tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate

Product Name: tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
CAS No.: 112741-50-1
Chemical Name: tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
Synonyms: (2S,3R)-tert-Butyl;(5R,6S)-N-Boc-5,6-diphenyl-2-morpholinone;6-oxo-2,3-diphenylMorpholine-4-carboxylate;(2S,3R)-(+)-N-Boc-6-oxo-2,3-diphenylMorpholine;2S,3R-6-oxo-2,3-diphenyl-4-morpholinecarboxylate;tert-butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morph;(2S,3R)-6-oxo-2,3-diphenylmorpholine-4-carboxylate;(5S,6R)-(+)-4-Boc-5,6-diphenyl-2-Morpholinone, 99%;(5R,6S)-4-TERT-BUTOXYCARBONYL-5,6-DIPHENYLMORPHOLIN-2-ONE;(5S,6R)-4-tert-Butoxycarbonyl-5,6-diphenylmorpholin-2-one
CBNumber: CB1239496
Molecular Formula: C21H23NO4
Formula Weight: 353.41
MOL File: 112741-50-1.mol

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tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Property

Melting point:: 206 °C (dec.)(lit.)
alpha: 86 º (c=5.5 in methylene chloride)
Boiling point:: 509.6±50.0 °C(Predicted)
Density: 1.175±0.06 g/cm3(Predicted)
storage temp.: 2-8°C
pka: -3.28±0.60(Predicted)
optical activity: [α]20/D +86°, c = 5.5 in methylene chloride
InChIKey: MRUKRSQUUNYOFK-MOPGFXCFSA-N
CAS DataBase Reference: 112741-50-1(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-37/39
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 331813
Product name: (2S,3R)-(+)-N-Boc-6-oxo-2,3-diphenylmorpholine
Purity: 99%
Packaging: 5g
Price: $441
Updated: 2023/06/20

Sigma-Aldrich

Product number: 331813
Product name: (2S,3R)-(+)-N-Boc-6-oxo-2,3-diphenylmorpholine
Purity: 99%
Packaging: 1g
Price: $97.8
Updated: 2023/01/07

TRC

Product number: B699835
Product name: (2S,3R)-(+)-N-Boc-6-oxo-2,3-diphenylmorpholine
Packaging: 500mg
Price: $140
Updated: 2021/12/16

TRC

Product number: B699835
Product name: (2S,3R)-(+)-N-Boc-6-oxo-2,3-diphenylmorpholine
Packaging: 2.5g
Price: $360
Updated: 2021/12/16

Matrix Scientific

Product number: 072699
Product name: N-Boc-(2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
Purity: 95+%
Packaging: 1g
Price: $98
Updated: 2021/12/16

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tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Chemical Properties,Usage,Production

Uses

(2S,3R)-(+)-N-Boc-6-oxo-2,3-diphenylmorpholine (Williams chiral auxiliary) can be used as a reactant:

In the asymmetric synthesis of cylindrospermopsin and related alkaloids via an intramolecular 1,3-dipolar cycloaddition reaction.
To synthesize boc-3-(1-methylcyclopropyl)-D-alanine, which is used as an intermediate to prepare 4-fluoroproline-based analogs as potent tripeptide thrombin inhibitors.
In the total synthesis of potent hepatotoxic alkaloid 7-epicylindrospermopsin by intramolecular 1,3-dipolar cycloaddition and nitroaldol reaction.
To prepare differentially functionalized diaminoglutamic acids via radical reaction of selenide with methyl 2-acetamidoacrylate.

tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Preparation Products And Raw materials

Raw materials

Preparation Products

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tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Suppliers

China 89 Germany 2 India 3 Switzerland 1 United Kingdom 3 United States 17 Global 115

INTATRADE GmbH

Tel: +49 3493/605464
Fax: +49 3493/605470
Email: sales@intatrade.de
Country: Germany
ProdList: 3572
Advantage: 66

NovoChemy Ltd.

