ChemicalBook > CAS DataBase List > tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
- Product Name
- tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
- CAS No.
- 112741-50-1
- Chemical Name
- tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
- Synonyms
- (2S,3R)-tert-Butyl;(5R,6S)-N-Boc-5,6-diphenyl-2-morpholinone;6-oxo-2,3-diphenylMorpholine-4-carboxylate;(2S,3R)-(+)-N-Boc-6-oxo-2,3-diphenylMorpholine;2S,3R-6-oxo-2,3-diphenyl-4-morpholinecarboxylate;tert-butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morph;(2S,3R)-6-oxo-2,3-diphenylmorpholine-4-carboxylate;(5S,6R)-(+)-4-Boc-5,6-diphenyl-2-Morpholinone, 99%;(5R,6S)-4-TERT-BUTOXYCARBONYL-5,6-DIPHENYLMORPHOLIN-2-ONE;(5S,6R)-4-tert-Butoxycarbonyl-5,6-diphenylmorpholin-2-one
- CBNumber
- CB1239496
- Molecular Formula
- C21H23NO4
- Formula Weight
- 353.41
- MOL File
- 112741-50-1.mol
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tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Property
- Melting point:
- 206 °C (dec.)(lit.)
- alpha
- 86 º (c=5.5 in methylene chloride)
- Boiling point:
- 509.6±50.0 °C(Predicted)
- Density
- 1.175±0.06 g/cm3(Predicted)
- storage temp.
- 2-8°C
- pka
- -3.28±0.60(Predicted)
- optical activity
- [α]20/D +86°, c = 5.5 in methylene chloride
- InChIKey
- MRUKRSQUUNYOFK-MOPGFXCFSA-N
- CAS DataBase Reference
- 112741-50-1(CAS DataBase Reference)
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 331813
- Product name
- (2S,3R)-(+)-N-Boc-6-oxo-2,3-diphenylmorpholine
- Purity
- 99%
- Packaging
- 5g
- Price
- $441
- Updated
- 2023/06/20
Sigma-Aldrich
- Product number
- 331813
- Product name
- (2S,3R)-(+)-N-Boc-6-oxo-2,3-diphenylmorpholine
- Purity
- 99%
- Packaging
- 1g
- Price
- $97.8
- Updated
- 2023/01/07
TRC
- Product number
- B699835
- Product name
- (2S,3R)-(+)-N-Boc-6-oxo-2,3-diphenylmorpholine
- Packaging
- 500mg
- Price
- $140
- Updated
- 2021/12/16
TRC
- Product number
- B699835
- Product name
- (2S,3R)-(+)-N-Boc-6-oxo-2,3-diphenylmorpholine
- Packaging
- 2.5g
- Price
- $360
- Updated
- 2021/12/16
Biosynth Carbosynth
- Product number
- FB63306
- Product name
- (2S,3R)-tert-Butyl 6-oxo-2,3-diphenylmorpholine-4-carboxylate
- Packaging
- 5G
- Price
- $825
- Updated
- 2021/12/16
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tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Chemical Properties,Usage,Production
Uses
(2S,3R)-(+)-N-Boc-6-oxo-2,3-diphenylmorpholine (Williams chiral auxiliary) can be used as a reactant:
- In the asymmetric synthesis of cylindrospermopsin and related alkaloids via an intramolecular 1,3-dipolar cycloaddition reaction.
- To synthesize boc-3-(1-methylcyclopropyl)-D-alanine, which is used as an intermediate to prepare 4-fluoroproline-based analogs as potent tripeptide thrombin inhibitors.
- In the total synthesis of potent hepatotoxic alkaloid 7-epicylindrospermopsin by intramolecular 1,3-dipolar cycloaddition and nitroaldol reaction.
- To prepare differentially functionalized diaminoglutamic acids via radical reaction of selenide with methyl 2-acetamidoacrylate.
tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate manufacturers
Zhuozhou Wenxi import and Export Co., Ltd
- Product
- tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate 112741-50-1
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-08-11
Career Henan Chemical Co
- Product
- tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate 112741-50-1
- Price
- US $9.80/KG
- Min. Order
- 1g
- Purity
- ≥99%
- Supply Ability
- 100kg
- Release date
- 2020-01-03
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