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ETHYL ANTHRANILATE

Product Name
ETHYL ANTHRANILATE
CAS No.
87-25-2
Chemical Name
ETHYL ANTHRANILATE
Synonyms
ETHYL 2-AMINOBENZOATE;ethyl-o-amino;o-(Ethoxycarbonyl)aniline;FEMA 2421;Ethylanthranilat;ETHYL ANTHRANILATE;2-carboethoxyaniline;ETHYL O-AMINOBENZOATE;Ethylanthranilate,98+%;Anthranilic acid ethyl
CBNumber
CB1221396
Molecular Formula
C9H11NO2
Formula Weight
165.19
MOL File
87-25-2.mol
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ETHYL ANTHRANILATE Property

Melting point:
13-15 °C (lit.)
Boiling point:
129-130 °C/9 mmHg (lit.)
Density 
1.117 g/mL at 25 °C (lit.)
vapor density 
5.7 (vs air)
refractive index 
n20/D 1.564(lit.)
FEMA 
2421 | ETHYL ANTHRANILATE
Flash point:
>230 °F
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
Insoluble in water but soluble in organic solvents
form 
Clear liquid
pka
2.20±0.10(Predicted)
color 
Light yellow
Specific Gravity
1.1170
Odor
at 100.00 %. sweet floral grape orangeblossom wintergreen
Odor Type
floral
JECFA Number
1535
BRN 
878874
Stability:
Stable. Combustible. Incompatible with acids, bases, oxidizing agents.
LogP
2.57
CAS DataBase Reference
87-25-2(CAS DataBase Reference)
EPA Substance Registry System
Ethyl anthranilate (87-25-2)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/38
Safety Statements 
26-36
WGK Germany 
2
RTECS 
DG2448000
Hazard Note 
Irritant
TSCA 
Yes
HS Code 
29224999
Hazardous Substances Data
87-25-2(Hazardous Substances Data)
Toxicity
The acute oral LD50 value in rats was reported as 3.75 g/kg (3.32-4.18 g/kg) and the acute dermal LD50 value in rabbits exceeded 5 g/kg (Moreno, 1975).
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H303May be harmfulif swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W242101
Product name
Ethyl 2-aminobenzoate
Purity
≥96%, FCC, FG
Packaging
sample-k
Price
$54.6
Updated
2024/03/01
Sigma-Aldrich
Product number
W242101
Product name
Ethyl 2-aminobenzoate
Purity
≥96%, FCC, FG
Packaging
1kg
Price
$173
Updated
2024/03/01
Sigma-Aldrich
Product number
W242101
Product name
Ethyl 2-aminobenzoate
Purity
≥96%, FCC, FG
Packaging
10Kg
Price
$1070
Updated
2024/03/01
Sigma-Aldrich
Product number
242977
Product name
Ethyl 2-aminobenzoate
Purity
≥99%
Packaging
100g
Price
$61.9
Updated
2024/03/01
Sigma-Aldrich
Product number
PHR9022
Product name
Ethyl 2-aminobenzoate
Purity
reference material
Packaging
100MG
Price
$318
Updated
2022/05/15
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ETHYL ANTHRANILATE Chemical Properties,Usage,Production

Chemical Properties

colourless liquid

Chemical Properties

Ethyl anthranilate has a faint, orange-flower odor and similar taste.

Occurrence

Reported found in grapes, orange juice, orange peel oil, starfruit and Vitis labrusca L.

Uses

Ethyl 2-aminobenzoate is used as a reactant in the amination of aryl chlorides, bromides, and triflates.

Uses

Perfumery and flavors, similar to methyl anthranilate.

Preparation

By esterification of anthranilic acid with ethanol in the presence of acid catalysts; by reacting sodium hypochlorite with an alkaline solution of phthalimide

Definition

ChEBI: Ethyl 2-aminobenzoate is a benzoate ester.

General Description

Colorless liquid with a fruity odor. Insoluble in water.

Air & Water Reactions

ETHYL ANTHRANILATE should be protected from air and light. Insoluble in water.

Reactivity Profile

ETHYL ANTHRANILATE may hydrolyze under acidic and basic conditions.

