4-Carboxyphenylboronic acid
Description Reference- Product Name
- 4-Carboxyphenylboronic acid
- CAS No.
- 14047-29-1
- Chemical Name
- 4-Carboxyphenylboronic acid
- Synonyms
- 4-BORONOBENZOIC ACID;4-borono-benzoicaci;4-Carboxyphenylboronic;4-Carboxyphenylboronic acid, 97% 5GR;NSC 221170;AURORA 14935;AKOS BRN-0008;WLN: VHOR DBQQ;4-CarboxyphenyL;ZERENEX ZX001647
- CBNumber
- CB1312607
- Molecular Formula
- C7H7BO4
- Formula Weight
- 165.94
- MOL File
- 14047-29-1.mol
4-Carboxyphenylboronic acid Property
- Melting point:
- 220 °C (dec.) (lit.)
- Boiling point:
- 406.4±47.0 °C(Predicted)
- Density
- 1.40±0.1 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- solubility
- DMSO (Slightly), Methanol (Slightly), Water (Slightly)
- pka
- 4.08±0.10(Predicted)
- form
- Powder
- color
- Off-white to light beige
- BRN
- 3031088
- InChI
- InChI=1S/C7H7BO4/c9-7(10)5-1-3-6(4-2-5)8(11)12/h1-4,11-12H,(H,9,10)
- InChIKey
- SIAVMDKGVRXFAX-UHFFFAOYSA-N
- SMILES
- C(O)(=O)C1=CC=C(B(O)O)C=C1
- CAS DataBase Reference
- 14047-29-1(CAS DataBase Reference)
Safety
- Hazard Codes
- Xi,Xn
- Risk Statements
- 36/37/38-20/21/22
- Safety Statements
- 37/39-26-36
- WGK Germany
- 2
- RTECS
- CY8925000
- TSCA
- No
- HazardClass
- IRRITANT
- HS Code
- 29319090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H303May be harmfulif swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- 456772
- Product name
- 4-Carboxyphenylboronic acid
- Packaging
- 1g
- Price
- $42.1
- Updated
- 2024/03/01
- Product number
- 456772
- Product name
- 4-Carboxyphenylboronic acid
- Packaging
- 10g
- Price
- $363
- Updated
- 2024/03/01
- Product number
- C1353
- Product name
- 4-Carboxyphenylboronic Acid (contains varying amounts of Anhydride)
- Packaging
- 1g
- Price
- $33
- Updated
- 2024/03/01
- Product number
- C1353
- Product name
- 4-Carboxyphenylboronic Acid (contains varying amounts of Anhydride)
- Packaging
- 5g
- Price
- $99
- Updated
- 2024/03/01
- Product number
- B20954
- Product name
- 4-Carboxybenzeneboronic acid, 97%
- Packaging
- 1g
- Price
- $33.65
- Updated
- 2024/03/01
4-Carboxyphenylboronic acid Chemical Properties,Usage,Production
Description
4-Carboxyphenylboronic acid is a highly versatile reagent. It is a reagent used in various reactions including condensation reactions with stabilizer chains at the surface of polystyrene latex, Suzuki coupling reactions, esterification, derivatization of polyvinylamine, synthesis of isotopically labeled mercury and functionalization of poly-SiNW for detection of dopamine. It is reagents used for Suzuki-Miyaura cross-coupling, induction of pH sensitivity on fluorescence lifetime of quantum dots by NIR fluorescent dyes, bio-supported palladium nanoparticles as phosphine-free catalyst for Suzuki reaction in water and Chan-Lam-type Copper (Cu)-catalyzed S-arylation with aryl boronic acids at room temperature. It is reagents used for the preparation of isoquinolones via regioselective Suzuki-Miyaura cross-coupling and tandem palladium-catalyzed intramolecular aminocarbonylation and annulation, amprenavir-based P1-substituted bi-aryl derivatives as ultra-potent HIV-1 protease inhibitors, phenols via visible-light initiated aerobic oxidative hydroxylation of arylboronic acids using air as oxidant catalyzed by Ruthenium (Ru)-complex, glucose sensitive boronic acid-bearing block copolymers, trisulfonated calixarene upper-rim sulfonamido derivatives and their complexation with the trimethyllysine epigenetic mark. It can also be used as a corrosion inhibitor for steel.
Reference
- Nam, N. D., et al. "A study of 4-carboxyphenylboronic acid as a corrosion inhibitor for steel in carbon dioxide containing environments." Corrosion Science 76.10(2013):257-266.
- Vollmueller, Frank, et al. "Cyclization of 4-carboxyphenylboronic acid with hydrazide derivative; hydrolysis; catalytic esterification." US, US 6197967 B1. 2001.
Chemical Properties
Off-white to light beige powder
Uses
suzuki reaction
Uses
4-Carboxyphenylboronic acid is a reagent used in suzuki coupling reactions.
Uses
Intermediates of Liquid Crystals
4-Carboxyphenylboronic acid Preparation Products And Raw materials
Raw materials
Preparation Products
4-Carboxyphenylboronic acid Suppliers
- Tel
- 03-36680489
- Fax
- 03-3668-0520
- Sales-JP@TCIchemicals.com
- Country
- Japan
- ProdList
- 28398
- Advantage
- 80
View Lastest Price from 4-Carboxyphenylboronic acid manufacturers
- Product
- 4-Carboxyphenylboronic acid 14047-29-1
- Price
- US $34.00-1.20/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-04-08
- Product
- 4-Boronobenzoic acid 14047-29-1
- Price
- US $7.00-15.00/g
- Min. Order
- 5g
- Purity
- 0.98
- Supply Ability
- 100kg
- Release date
- 2023-12-14
- Product
- 4-Carboxyphenylboronic acid 14047-29-1
- Price
- US $50.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 10000tons
- Release date
- 2023-09-08