ChemicalBook > CAS DataBase List > H-GLY-OIPR HCL

H-GLY-OIPR HCL

Product Name
H-GLY-OIPR HCL
CAS No.
14019-62-6
Chemical Name
H-GLY-OIPR HCL
Synonyms
H50249;Gly-OiPr·HCl;H-GLY-OIPR HCL;L-Gly-Oipr.HCL;Gly-OiPr hydrochloride;GLYCINE ISOPROPYL ESTER;GlycineisopropylesterHCl;H-GLY-OIPR HCL USP/EP/BP;Glycine 1-methylethyl ester HCl;ISOPROPYL GLYCINATE HYDROCHLORIDE
CBNumber
CB1342404
Molecular Formula
C5H12ClNO2
Formula Weight
153.61
MOL File
14019-62-6.mol
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H-GLY-OIPR HCL Property

storage temp. 
Sealed in dry,Room Temperature
Appearance
White to off-white Solid
Water Solubility 
Soluble in water
CAS DataBase Reference
14019-62-6
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Safety

Safety Statements 
22-24/25
HS Code 
2922498590
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P330Rinse mouth.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
I779015
Product name
Isopropyl2-AminoacetateHydrochloride
Packaging
10mg
Price
$45
Updated
2021/12/16
Usbiological
Product number
278602
Product name
Glycine isopropyl ester hydrochloride
Packaging
2g
Price
$333
Updated
2021/12/16
Activate Scientific
Product number
AS102611
Product name
Glycine 1-methylethyl ester HCl
Purity
95%
Packaging
100g
Price
$473
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
AAA0010823
Product name
ISOPROPYL-2-AMINOACETATE HYDROCHLORIDE
Purity
95.00%
Packaging
5MG
Price
$500.06
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
AAA0010823
Product name
ISOPROPYL-2-AMINOACETATE HYDROCHLORIDE
Purity
95.00%
Packaging
1G
Price
$529
Updated
2021/12/16
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H-GLY-OIPR HCL Chemical Properties,Usage,Production

Chemical Properties

White powder

Uses

Glycine isopropyl ester hydrochloride can react with indol-3-yl-oxo-acetyl chloride to produce [2-(1H-indol-3-yl)-2-oxo-acetylamino]-acetic acid isopropyl ester. This reaction will need reagent Et3N, and the menstruum benzene.

Synthesis

67-63-0

56-40-6

14019-62-6

1. dissolve glycine (1 g, 13.3 mmol) in isopropanol (10 mL) at 0 °C. 2. sulfoxide chloride (SOCl2, 1.93 mL, 26.6 mmol) was added slowly and dropwise to the above solution. 3. the reaction mixture was heated to reflux and stirred continuously overnight. 4. Upon completion of the reaction, it was cooled to room temperature and the solvent was subsequently removed by evaporation under reduced pressure. 5. Hexane was added to the residue at 0 °C to form a suspension. 6. The suspension was filtered and the white solid product isopropyl 2-aminoacetate hydrochloride (1.76 g, 86% yield) was collected. 7. The product was characterized as follows. 7. The product was characterized as follows: - 1H NMR (300 MHz, MeOD) δ 5.13 (hept, J = 6.3 Hz, 1H, (CH3)2CHO), 3.81 (s, 2H, CH2), 1.32 (s, 3H, (CH3)2CHO), 1.30 (s, 3H, (CH3)2CHO). 13C NMR (75 MHz, MeOD) δ 1.30 (s, 3H, (CH3)2CHO). - 13C NMR (75 MHz, MeOD) δ 168.0 (C), 71.7 ((CH3)2CHO), 41.2 (CH2), 21.9 ((CH3)2CHO). - HRMS [M + H]+ C5H12NO2: calculated value 118.0858, measured value 118.0863.

References

[1] RSC Advances, 2017, vol. 7, # 17, p. 10158 - 10174
[2] ACS Medicinal Chemistry Letters, 2016, vol. 7, # 12, p. 1197 - 1201
[3] Patent: WO2015/1024, 2015, A1. Location in patent: Page/Page column 93
[4] European Journal of Organic Chemistry, 2001, # 10, p. 1971 - 1982
[5] ChemSusChem, 2011, vol. 4, # 5, p. 604 - 608

H-GLY-OIPR HCL Preparation Products And Raw materials

Raw materials

Preparation Products

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H-GLY-OIPR HCL Suppliers

Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44802
Advantage
61
Beijing Ouhe Technology Co., Ltd
Tel
13552068683 13522913783
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
11780
Advantage
60
Adamas Reagent, Ltd.
Tel
400-6009262 15618770481
Fax
021-64823266
Email
yhx@titansci.com
Country
China
ProdList
14100
Advantage
59
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42934
Advantage
64
Beijing HuaMeiHuLiBiological Chemical
Tel
010-56205725
Fax
010-65763397
Email
waley188@sohu.com
Country
China
ProdList
12335
Advantage
58
Baiyin Chengze Chemical Technology Co., Ltd.
Tel
+86 943-8535351 13389336721
Fax
+86-943-8535351
Email
sales@chengzechem.com
Country
China
ProdList
289
Advantage
58
NovoChemy Ltd.
Tel
021-31261262/ 49 (0)17662837245
Fax
(0)21-33250524
Email
sales@novochemy.com
Country
Germany
ProdList
6328
Advantage
58
Shanghai Topbiochem Technology Co., Ltd
Tel
021-58170097
Email
info@topbiochem.com
Country
China
ProdList
9520
Advantage
58
Bide Pharmatech Ltd.
Tel
400-400-164-7117 18317119277
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
39999
Advantage
60
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View Lastest Price from H-GLY-OIPR HCL manufacturers

Sichuan HongRi Pharma-Tech Co.,Ltd
Product
H-Gly-Oipr. HCL 14019-62-6
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1T+
Release date
2024-03-24
Henan Aochuang Chemical Co.,Ltd.
Product
H-GLY-OIPR HCL 14019-62-6
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-09-29
Career Henan Chemical Co
Product
H-GLY-OIPR HCL 14019-62-6
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20kg
Release date
2018-08-15

14019-62-6, H-GLY-OIPR HCLRelated Search:


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  • Glycine isopropyl ester hydrochloride≥ 98% (HPLC)
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  • H-GLY-OIPR HCL
  • ISOPROPYL GLYCINATE HYDROCHLORIDE
  • GLYCINE ISOPROPYL ESTER
  • GLYCINE ISOPROPYL ESTER HYDROCHLORIDE
  • GLYCINE ALPHA-ISOPROPYL ESTER HYDROCHLORIDE
  • GlycineisopropylesterHCl
  • H50249
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  • Glycine 1-methylethyl ester HCl
  • Isopropyl 2-Aminoacetate Hydrocholride
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