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4-Carboxyphenylboronic acid

Description Reference
Product Name
4-Carboxyphenylboronic acid
CAS No.
14047-29-1
Chemical Name
4-Carboxyphenylboronic acid
Synonyms
4-BORONOBENZOIC ACID;4-borono-benzoicaci;4-Carboxyphenylboronic;4-Carboxyphenylboronic acid, 97% 5GR;NSC 221170;AURORA 14935;AKOS BRN-0008;WLN: VHOR DBQQ;4-CarboxyphenyL;ZERENEX ZX001647
CBNumber
CB1312607
Molecular Formula
C7H7BO4
Formula Weight
165.94
MOL File
14047-29-1.mol
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4-Carboxyphenylboronic acid Property

Melting point:
220 °C (dec.) (lit.)
Boiling point:
406.4±47.0 °C(Predicted)
Density 
1.40±0.1 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
DMSO (Slightly), Methanol (Slightly), Water (Slightly)
pka
4.08±0.10(Predicted)
form 
Powder
color 
Off-white to light beige
BRN 
3031088
InChI
InChI=1S/C7H7BO4/c9-7(10)5-1-3-6(4-2-5)8(11)12/h1-4,11-12H,(H,9,10)
InChIKey
SIAVMDKGVRXFAX-UHFFFAOYSA-N
SMILES
C(O)(=O)C1=CC=C(B(O)O)C=C1
CAS DataBase Reference
14047-29-1(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-20/21/22
Safety Statements 
37/39-26-36
WGK Germany 
2
RTECS 
CY8925000
TSCA 
No
HazardClass 
IRRITANT
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H303May be harmfulif swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
456772
Product name
4-Carboxyphenylboronic acid
Packaging
1g
Price
$42.1
Updated
2024/03/01
Sigma-Aldrich
Product number
456772
Product name
4-Carboxyphenylboronic acid
Packaging
10g
Price
$363
Updated
2024/03/01
TCI Chemical
Product number
C1353
Product name
4-Carboxyphenylboronic Acid (contains varying amounts of Anhydride)
Packaging
1g
Price
$33
Updated
2024/03/01
TCI Chemical
Product number
C1353
Product name
4-Carboxyphenylboronic Acid (contains varying amounts of Anhydride)
Packaging
5g
Price
$99
Updated
2024/03/01
Alfa Aesar
Product number
B20954
Product name
4-Carboxybenzeneboronic acid, 97%
Packaging
1g
Price
$33.65
Updated
2024/03/01
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4-Carboxyphenylboronic acid Chemical Properties,Usage,Production

Description

4-Carboxyphenylboronic acid is a highly versatile reagent. It is a reagent used in various reactions including condensation reactions with stabilizer chains at the surface of polystyrene latex, Suzuki coupling reactions, esterification, derivatization of polyvinylamine, synthesis of isotopically labeled mercury and functionalization of poly-SiNW for detection of dopamine. It is reagents used for Suzuki-Miyaura cross-coupling, induction of pH sensitivity on fluorescence lifetime of quantum dots by NIR fluorescent dyes, bio-supported palladium nanoparticles as phosphine-free catalyst for Suzuki reaction in water and Chan-Lam-type Copper (Cu)-catalyzed S-arylation with aryl boronic acids at room temperature. It is reagents used for the preparation of isoquinolones via regioselective Suzuki-Miyaura cross-coupling and tandem palladium-catalyzed intramolecular aminocarbonylation and annulation, amprenavir-based P1-substituted bi-aryl derivatives as ultra-potent HIV-1 protease inhibitors, phenols via visible-light initiated aerobic oxidative hydroxylation of arylboronic acids using air as oxidant catalyzed by Ruthenium (Ru)-complex, glucose sensitive boronic acid-bearing block copolymers, trisulfonated calixarene upper-rim sulfonamido derivatives and their complexation with the trimethyllysine epigenetic mark. It can also be used as a corrosion inhibitor for steel.

Reference

  1. Nam, N. D., et al. "A study of 4-carboxyphenylboronic acid as a corrosion inhibitor for steel in carbon dioxide containing environments." Corrosion Science 76.10(2013):257-266.
  2. Vollmueller, Frank, et al. "Cyclization of 4-carboxyphenylboronic acid with hydrazide derivative; hydrolysis; catalytic esterification." US, US 6197967 B1. 2001.

Chemical Properties

Off-white to light beige powder

Uses

suzuki reaction

Uses

4-Carboxyphenylboronic acid is a reagent used in suzuki coupling reactions.

Uses

Intermediates of Liquid Crystals

4-Carboxyphenylboronic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Carboxyphenylboronic acid Suppliers

TCI Europe
Tel
320-37350700
Fax
+32 (0)37350701
Email
sales@tcieurope.eu
Country
Europe
ProdList
23671
Advantage
75
B&S Group B.V.
Tel
--
Fax
--
Email
a.sijrier@bs-group.com
Country
Europe
ProdList
324
Advantage
38
ecochem international chemical broker
Tel
--
Fax
--
Email
export@ecochem.dk
Country
Europe
ProdList
6371
Advantage
66
kemikalieimport
Tel
--
Fax
--
Email
Sales@kemikalieimport.dk
Country
Europe
ProdList
6685
Advantage
47
Discovery Fine Chemicals
Tel
--
Fax
--
Country
Europe
ProdList
1780
Advantage
38
Camida
Tel
--
Fax
--
Email
info@camida.com
Country
Europe
ProdList
3704
Advantage
71
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View Lastest Price from 4-Carboxyphenylboronic acid manufacturers

HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
Product
4-Carboxyphenylboronic acid 14047-29-1
Price
US $99.00-80.00/ton
Min. Order
1ton
Purity
99%
Supply Ability
5000
Release date
2024-08-21
Hebei Zhuanglai Chemical Trading Co Ltd
Product
4-Carboxyphenylboronic acid 14047-29-1
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 ton
Release date
2024-12-06
Hebei Weibang Biotechnology Co., Ltd
Product
4-Carboxyphenylboronic acid 14047-29-1
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
5tons
Release date
2024-12-02

14047-29-1, 4-Carboxyphenylboronic acidRelated Search:


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