ChemicalBook > CAS DataBase List > ETHYL ANTHRANILATE

ETHYL ANTHRANILATE

Product Name
ETHYL ANTHRANILATE
CAS No.
87-25-2
Chemical Name
ETHYL ANTHRANILATE
Synonyms
ETHYL 2-AMINOBENZOATE;ethyl-o-amino;o-(Ethoxycarbonyl)aniline;FEMA 2421;Ethylanthranilat;ETHYL ANTHRANILATE;2-carboethoxyaniline;ETHYL O-AMINOBENZOATE;Ethylanthranilate,98+%;Anthranilic acid ethyl
CBNumber
CB1221396
Molecular Formula
C9H11NO2
Formula Weight
165.19
MOL File
87-25-2.mol
More
Less

ETHYL ANTHRANILATE Property

Melting point:
13-15 °C (lit.)
Boiling point:
129-130 °C/9 mmHg (lit.)
Density 
1.117 g/mL at 25 °C (lit.)
vapor density 
5.7 (vs air)
refractive index 
n20/D 1.564(lit.)
FEMA 
2421 | ETHYL ANTHRANILATE
Flash point:
>230 °F
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
Insoluble in water but soluble in organic solvents
form 
Clear liquid
pka
2.20±0.10(Predicted)
color 
Light yellow
Specific Gravity
1.1170
Odor
at 100.00 %. sweet floral grape orangeblossom wintergreen
Odor Type
floral
JECFA Number
1535
BRN 
878874
Stability:
Stable. Combustible. Incompatible with acids, bases, oxidizing agents.
LogP
2.57
CAS DataBase Reference
87-25-2(CAS DataBase Reference)
EPA Substance Registry System
Ethyl anthranilate (87-25-2)
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/38
Safety Statements 
26-36
WGK Germany 
2
RTECS 
DG2448000
Hazard Note 
Irritant
TSCA 
Yes
HS Code 
29224999
Hazardous Substances Data
87-25-2(Hazardous Substances Data)
Toxicity
The acute oral LD50 value in rats was reported as 3.75 g/kg (3.32-4.18 g/kg) and the acute dermal LD50 value in rabbits exceeded 5 g/kg (Moreno, 1975).
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H303May be harmfulif swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W242101
Product name
Ethyl 2-aminobenzoate
Purity
≥96%, FCC, FG
Packaging
sample-k
Price
$54.6
Updated
2024/03/01
Sigma-Aldrich
Product number
W242101
Product name
Ethyl 2-aminobenzoate
Purity
≥96%, FCC, FG
Packaging
1kg
Price
$173
Updated
2024/03/01
Sigma-Aldrich
Product number
W242101
Product name
Ethyl 2-aminobenzoate
Purity
≥96%, FCC, FG
Packaging
10Kg
Price
$1070
Updated
2024/03/01
Sigma-Aldrich
Product number
242977
Product name
Ethyl 2-aminobenzoate
Purity
≥99%
Packaging
100g
Price
$61.9
Updated
2024/03/01
Sigma-Aldrich
Product number
PHR9022
Product name
Ethyl 2-aminobenzoate
Purity
reference material
Packaging
100MG
Price
$318
Updated
2022/05/15
More
Less

ETHYL ANTHRANILATE Chemical Properties,Usage,Production

Chemical Properties

colourless liquid

Chemical Properties

Ethyl anthranilate has a faint, orange-flower odor and similar taste.

Occurrence

Reported found in grapes, orange juice, orange peel oil, starfruit and Vitis labrusca L.

Uses

Ethyl 2-aminobenzoate is used as a reactant in the amination of aryl chlorides, bromides, and triflates.

Uses

Perfumery and flavors, similar to methyl anthranilate.

Preparation

By esterification of anthranilic acid with ethanol in the presence of acid catalysts; by reacting sodium hypochlorite with an alkaline solution of phthalimide

Definition

ChEBI: Ethyl 2-aminobenzoate is a benzoate ester.

General Description

Colorless liquid with a fruity odor. Insoluble in water.

Air & Water Reactions

ETHYL ANTHRANILATE should be protected from air and light. Insoluble in water.

Reactivity Profile

ETHYL ANTHRANILATE may hydrolyze under acidic and basic conditions.

Fire Hazard

Flash point data for ETHYL ANTHRANILATE are not available. ETHYL ANTHRANILATE is probably combustible.

