Description Reference
ChemicalBook > CAS DataBase List > 4-Carboxyphenylboronic acid

4-Carboxyphenylboronic acid

Description Reference
Product Name
4-Carboxyphenylboronic acid
CAS No.
14047-29-1
Chemical Name
4-Carboxyphenylboronic acid
Synonyms
4-BORONOBENZOIC ACID;4-borono-benzoicaci;4-Carboxyphenylboronic;4-Carboxyphenylboronic acid, 97% 5GR;NSC 221170;AURORA 14935;AKOS BRN-0008;WLN: VHOR DBQQ;4-CarboxyphenyL;ZERENEX ZX001647
CBNumber
CB1312607
Molecular Formula
C7H7BO4
Formula Weight
165.94
MOL File
14047-29-1.mol
More
Less

4-Carboxyphenylboronic acid Property

Melting point:
220 °C (dec.) (lit.)
Boiling point:
406.4±47.0 °C(Predicted)
Density 
1.40±0.1 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
DMSO (Slightly), Methanol (Slightly), Water (Slightly)
pka
4.08±0.10(Predicted)
form 
Powder
color 
Off-white to light beige
BRN 
3031088
InChI
InChI=1S/C7H7BO4/c9-7(10)5-1-3-6(4-2-5)8(11)12/h1-4,11-12H,(H,9,10)
InChIKey
SIAVMDKGVRXFAX-UHFFFAOYSA-N
SMILES
C(O)(=O)C1=CC=C(B(O)O)C=C1
CAS DataBase Reference
14047-29-1(CAS DataBase Reference)
More
Less

Safety

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-20/21/22
Safety Statements 
37/39-26-36
WGK Germany 
2
RTECS 
CY8925000
TSCA 
No
HazardClass 
IRRITANT
HS Code 
29319090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H303May be harmfulif swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
456772
Product name
4-Carboxyphenylboronic acid
Packaging
1g
Price
$42.1
Updated
2024/03/01
Sigma-Aldrich
Product number
456772
Product name
4-Carboxyphenylboronic acid
Packaging
10g
Price
$363
Updated
2024/03/01
TCI Chemical
Product number
C1353
Product name
4-Carboxyphenylboronic Acid (contains varying amounts of Anhydride)
Packaging
1g
Price
$33
Updated
2024/03/01
TCI Chemical
Product number
C1353
Product name
4-Carboxyphenylboronic Acid (contains varying amounts of Anhydride)
Packaging
5g
Price
$99
Updated
2024/03/01
Alfa Aesar
Product number
B20954
Product name
4-Carboxybenzeneboronic acid, 97%
Packaging
1g
Price
$33.65
Updated
2024/03/01
More
Less

4-Carboxyphenylboronic acid Chemical Properties,Usage,Production

Description

4-Carboxyphenylboronic acid is a highly versatile reagent. It is a reagent used in various reactions including condensation reactions with stabilizer chains at the surface of polystyrene latex, Suzuki coupling reactions, esterification, derivatization of polyvinylamine, synthesis of isotopically labeled mercury and functionalization of poly-SiNW for detection of dopamine. It is reagents used for Suzuki-Miyaura cross-coupling, induction of pH sensitivity on fluorescence lifetime of quantum dots by NIR fluorescent dyes, bio-supported palladium nanoparticles as phosphine-free catalyst for Suzuki reaction in water and Chan-Lam-type Copper (Cu)-catalyzed S-arylation with aryl boronic acids at room temperature. It is reagents used for the preparation of isoquinolones via regioselective Suzuki-Miyaura cross-coupling and tandem palladium-catalyzed intramolecular aminocarbonylation and annulation, amprenavir-based P1-substituted bi-aryl derivatives as ultra-potent HIV-1 protease inhibitors, phenols via visible-light initiated aerobic oxidative hydroxylation of arylboronic acids using air as oxidant catalyzed by Ruthenium (Ru)-complex, glucose sensitive boronic acid-bearing block copolymers, trisulfonated calixarene upper-rim sulfonamido derivatives and their complexation with the trimethyllysine epigenetic mark. It can also be used as a corrosion inhibitor for steel.

Reference

  1. Nam, N. D., et al. "A study of 4-carboxyphenylboronic acid as a corrosion inhibitor for steel in carbon dioxide containing environments." Corrosion Science 76.10(2013):257-266.
  2. Vollmueller, Frank, et al. "Cyclization of 4-carboxyphenylboronic acid with hydrazide derivative; hydrolysis; catalytic esterification." US, US 6197967 B1. 2001.

Chemical Properties

Off-white to light beige powder

Uses

suzuki reaction

Uses

4-Carboxyphenylboronic acid is a reagent used in suzuki coupling reactions.

