- Release date
- 2021-06-02
- Product
- Furaneol 3658-77-3
- Price
- US $0.00/Kg/Drum
- Min. Order
- 1KG
- Purity
- 99%min
- Supply Ability
- 1000KGS
- Release date
- 2021-08-13