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RETRORSINE

Product Name
RETRORSINE
CAS No.
480-54-6
Chemical Name
RETRORSINE
Synonyms
Retrosine;RETRORSIN;RETRORSINE;Retrorcine;β-Longilobine;RETRORSINE(AS);BETA-LONGILOBINE;Retrorsine 100 μg/mL in Water;cis-retronecicacidesterofretronecine;16-dione,12,18-dihydroxy-senecionan-1
CBNumber
CB1256406
Molecular Formula
C18H25NO6
Formula Weight
351.39
MOL File
480-54-6.mol
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RETRORSINE Property

Melting point:
208-211 °C (lit.)
alpha 
D18 -17.6° (c = 1.99 in ethanol)
Boiling point:
485.2°C (rough estimate)
Density 
1.32±0.1 g/cm3 (20 ºC 760 Torr)
refractive index 
1.5100 (estimate)
storage temp. 
2-8°C
solubility 
DMSO: Slightly soluble: 0.1-1 mg/mlPBS (pH 7.2): Slightly soluble: 0.1-1 mg/ml
pka
12.00±0.40(Predicted)
form 
Solid
color 
White to off-white
Merck 
13,8253
InChI
InChI=1S/C18H25NO6/c1-3-12-8-11(2)18(23,10-20)17(22)24-9-13-4-6-19-7-5-14(15(13)19)25-16(12)21/h3-4,11,14-15,20,23H,5-10H2,1-2H3/b12-3-/t11-,14-,15-,18-/m1/s1
InChIKey
BCJMNZRQJAVDLD-VMOBWIEOSA-N
SMILES
N12CC=C3COC(=O)[C@@](O)(CO)[C@H](C)C/C(=C/C)/C(=O)O[C@@]([H])([C@]13[H])CC2
CAS DataBase Reference
480-54-6
IARC
3 (Vol. 10, Sup 7) 1987
EPA Substance Registry System
Retrorsine (480-54-6)
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Safety

Hazard Codes 
T
Risk Statements 
25
Safety Statements 
22-36/37/39-45
RIDADR 
1544
WGK Germany 
3
RTECS 
VH7525000
HazardClass 
6.1(a)
PackingGroup 
II
Hazardous Substances Data
480-54-6(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P262Do not get in eyes, on skin, or on clothing.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
R0382
Product name
Retrorsine
Purity
≥90% (HPLC)
Packaging
100mg
Price
$268
Updated
2025/07/31
Sigma-Aldrich
Product number
R0382
Product name
Retrorsine
Purity
≥90% (HPLC)
Packaging
500mg
Price
$923
Updated
2025/07/31
Sigma-Aldrich
Product number
PHL89775
Product name
Retrorsine
Purity
phyproof Reference Substance
Packaging
10mg
Price
$303
Updated
2025/07/31
American Custom Chemicals Corporation
Product number
API0009902
Product name
RETRORSINE
Purity
95.00%
Packaging
10MG
Price
$573.3
Updated
2021/12/16
Medical Isotopes, Inc.
Product number
48570
Product name
Retrorsine
Packaging
10mg
Price
$585
Updated
2021/12/16
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RETRORSINE Chemical Properties,Usage,Production

Uses

Retrorsine-D4 is a labelled analogue of Retrorsine (R279000). Retrorsine is a pyrrolizidine alkaloid that blocks the hepatocyte cell cycle, ultimately affecting hepatocyte proliferative capacity.

Definition

ChEBI: Retrorsine is a macrolide.

General Description

This substance is a primary reference substance with assigned absolute purity (considering chromatographic purity, water, residual solvents, inorganic impurities). The exact value can be found on the certificate. Produced by PhytoLab GmbH & Co. KG

Safety Profile

Poison by ingestion, intraperitoneal, and intravenous routes. Questionable carcinogen with experimental neoplastigenic and tumorigenic data. hhtation data reported. When heated to decomposition it emits toxic fumes of NOx.

in vivo

Retrorsine (30 mg/kg; i.p.; twice) impairs liver regeneration in the PBL model not only by an S or G2/M phase block, but also by a block located before the G1/S transition of the cell cycle[4].

