Reactions
ChemicalBook > CAS DataBase List > (2S,3S)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-met hyl-2,3-dihydrobenzo[d][1, 3]oxaphosphole

(2S,3S)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-met hyl-2,3-dihydrobenzo[d][1, 3]oxaphosphole

Reactions
Product Name
(2S,3S)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-met hyl-2,3-dihydrobenzo[d][1, 3]oxaphosphole
CAS No.
1373432-11-1
Chemical Name
(2S,3S)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-met hyl-2,3-dihydrobenzo[d][1, 3]oxaphosphole
Synonyms
ZJ-0040;(S,S)-Me-BI-DIME;(2S,3S)-Me-BIDIME;(2S,3S)-4-(2,6-Dimethoxyphenyl)-3-(tert-Butyl)-2,3-dihydro-2-methyl-1,3-benzoxaphosphole;(2S,3S)-3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2-methyl-2,3-dihydrobenzo[d][1,3]oxaphosphole;(2S,3S)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-met hyl-2,3-dihydrobenzo[d][1, 3]oxaphosphole;1,3-Benzoxaphosphole, 4-(2,6-dimethoxyphenyl)-3-(1,1-dimethylethyl)-2,3-dihydro-2-methyl-, (2S,3S)-;(2S,3S)-3-(T-BUTYL)-4-(2,6-DIMETHOXYPHENYL)-2-METHYL-2,3-DIHYDROBENZO[D][1,3]OXAPHOSPHOLE,MIN.97%(S,S)-ME-BI-DIME
CBNumber
CB13340359
Molecular Formula
C20H25O3P
Formula Weight
344.38
MOL File
1373432-11-1.mol
More
Less

(2S,3S)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-met hyl-2,3-dihydrobenzo[d][1, 3]oxaphosphole Property

Boiling point:
429.6±45.0 °C(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
crystal
color 
light-yellow
CAS DataBase Reference
1373432-11-1
More
Less

Safety

HS Code 
2931499090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Strem Chemicals
Product number
15-6220
Product name
(2S,3S)-3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2-methyl-2,3-dihydrobenzo[d][1,3]oxaphosphole, min. 97% (S,S)-Me-BI-DIME
Packaging
25mg
Price
$82
Updated
2024/03/01
Strem Chemicals
Product number
15-6220
Product name
(2S,3S)-3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2-methyl-2,3-dihydrobenzo[d][1,3]oxaphosphole, min. 97% (S,S)-Me-BI-DIME
Packaging
100mg
Price
$153
Updated
2024/03/01
Strem Chemicals
Product number
15-6220
Product name
(2S,3S)-3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2-methyl-2,3-dihydrobenzo[d][1,3]oxaphosphole, min. 97% (S,S)-Me-BI-DIME
Packaging
500mg
Price
$612
Updated
2024/03/01
ChemScene
Product number
CS-0087679
Product name
(S,S)-Me-BI-DIME
Purity
>97.0%
Packaging
100mg
Price
$143
Updated
2021/12/16
ChemScene
Product number
CS-0087679
Product name
(S,S)-Me-BI-DIME
Purity
>97.0%
Packaging
500mg
Price
$572
Updated
2021/12/16
More
Less

(2S,3S)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-met hyl-2,3-dihydrobenzo[d][1, 3]oxaphosphole Chemical Properties,Usage,Production

Reactions

Ligand/palladium catalyst for asymmetric Suzuki-Miyaura cross-coupling reactions.

(2S,3S)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-met hyl-2,3-dihydrobenzo[d][1, 3]oxaphosphole Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

(2S,3S)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-met hyl-2,3-dihydrobenzo[d][1, 3]oxaphosphole Suppliers