Tel: 021-31261262/ 49 (0)17662837245
Fax: (0)21-33250524
Email: sales@novochemy.com
Country: Germany
ProdList: 6328
Advantage: 58

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View Lastest Price from tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate 112741-50-1
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

Career Henan Chemical Co

Product: tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate 112741-50-1
Price: US $9.80/KG
Min. Order: 1g
Purity: ≥99%
Supply Ability: 100kg
Release date: 2020-01-03

112741-50-1, tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylateRelated Search:

tert-Butanol Cyhalofop-butyl Buprofezin Tridemorph 2-Butoxyethanol Diethylene glycol monobutyl ether Dimethomorph Moroxydine hydrochloride tert-Butyl peroxyacetate tert-Butyl acetate Biphenyl Butyl acrylate Butyl acetate Moroxydine Phenmetrazine (5R,6S)-5,6-Diphenyl-2-morpholinone 3-methylmorpholine (S)-2-Methyl-morpholine

(2S,3R)-6-Oxo-2,3-diphenyl-morpholine-4-carboxylic acid tert-butyl ester

(5S,6R)-(+)-4-Boc-5,6-diphenyl-2-Morpholinone, 99%

(2S,3R)-(+)-N-Boc-6-oxo-2,3-diphenylMorpholine

(5R,6S)-N-Boc-5,6-diphenyl-2-morpholinone

tert-butyl (2S,3R)-6-oxo-2,3-diphenylMorpholine-4-carboxylate

(2S,3R)-(+)-N-Boc-6-oxo-2,3-diphenylMorpholine

(2S, 3R) - (+) - N- t-butoxycarbonyl-6-oxo-2,3-diphenyl-Morpholine

(2S,3R)-tert-Butyl

6-oxo-2,3-diphenylMorpholine-4-carboxylate

(2S,3R)-6-Oxo-2,3-diphenyl-4-morpholinecarboxylic Acid 1,1-Dimethylethyl Ester

(2S,3R)-6-oxo-2,3-diphenylmorpholine-4-carboxylate

(2S,3R)-(+)-N-tert-Butoxycarbonyl-6-oxo-2,3-diphenylmorpholine

(2S,3R)-6-Oxo-2,3-diphenyl-4-morpholinecarboxylic Acid tert-Butyl Ester,99%e.e.

TERT-BUTYL (2S,3R)-(+)-6-OXO-2,3-DIPHENYL-4-MORPHOLINECARBOXYLATE

N-TERT-BUTOXYCARBONYL-(2S,3R)-(+)-6-OXO-2,3-DIPHENYL-4-MORPHOLINE-CARBOXYLATE

N-BOC(2S, 3R)-(+)-6-OXO-2,3-DIPHENYL-4-MORPHOLINE CARBOXYLATE

(2S,3R)-6-Oxo-2,3-diphenyl-4-morpholinecarboxylic Acid tert-Butyl Ester

(5R,6S)-4-TERT-BUTOXYCARBONYL-5,6-DIPHENYLMORPHOLIN-2-ONE

tert-butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morph

TERT-BUTYL (2S,3R)-(+)-6-OXO-2,3-DIPHENY L-4-MORPHOLINECARBOXYLATE, 99% (99% EE)

(2S,3R)-tert-Butyl 6-oxo-2,3- diphenylmorpholine-4-carboxylate

(5S,6R)-4-tert-Butoxycarbonyl-5,6-diphenylmorpholin-2-one

4-Morpholinecarboxylic acid, 6-oxo-2,3-diphenyl-, 1,1-dimethylethyl ester, (2S,3R)-

2S,3R-6-oxo-2,3-diphenyl-4-morpholinecarboxylate

112741-50-1

41-50-1

Morpholines

Heterocyclic Building Blocks

Asymmetric Synthesis

Chiral Building Blocks

Heterocyclic Building Blocks

Morpholines

API intermediates