Animal Model:Male Wistar rats (180±20 g), portal branch ligation (PBL) model[4]
Dosage:30 mg/kg
Administration:Intraperitoneal injection, twice, separated by 2-week interval
Result:Strongly impaired the liver weight gain, protein and DNA synthesis as well as induction of cell cycle related proteins in the regenerating lobes after PBL.

References

[1] C.C.J. CULVENOR. Hepato- and pneumotoxicity of pyrrolizidine alkaloids and derivatives in relation to molecular structure[J]. Chemico-Biological Interactions, 1976, 12 3: Pages 299-324. DOI: 10.1016/0009-2797(76)90046-6
[2] M. J. PESTCHANKER  O. S G. Pyrrolizidine Alkaloids from Five Senecio Species[J]. Journal of Natural Products , 1986, 49 4: 722-723. DOI: 10.1021/np50046a041
[3] YAN HONG LI. Assessment of pyrrolizidine alkaloid-induced toxicity in an in vitro screening model[J]. Journal of ethnopharmacology, 2013, 150 2: Pages 560-567. DOI: 10.1016/j.jep.2013.09.010

RETRORSINE Preparation Products And Raw materials

Raw materials

Preparation Products

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RETRORSINE Suppliers

RENI Pharmaceutical Technology Co., Ltd
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028-87865381 18108190480
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2881944542@qq.com
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China
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3308
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Chemsky(shanghai)International Co.,Ltd.
Tel
021-50135380
Email
shchemsky@sina.com
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China
ProdList
32321
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50
Dalian Meilun Biotech Co., Ltd.
Tel
0411-62910999 13889544652
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China
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Shanghai Tauto Biotech Co., Ltd.
Tel
021-51320588
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0086-21-51320502
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tauto@tautobiotech.com
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China
ProdList
3988
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66
ChemStrong Scientific Co.,Ltd
Tel
0755-0755-66853366 13670046396
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0755-28363542
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sales@chem-strong.com
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China
ProdList
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Wuxi Zhongkun Biochemical Technology Co., Ltd.
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0510-85629785 18013409632
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051085625359
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sales@reading-chemicals.com
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China
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Finetech Industry Limited
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027-87465837 19945049750
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027-8777-2287
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sales@finetechnology-ind.com
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China
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Sigma-Aldrich
Tel
021-61415566 800-8193336
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orderCN@merckgroup.com
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China
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ALB Technology Limited
Tel
702-983-3769
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702-983-3769
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United States
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Wuhan ChemFaces Biochemical Co., Ltd.
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18607101326 15172504745
Fax
+86-27-84254680
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China
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480-54-6, RETRORSINERelated Search:


  • BETA-LONGILOBINE
  • 12,18-DIHYDROXYSENECIONAN-11,16-DIONE
  • RETRORSIN
  • RETRORSINE
  • 16-dione,12,18-dihydroxy-senecionan-1
  • 5,6,9,11,13,14,14a,14b-decahydro-6-hydroxy-6-hydroxymethyl-5-3-ethylidene-4
  • cis-retronecicacidesterofretronecine
  • methyl(1,6)dioxacyclododeca(2,3,4-gh)pyrrolizidine-2,7-dione
  • Retrosine
  • trans-15-ethylidene-12beta-hydroxy-12alpha-hydroxymethyl-13beta-methylsenec-1-
  • RETRORSINE(AS)
  • β-Longilobine, 12,18-Dihydroxysenecionan-11,16-dione
  • β-Longilobine
  • Retrorcine
  • [1,6]Dioxacyclododecino[2,3,4-gh]pyrrolizine-2,7-dione, 3-ethylidene-3,4,5,6,9,11,13,14,14a,14b-decahydro-6-hydroxy-6-(hydroxymethyl)-5-methyl-, (3Z,5R,6S,14aR,14bR)-
  • Retrorsine 100 μg/mL in Water
  • 480-54-6
  • C18H23O5N