Benzotrifluoride

Product Name: Benzotrifluoride
CAS No.: 98-08-8
Chemical Name: Benzotrifluoride
Synonyms: α，α，α-Trifluorotoluene;TRIFLUORO TOLUENE;A,A,A-TRIFLUOROTOLUENE;Benzotrifluoide;Triflorotoluene;BENZOTRIFLOURIDE;ALPHA,ALPHA,ALPHA-TRIFLUOROTOLUENE;Oxsol2000;usafma-16;BenzotrifL
CBNumber: CB1292738
Molecular Formula: C7H5F3
Formula Weight: 146.11
MOL File: 98-08-8.mol

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Benzotrifluoride Property

Melting point:: −29 °C(lit.)
Boiling point:: 102 °C(lit.)
Density: 1.19 g/mL at 20 °C(lit.)
vapor density: 5.04
vapor pressure: 53 hPa (25 °C)
refractive index: n20/D 1.414(lit.)
Flash point:: 54 °F
storage temp.: Store below +30°C.
solubility: 0.45g/l Hydrolysis
form: Liquid
color: Clear colorless
Specific Gravity: 1.199
Odor: aromatic odor
explosive limit: 1.4-9.3%(V)
Water Solubility: <0.1 g/100 mL at 21 ºC
Merck: 14,1110
BRN: 1906908
Exposure limits: ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3
Dielectric constant: 9.4000000000000004
Dielectric constant: 9.4000000000000004
Dielectric constant: 39.0（20℃）
Stability:: Stable. Highly flammable. Incompatible with strong oxidizing agents, strong bases, strong reducing agents.
InChIKey: GETTZEONDQJALK-UHFFFAOYSA-N
LogP: 3.01 at 20℃
CAS DataBase Reference: 98-08-8(CAS DataBase Reference)
NIST Chemistry Reference: Benzene, (trifluoromethyl)-(98-08-8)
EPA Substance Registry System: Benzotrifluoride (98-08-8)

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Safety

Hazard Codes: F,T,C,N,Xn
Risk Statements: 45-46-11-36/38-48/23/24/25-65-51/53-39/23/24/25-23/24/25-48/20/22-40-38-22
Safety Statements: 53-26-36/37-45-62-61-23-16
RIDADR: UN 2338 3/PG 2
WGK Germany: 3
RTECS: XT9450000
Autoignition Temperature: 650 °C
Hazard Note: Flammable/Corrosive
TSCA: Yes
HazardClass: 3
PackingGroup: II
HS Code: 29049090
Hazardous Substances Data: 98-08-8(Hazardous Substances Data)
Toxicity: LD50 orally in Rabbit: 15000 mg/kg LD50 dermal Rat > 2000 mg/kg

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H304May be fatal if swallowed and enters airways

H315Causes skin irritation

H319Causes serious eye irritation

H340May cause genetic defects

H350May cause cancer

H372Causes damage to organs through prolonged or repeated exposure

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273Avoid release to the environment.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P331Do NOT induce vomiting.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 8.41554
Product name: Benzotrifluoride
Purity: for synthesis
Packaging: 100mL
Price: $48.7
Updated: 2024/03/01

Sigma-Aldrich

Product number: 733806
Product name: α,α,α-Trifluorotoluene solution
Purity: NMR reference standard, 0.05% in benzene-d6 (99.6 atom % D), NMR tube size 10?mm × 8?in.
Packaging: 1pkg
Price: $329
Updated: 2024/03/01

Sigma-Aldrich

Product number: 547948
Product name: α,α,α-Trifluorotoluene
Purity: anhydrous, ≥99%
Packaging: 1l
Price: $112
Updated: 2024/03/01

Sigma-Aldrich

Product number: 551406
Product name: α,α,α-Trifluorotoluene solution
Purity: NMR reference standard, 0.05% in benzene-d6 (99.6 atom % D)
Packaging: 1pkg
Price: $180
Updated: 2024/03/01

Sigma-Aldrich

Product number: 761427
Product name: α,α,α-Trifluorotoluene solution
Purity: NMR reference standard, 0.05% in chloroform-d ("100%", 99.96 atom % D), NMR tube size 5?mm × 8?in.
Packaging: 1pkg
Price: $189
Updated: 2022/05/15

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Benzotrifluoride Chemical Properties,Usage,Production

Chemical Properties

Benzotrifluoride is a colorless to light yellow liquid, low viscosity liquid. Its polarity is intermediate between those of dichloromethane and ethyl acetate, and it is miscible with common organic solvents and able to dissolve many organic compounds. Benzotrifluoride is used in a wide variety of reactions including radical reactions, oxidations and reductions, phase-transfer reactions, transition metal catalyzed processes andLewis acid reactions.