Uses

Intermediates of Liquid Crystals

4-Carboxyphenylboronic acid Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

4-Carboxyphenylboronic acid Suppliers

Dafeng Newti Pharmaceutical Technology Co., Ltd.
Tel
0512-62706796 13812758145
Email
2760994703@qq.com
Country
China
ProdList
276
Advantage
55
Hebei Maison Chemical Co.,Ltd.
Tel
0311-85381176 15511852758
Fax
0311-83832777
Email
ruby@maisonchem.com.cn
Country
China
ProdList
545
Advantage
58
Shanghai Youji Materials Co., Ltd
Tel
13052376889 13681663468
Email
2851911691@qq.com
Country
China
ProdList
824
Advantage
58
CE Pharm Co.,Ltd
Tel
15317222985
Fax
binbin.lin@cepharm.cn
Email
bingna.wang@cepharm.cn
Country
China
ProdList
141
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TAIYUAN RHF CO.,LTD.
Tel
+86 351 7031519
Fax
+86 351 7031519
Email
sales@RHFChem.com
Country
China
ProdList
2338
Advantage
56
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
ShangHai DEMO Chemical Co.,Ltd
Tel
400-021-7337 2355568890
Fax
0086-21-50182339
Email
sales@demochem.com
Country
China
ProdList
2572
Advantage
57
More
Less

View Lastest Price from 4-Carboxyphenylboronic acid manufacturers

HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
Product
4-Carboxyphenylboronic acid 14047-29-1
Price
US $99.00-80.00/ton
Min. Order
1ton
Purity
99%
Supply Ability
5000
Release date
2024-08-21
Hebei Zhuanglai Chemical Trading Co Ltd
Product
4-Carboxyphenylboronic acid 14047-29-1
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 ton
Release date
2024-12-06
Hebei Weibang Biotechnology Co., Ltd
Product
4-Carboxyphenylboronic acid 14047-29-1
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
5tons
Release date
2024-12-02

14047-29-1, 4-Carboxyphenylboronic acidRelated Search:


  • 4-borono-benzoicaci
  • AKOS BRN-0008
  • RARECHEM AH PB 0147
  • TIMTEC-BB SBB003899
  • OTAVA-BB BB7110951390
  • P-CARBOXYPHENYLBORONIC ACID
  • ZERENEX ZX001647
  • 4-(Dihydroxyboronyl)benzoic acid, 4-Boronobenzoic acid
  • 4-Carboxyphenylboron
  • 4-(dihydroxyboryl)benzoic acid(SALTDATA: FREE)
  • 4-Carboxyphenylboronic acid, 97% 5GR
  • 4-(Dihydroxyboryl)benzoic acid, 4-Boronobenzoic acid
  • 4-Carboxyborophenylic acid
  • p-Carboxyborophenylic acid
  • 4-Carboxyphenylboronic acid ,98%
  • 4-Carboxyphenylboronic acid, min. 97%
  • 4-Carboxyphenylboranic acid
  • 4-boronobenzoic acid,4-Carboxyphenylboronic acid
  • 4-Carboxyphenylboronic acid,97%
  • 4 - carboxyl benzene boric acid
  • hericium erinaceus p.e.
  • 4-Carboxyphenylboronic acid 4-(Dihydroxyboryl)benzoic acid
  • 4-Carboxylphenylboronic acid
  • 44-Carboxyphenylboronic acid
  • Benzeneboronic acid, p-carboxy-
  • Benzoic acid, p-borono-
  • WLN: VHOR DBQQ
  • 4-Hydroxycarbonylphenyl boronic acid
  • NSC 221170
  • Benzoic acid, 4-borono-
  • AURORA 14935
  • IFLAB-BB F1371-0202
  • 4-(DIHYDROXYBORYL)BENZOIC ACID
  • 4-(DIHYDROXYBORANE)BENZOIC ACID
  • 4-BORONOBENZOIC ACID
  • 4-CARBOXYBENZENEBORONIC ACID
  • 4-CARBOXYPHENYLBORONIC ACID
  • 4-Carboxyphenylboronic acid D4
  • 4-Carboxyphenylboronic acid≥ 99.5% (HPLC)
  • p-borono-benzoicaci
  • p-boronobenzoicacid
  • p-carboxy-benzeneboronicaci
  • p-carboxybenzeneboronicacid
  • 4-(Dihydroxyboronyl)benzoic acid
  • 4-Carboxypenylboronic Acid
  • 4-darboxybenzeneboronic acid
  • 4-Carboxyphenylboron dihydroxide
  • 4-Carboxyphenylboronic
  • 4-Carboxyphenylboronicacid,min.97%
  • 4-CARBOXYBENZENEBORONIC ACID 98%
  • 4-DIHYDROXYBORANYL-BENZOIC ACID
  • 4-Carboxyphenylboronic Acid (contains varying amounts of Anhydride)
  • 4-Carboxyphenylboronic acid, 98%, for synthesis
  • 4-CarboxyphenyL
  • 4-Carboxyphenylboronicaci
  • 4-Carboxyphenylboronic Acid extrapure, 97%
  • 14047-29-1
  • Boronic Acids and Derivatives