Fire Hazard

Flash point data for ETHYL ANTHRANILATE are not available. ETHYL ANTHRANILATE is probably combustible.

Pharmacology

Ethyl anthranilate behaved as a local anaesthetic, as measured by depression of muscle twitch, but was 50% less effective than the m- and p-aminobenzoate isomers. All three compounds potentiated the initial phase of caffeine-induced contracture of frog sartorius muscle, but the o-isomer had no effect on the peak tension of the contracture (Friedman, Bianchi & Weiss. 1974). It was proposed that the o-amino group has both steric and polar effects, its bulk preventing the inhibitory action of the carbonyl group on the caffeine-induced contracture of sartorius muscle, while the lone electron pair of the nitrogen atom induces a contracture on its own accord and potentiates a caffeine-induced contracture (Friedman, 1975).
Ethyl anthranilate (0-1 mmol/litre) decreased the frequency of the electric-organ discharges of the electric fish, Gnathonemus moori, but did not affect the individual pulse amplitudes, indicating that the compound acted on the pacemaker cells of the mesencephalic command nucleus (Walsh & Schopp, 1966).

Safety Profile

Moderately toxic by ingestion. A skin irritant. Combustible liquid. When heated to decomposition it emits toxic fumes of NOx.

ETHYL ANTHRANILATE Preparation Products And Raw materials

Raw materials

Preparation Products

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ETHYL ANTHRANILATE Suppliers

TCI Europe
Tel
320-37350700
Fax
+32 (0)37350701
Email
sales@tcieurope.eu
Country
Europe
ProdList
23680
Advantage
75
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View Lastest Price from ETHYL ANTHRANILATE manufacturers

Hebei Yanxi Chemical Co., Ltd.
Product
ETHYL ANTHRANILATE 87-25-2
Price
US $20.00-9.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10 tons
Release date
2023-10-12
Hebei Mojin Biotechnology Co., Ltd
Product
ETHYL ANTHRANILATE 87-25-2
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-09-22
Hebei Guanlang Biotechnology Co., Ltd.
Product
ETHYL ANTHRANILATE 87-25-2
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2023-04-11

87-25-2, ETHYL ANTHRANILATERelated Search:


  • FEMA 2421
  • ETHYL ANTHRANILATE
  • ETHYL O-AMINOBENZOATE
  • ETHYL 2-AMINOBENZOATE
  • 2-AMINOBENZOIC ACID ETHYL ESTER
  • ethyl-o-amino
  • o-(Ethoxycarbonyl)aniline
  • o-aminobenzoicacid,ethylester
  • o-amino-benzoicaciethylester
  • ETHYL ANTHRANILATE 96+% FCC
  • ETHYL 2-AMINOBENZOATE, 99+%
  • ETHYL-2-AMINOBENZOATE 99% (GC)
  • Ethylanthranilate,98+%
  • Ethylanthranilat
  • 2-Aminobenzoic acid ethyl
  • Anthranilic acid ethyl
  • Ethyl 2-aminobenzoate,Ethyl anthranilate
  • 4-(phenylmethylthio)quinazoline
  • ANTHRANILIC ACID ETHYL ESTER
  • 2-(ethoxycarbonyl)aniline
  • 2-amino-benzoicaciethylester
  • 2-carboethoxyaniline
  • Aminobenzoicacid,ethylester
  • Benzoic acid, o-amino-, ethyl ester
  • benzoicacid,2-amino-,ethylester
  • Ethyl 2-aMinobenzoate, 99% 100GR
  • 2-Aminobenzoic Acid Ethyl Ester Ethyl 2-Aminobenzoate Anthranilic Acid Ethyl Ester
  • Ethyl Anthranilate &gt
  • Tetracaine Impurity 6 (Ethyl 2-Aminobenzoate)
  • Ethyl anthranilate USP/EP/BP
  • ETHYL ANTHRANILATE FOR SYNTHESIS
  • Benzocaine Impurity D (BP)
  • 87-25-2
  • H2NC6H4CO2C2H5
  • ESTER
  • Building Blocks
  • C8 to C9
  • Carbonyl Compounds
  • Organic Building Blocks
  • Esters
  • Aromatic Esters