ETHYL ANTHRANILATE
- Product Name
- ETHYL ANTHRANILATE
- CAS No.
- 87-25-2
- Chemical Name
- ETHYL ANTHRANILATE
- Synonyms
- ETHYL 2-AMINOBENZOATE;ethyl-o-amino;o-(Ethoxycarbonyl)aniline;FEMA 2421;Ethylanthranilat;ETHYL ANTHRANILATE;2-carboethoxyaniline;ETHYL O-AMINOBENZOATE;Ethylanthranilate,98+%;Anthranilic acid ethyl
- CBNumber
- CB1221396
- Molecular Formula
- C9H11NO2
- Formula Weight
- 165.19
- MOL File
- 87-25-2.mol
ETHYL ANTHRANILATE Property
- Melting point:
- 13-15 °C (lit.)
- Boiling point:
- 129-130 °C/9 mmHg (lit.)
- Density
- 1.117 g/mL at 25 °C (lit.)
- vapor density
- 5.7 (vs air)
- refractive index
- n20/D 1.564(lit.)
- FEMA
- 2421 | ETHYL ANTHRANILATE
- Flash point:
- >230 °F
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- solubility
- Insoluble in water but soluble in organic solvents
- pka
- 2.20±0.10(Predicted)
- form
- Clear liquid
- color
- Light yellow
- Specific Gravity
- 1.1170
- Odor
- at 100.00 %. sweet floral grape orangeblossom wintergreen
- Odor Type
- floral
- JECFA Number
- 1535
- BRN
- 878874
- Stability:
- Stable. Combustible. Incompatible with acids, bases, oxidizing agents.
- LogP
- 2.57
- CAS DataBase Reference
- 87-25-2(CAS DataBase Reference)
- EPA Substance Registry System
- Ethyl anthranilate (87-25-2)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/38
- Safety Statements
- 26-36
- WGK Germany
- 2
- RTECS
- DG2448000
- Hazard Note
- Irritant
- TSCA
- Yes
- HS Code
- 29224999
- Hazardous Substances Data
- 87-25-2(Hazardous Substances Data)
- Toxicity
- The acute oral LD50 value in rats was reported as 3.75 g/kg (3.32-4.18 g/kg) and the acute dermal LD50 value in rabbits exceeded 5 g/kg (Moreno, 1975).
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H303May be harmfulif swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- W242101
- Product name
- Ethyl 2-aminobenzoate
- Purity
- ≥96%, FCC, FG
- Packaging
- sample-k
- Price
- $54.6
- Updated
- 2024/03/01
- Product number
- W242101
- Product name
- Ethyl 2-aminobenzoate
- Purity
- ≥96%, FCC, FG
- Packaging
- 1kg
- Price
- $173
- Updated
- 2024/03/01
- Product number
- W242101
- Product name
- Ethyl 2-aminobenzoate
- Purity
- ≥96%, FCC, FG
- Packaging
- 10Kg
- Price
- $1070
- Updated
- 2024/03/01
- Product number
- 242977
- Product name
- Ethyl 2-aminobenzoate
- Purity
- ≥99%
- Packaging
- 100g
- Price
- $61.9
- Updated
- 2024/03/01
- Product number
- PHR9022
- Product name
- Ethyl 2-aminobenzoate
- Purity
- reference material
- Packaging
- 100MG
- Price
- $318
- Updated
- 2022/05/15
ETHYL ANTHRANILATE Chemical Properties,Usage,Production
Chemical Properties
colourless liquid
Chemical Properties
Ethyl anthranilate has a faint, orange-flower odor and similar taste.
Occurrence
Reported found in grapes, orange juice, orange peel oil, starfruit and Vitis labrusca L.
Uses
Ethyl 2-aminobenzoate is used as a reactant in the amination of aryl chlorides, bromides, and triflates.
Uses
Perfumery and flavors, similar to methyl anthranilate.
Preparation
By esterification of anthranilic acid with ethanol in the presence of acid catalysts; by reacting sodium hypochlorite with an alkaline solution of phthalimide
Definition
ChEBI: Ethyl 2-aminobenzoate is a benzoate ester.
General Description
Colorless liquid with a fruity odor. Insoluble in water.
Air & Water Reactions
ETHYL ANTHRANILATE should be protected from air and light. Insoluble in water.
Reactivity Profile
ETHYL ANTHRANILATE may hydrolyze under acidic and basic conditions.
Fire Hazard
Flash point data for ETHYL ANTHRANILATE are not available. ETHYL ANTHRANILATE is probably combustible.
Pharmacology
Ethyl anthranilate behaved as a local anaesthetic, as measured by depression of
muscle twitch, but was 50% less effective than the m- and p-aminobenzoate isomers. All three compounds
potentiated the initial phase of caffeine-induced contracture of frog sartorius muscle, but
the o-isomer had no effect on the peak tension of the contracture (Friedman, Bianchi & Weiss.
1974). It was proposed that the o-amino group has both steric and polar effects, its bulk preventing
the inhibitory action of the carbonyl group on the caffeine-induced contracture of sartorius muscle,
while the lone electron pair of the nitrogen atom induces a contracture on its own accord and
potentiates a caffeine-induced contracture (Friedman, 1975).
Ethyl anthranilate (0-1 mmol/litre) decreased the frequency of the electric-organ discharges of
the electric fish, Gnathonemus moori, but did not affect the individual pulse amplitudes, indicating
that the compound acted on the pacemaker cells of the mesencephalic command nucleus (Walsh
& Schopp, 1966).
Safety Profile
Moderately toxic by ingestion. A skin irritant. Combustible liquid. When heated to decomposition it emits toxic fumes of NOx.
ETHYL ANTHRANILATE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from ETHYL ANTHRANILATE manufacturers
- Product
- ETHYL ANTHRANILATE 87-25-2
- Price
- US $20.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20MT
- Release date
- 2024-04-22
- Product
- ETHYL ANTHRANILATE 87-25-2
- Price
- US $20.00-9.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 10 tons
- Release date
- 2023-10-12
- Product
- ETHYL ANTHRANILATE 87-25-2
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 500000kg
- Release date
- 2024-10-24