Description Referrence
ChemicalBook > CAS DataBase List > Cyclopropyl carbinol

Cyclopropyl carbinol

Description Referrence
Product Name
Cyclopropyl carbinol
CAS No.
2516-33-8
Chemical Name
Cyclopropyl carbinol
Synonyms
CYCLOPROPYLMETHANOL;CYCLOPROPANEMETHANOL;CPMO;CP-CARBINOL;(HYDROXYMETHYL)CYCLOPROPANE;CPC-OL;Cyclopropylmethane;RARECHEM AK ML 0580;CYCLOPROPYL CARBINOL;CYCLPOPROPANEMETHANOL
CBNumber
CB1254806
Molecular Formula
C4H8O
Formula Weight
72.11
MOL File
2516-33-8.mol
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Cyclopropyl carbinol Property

Melting point:
-60 °C
Boiling point:
123-124 °C738 mm Hg(lit.)
Density 
0.89 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.431(lit.)
Flash point:
95 °F
storage temp. 
Flammables area
solubility 
Chloroform, Ethyl Acetate
pka
15.10±0.10(Predicted)
form 
Liquid
color 
Clear colorless
Specific Gravity
0.890
Water Solubility 
miscible
BRN 
1846846
InChIKey
GUDMZGLFZNLYEY-UHFFFAOYSA-N
CAS DataBase Reference
2516-33-8(CAS DataBase Reference)
NIST Chemistry Reference
Cyclopropyl carbinol(2516-33-8)
EPA Substance Registry System
Cyclopropanemethanol (2516-33-8)
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Safety

Hazard Codes 
Xn,Xi,C,F
Risk Statements 
10-22-36-34
Safety Statements 
16-26-36-45-36/37/39
RIDADR 
UN 1987 3/PG 3
WGK Germany 
1
RTECS 
GZ2212250
Hazard Note 
Irritant
TSCA 
Yes
HazardClass 
3
PackingGroup 
III
HS Code 
29061990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

H302Harmful if swallowed

H319Causes serious eye irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
482099
Product name
Cyclopropanemethanol
Purity
≥99.5%
Packaging
25ml
Price
$67.8
Updated
2024/03/01
Sigma-Aldrich
Product number
482099
Product name
Cyclopropanemethanol
Purity
≥99.5%
Packaging
1l
Price
$384.6
Updated
2024/03/01
TCI Chemical
Product number
C0982
Product name
Cyclopropanemethanol
Purity
>98.0%(GC)
Packaging
5mL
Price
$20
Updated
2024/03/01
TCI Chemical
Product number
C0982
Product name
Cyclopropanemethanol
Purity
>98.0%(GC)
Packaging
25mL
Price
$37
Updated
2024/03/01
Alfa Aesar
Product number
A12567
Product name
Cyclopropanemethanol, 98%
Packaging
5g
Price
$27.65
Updated
2024/03/01
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Cyclopropyl carbinol Chemical Properties,Usage,Production

Description

Cyclopropyl carbinol (also known as Cyclopropanemethanol) is an anaesthetic. Cyclopropyl Carbinol is used as an intermediate for pharmaceuticals, agrochemical, and other organic synthesis such as for the applications for electronics chemicals, polymer additives, coatings, adhesives, surfactants, and other applications3. It can also be used for the preparation of cyclopropanecarbaldehyde, cyclopropylmethylsulfonate and dibenzyl cyclopropylmethyl phosphate1. It is also quite useful to for stereoselective synthesis of cycloalkene-fused butyrolactones via cyclopropylcarbinol solvolysis.

Referrence

Marshall, James A., and R. H. Ellison. "Stereoselective synthesis of cycloalkene-fused butyrolactones via cyclopropylcarbinol solvolysis." Journal of Organic Chemistry 40.14(1975):2070-2073.

Chemical Properties

Clear colorless liquid

Uses

Cyclopropanemethanol is used as an organic chemical synthesis intermediate.

Uses

Cyclopropylmethanol used to increase selectivity of pyridyl-cinnoline phosphodiesterase 10A, inhibitors against phosphodiesterase 3 (PDE3). Also used in the synthesis of benzodiazapin-2-ones

Preparation

The preparation of Cyclopropyl carbinol is as follows:A 1L three-necked flask was charged with 100 g (1mol) of methyl cyclopropanoate. 57g (1.5mol) of sodium borohydride, 500 mL of methanol, and then cooled to 2°C, 66.67g (0.5mol) of aluminum trichloride was added in batches and reacted overnight. The reaction was quenched by the addition of a saturated aqueous solution of ammonium chloride, filtered, and the filtrate was concentrated and evaporated. The product was collected in a yield of 53.49g, a yield of 74.3%.

General Description

Cyclopropanemethanol (Cyclopropyl carbinol, CPMO), a cycloalkanemethanol, is an anaesthetic. The coupling reaction of cyclopropanemethanol with alkynes to form substituted allylic alcohols has been reported. The microwave spectrum of CPMO has been recorded. Its rotational constants and dipole moment have been determined.

Cyclopropyl carbinol Preparation Products And Raw materials

Raw materials

Diazomethane Diiodomethane ZINC-COPPER COUPLE Allyl alcohol

Preparation Products

Cyclopropanecarboxaldehyde Cyclobutanol
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Cyclopropyl carbinol Suppliers

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View Lastest Price from Cyclopropyl carbinol manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
Cyclopropyl carbinol 2516-33-8
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2024-10-28
Henan Fengda Chemical Co., Ltd
Product
Cyclopropyl carbinol 2516-33-8
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-26
Hebei Mojin Biotechnology Co., Ltd
Product
Cyclopropyl carbinol 2516-33-8
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-07-24

2516-33-8, Cyclopropyl carbinolRelated Search:

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