Daicel Chiral Technologies (China)CO.,LTD
Tel
021-50460086-9 15921403865
Fax
+86-21-50462321
Email
han_yajun@dctc.daicel.com
Country
China
ProdList
7195
Advantage
65
Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
41462
Advantage
60
LaaJoo
Tel
021-60702684 18516024827
Email
huang.jiayi@sinocompound.com
Country
China
ProdList
2409
Advantage
58
Greenherbs Science and Technology Development Co., Ltd.
Tel
010-61136123
Fax
+86 (10) 8857-9127
Email
pub02@greenherbs.com.cn
Country
China
ProdList
4049
Advantage
58
Aikon International Limited
Tel
025-66113011 18112977050
Fax
02557626880
Email
sales01@aikonchem.com
Country
China
ProdList
16027
Advantage
58
Rhawn Reagent
Tel
400-400-1332688 18019345275
Fax
400-133-2688
Email
amy@rhawn.cn
Country
China
ProdList
15497
Advantage
58
3A Chemicals
Tel
400-668-9898
Fax
010-51582189
Email
service@3achem.com
Country
China
ProdList
20557
Advantage
58
Shanghai Anyinuo Biomedical Technology Co., Ltd.
Tel
021-34625901
Email
420970979@qq.com
Country
China
ProdList
5783
Advantage
58
Shaoxing Zejun Pharmaceuticals Co.,Ltd
Tel
0575-82126188 15395856318
Email
service@zejunpharma.com
Country
China
ProdList
455
Advantage
58
Zhengzhou Akem Chemical Co., Ltd
Tel
13303867194
Email
3001317055@qq.com
Country
China
ProdList
9962
Advantage
58
Beijing Jin Ming Biotechnology Co., Ltd.
Tel
010-60605840 15801484223;
Email
psaitong@jm-bio.com
Country
China
ProdList
29774
Advantage
58
Shanghai Haohong Pharmaceutical Co., Ltd.
Tel
400-8210725 4008210725
Email
malulu@leyan.com
Country
China
ProdList
39995
Advantage
58
CHO Chemical Materials Chang Zhou CO., LTD
Tel
15995034354
Email
purchase@chochem.cn
Country
China
ProdList
2704
Advantage
58
Beijing Solarbio Science & Tecnology Co., Ltd.
Tel
010-50973130 17801761073
Email
Gsiyu@solarbio.com
Country
China
ProdList
50749
Advantage
58
Shanghai Jieshikai Biotechnology Co. , Ltd.
Tel
021-57520305 15221441005
Email
wangkang@jskchem.com
Country
China
ProdList
49234
Advantage
58
Shanghai Aladdin Biochemical Technology Co.,Ltd.
Tel
+86-18521732826
Email
market@aladdin-e.com
Country
China
ProdList
48461
Advantage
58
Nantong Hanfang Biotechnology Co. , Ltd.
Tel
18616537568
Email
hanfangpharma@126.com
Country
China
ProdList
29971
Advantage
58
Tianjin Rongshen Chemical Co., Ltd
Tel
18317763565 18317763565
Email
18317763565@163.com
Country
China
ProdList
10042
Advantage
58
Watson Biotechnology Co.,Ltd
Tel
+86-18186686046 +86-18186686046
Fax
+86-27-59524646
Email
sales01@watsonbiotech.cn
Country
China
ProdList
5841
Advantage
58
Wuhan Fortuna Chemical Co.,Ltd
Tel
+8618007136271
Email
hk@fortunachem.com
Country
China
ProdList
5998
Advantage
58
Shanghai Hao Zhun Biological Technology Co., Ltd.
Tel
--
Fax
--
Email
info@zzsrm.com
Country
CHINA
ProdList
6650
Advantage
58

1373432-11-1, (2S,3S)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-met hyl-2,3-dihydrobenzo[d][1, 3]oxaphospholeRelated Search:


  • (2S,3S)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-met hyl-2,3-dihydrobenzo[d][1, 3]oxaphosphole
  • (2S,3S)-Me-BIDIME
  • ZJ-0040
  • (S,S)-Me-BI-DIME
  • (2S,3S)-3-(T-BUTYL)-4-(2,6-DIMETHOXYPHENYL)-2-METHYL-2,3-DIHYDROBENZO[D][1,3]OXAPHOSPHOLE,MIN.97%(S,S)-ME-BI-DIME
  • (2S,3S)-4-(2,6-Dimethoxyphenyl)-3-(tert-Butyl)-2,3-dihydro-2-methyl-1,3-benzoxaphosphole
  • 1,3-Benzoxaphosphole, 4-(2,6-dimethoxyphenyl)-3-(1,1-dimethylethyl)-2,3-dihydro-2-methyl-, (2S,3S)-
  • (2S,3S)-3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2-methyl-2,3-dihydrobenzo[d][1,3]oxaphosphole
  • 1373432-11-1
  • Chiral Phosphine