Pharmacology

Ethyl anthranilate behaved as a local anaesthetic, as measured by depression of muscle twitch, but was 50% less effective than the m- and p-aminobenzoate isomers. All three compounds potentiated the initial phase of caffeine-induced contracture of frog sartorius muscle, but the o-isomer had no effect on the peak tension of the contracture (Friedman, Bianchi & Weiss. 1974). It was proposed that the o-amino group has both steric and polar effects, its bulk preventing the inhibitory action of the carbonyl group on the caffeine-induced contracture of sartorius muscle, while the lone electron pair of the nitrogen atom induces a contracture on its own accord and potentiates a caffeine-induced contracture (Friedman, 1975).
Ethyl anthranilate (0-1 mmol/litre) decreased the frequency of the electric-organ discharges of the electric fish, Gnathonemus moori, but did not affect the individual pulse amplitudes, indicating that the compound acted on the pacemaker cells of the mesencephalic command nucleus (Walsh & Schopp, 1966).

Safety Profile

Moderately toxic by ingestion. A skin irritant. Combustible liquid. When heated to decomposition it emits toxic fumes of NOx.

ETHYL ANTHRANILATE Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

ETHYL ANTHRANILATE Suppliers

Henan Lingbei Biotechnology Co., Ltd
Tel
86-18539896799 18539896799
Email
71889632@qq.com
Country
China
ProdList
116
Advantage
58
Shanxi Xinsheng Biotechnology Co., Ltd
Tel
15835826763
Email
997855689@qq.com
Country
China
ProdList
111
Advantage
58
MedicalChem(Yancheng)Manuf.Co.,Ltd
Tel
+86-515-84383180
Fax
+86-515-84383182
Email
sales@medicalchem.com
Country
China
ProdList
80
Advantage
69
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15839
Advantage
69
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
18207
Advantage
66
More
Less

View Lastest Price from ETHYL ANTHRANILATE manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
ETHYL ANTHRANILATE 87-25-2
Price
US $20.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20MT
Release date
2024-04-22
Hebei Yanxi Chemical Co., Ltd.
Product
ETHYL ANTHRANILATE 87-25-2
Price
US $20.00-9.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10 tons
Release date
2023-10-12
Hebei Weibang Biotechnology Co., Ltd
Product
ETHYL ANTHRANILATE 87-25-2
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-24

87-25-2, ETHYL ANTHRANILATERelated Search:


  • FEMA 2421
  • ETHYL ANTHRANILATE
  • ETHYL O-AMINOBENZOATE
  • ETHYL 2-AMINOBENZOATE
  • 2-AMINOBENZOIC ACID ETHYL ESTER
  • ethyl-o-amino
  • o-(Ethoxycarbonyl)aniline
  • o-aminobenzoicacid,ethylester
  • o-amino-benzoicaciethylester
  • ETHYL ANTHRANILATE 96+% FCC
  • ETHYL 2-AMINOBENZOATE, 99+%
  • ETHYL-2-AMINOBENZOATE 99% (GC)
  • Ethylanthranilate,98+%
  • Ethylanthranilat
  • 2-Aminobenzoic acid ethyl
  • Anthranilic acid ethyl
  • Ethyl 2-aminobenzoate,Ethyl anthranilate
  • 4-(phenylmethylthio)quinazoline
  • ANTHRANILIC ACID ETHYL ESTER
  • 2-(ethoxycarbonyl)aniline
  • 2-amino-benzoicaciethylester
  • 2-carboethoxyaniline
  • Aminobenzoicacid,ethylester
  • Benzoic acid, o-amino-, ethyl ester
  • benzoicacid,2-amino-,ethylester
  • Ethyl 2-aMinobenzoate, 99% 100GR
  • 2-Aminobenzoic Acid Ethyl Ester Ethyl 2-Aminobenzoate Anthranilic Acid Ethyl Ester
  • Ethyl Anthranilate &gt
  • Tetracaine Impurity 6 (Ethyl 2-Aminobenzoate)
  • Ethyl anthranilate USP/EP/BP
  • ETHYL ANTHRANILATE FOR SYNTHESIS
  • Benzocaine Impurity D (BP)
  • 87-25-2
  • H2NC6H4CO2C2H5
  • ESTER
  • Building Blocks
  • C8 to C9
  • Carbonyl Compounds
  • Organic Building Blocks
  • Esters
  • Aromatic Esters