Uses

Benzotrifluoride is a useful alternative solvent for organic reactions currently conducted in dichloromethane and related solvents.

Uses

It is applied as an alternative solvent to dichloromethane, where it has a higher bp. It is used as an intermediate for dyes and pharmaceuticals, as a solvent and a dielectric fluid, a vulcanizing agent.

Uses

In dye chemistry; in the manufacture of substituted benzotrifluorides contg an ethylenic group, used in high polymer chemistry; in dielectric fluids, such as transformer oils.

Definition

ChEBI: (trifluoromethyl)benzene is a fluorohydrocarbon that is fluoroform in which the hydrogen is substituted by a phenyl group. It has a role as a solvent and an environmental contaminant. It is a fluorohydrocarbon and a member of (trifluoromethyl)benzenes. It derives from a fluoroform.

Synthesis Reference(s)

Synthesis, p. 932, 1980 DOI: 10.1055/s-1980-29276

General Description

A clear colorless liquid with an aromatic odor. Flash point of 54°F. Vapors are heavier than air. Insoluble in water and slightly denser than water. May be toxic by inhalation.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

Benzotrifluoride may react with oxidizing materials, strong bases and reducing agents.

Hazard

Highly toxic by inhalation. Flammable, dangerous fire risk.

Health Hazard

Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control may cause pollution.

Fire Hazard

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Flammability and Explosibility

Not classified

Safety Profile

Poison by intraperitoneal route.Moderately toxic by subcutaneous route. Dangerous fire hazard. To fight fire, usewater, foam, CO2, spray mist, dry chemical. When heatedto decomposition it emits toxic fumes of F??. Incompatiblewith oxidizing materials

Purification Methods

Purify benzotrifluoride by repeated treatment with boiling aqueous Na2CO3 (until no test for chloride ion is obtained), dry it with K2CO3, then with P2O5, and fractionally distil it. [Beilstein 5 IV 802.]

Benzotrifluoride Preparation Products And Raw materials

Raw materials

Chlorine Benzotrichloride Hydrogen fluoride

Preparation Products

2-Aminoquinoline Acifluorfen 2-Allylcyclohexanone 3-Nitrobenzotrifluoride 3-Bromobenzotrifluoride FENFLURAMINE Flutamide Fluotrimazol (1S)-(+)-3-Carene BENDROFLUMETHIAZIDE Fluoxetine Diflufenican 3,4-Dichlorobenzotrifluoride Trifluoroacetic acid 2-Amino-5-chlorobenzotrifluoride 4-Amino-6-(trifluoromethyl)benzene-1,3-disulfonamide 3-Chlorobenzotrifluoride (3-FLUORO-PHENYL)-METHANESULFONYL CHLORIDE 2,6-DICHLORO-4-(TRIFLUOROMETHYL)PHENYLHYDRAZINE 5-Methoxy-1-[4-(trifluoromethyl)phenyl]-1-pentanone 3-Aminobenzotrifluoride

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Benzotrifluoride Suppliers

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View Lastest Price from Benzotrifluoride manufacturers

Hebei Weibang Biotechnology Co., Ltd

Product: Benzotrifluoride BTF 98-08-8
Price: US $100.00/KG
Min. Order: 1KG
Purity: 99%min
Supply Ability: 200TON
Release date: 2024-10-31

Wuhan Boyuan Import & Export Co., LTD

Product: Benzotrifluoride 98-08-8
Price: US $20.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000tons
Release date: 2023-04-07

Hebei Mojin Biotechnology Co., Ltd

Product: Benzotrifluoride BTF 98-08-8
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-09-08

98-08-8, BenzotrifluorideRelated Search:

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BENZOTRIFLOURIDE

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benzylidynefluoride

omega-Trifluorotoluene

Oxsol2000

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