H-GLY-OIPR HCL
- Product Name
- H-GLY-OIPR HCL
- CAS No.
- 14019-62-6
- Chemical Name
- H-GLY-OIPR HCL
- Synonyms
- H50249;Gly-OiPr·HCl;H-GLY-OIPR HCL;L-Gly-Oipr.HCL;Gly-OiPr hydrochloride;GLYCINE ISOPROPYL ESTER;GlycineisopropylesterHCl;H-GLY-OIPR HCL USP/EP/BP;Glycine 1-methylethyl ester HCl;ISOPROPYL GLYCINATE HYDROCHLORIDE
- CBNumber
- CB1342404
- Molecular Formula
- C5H12ClNO2
- Formula Weight
- 153.61
- MOL File
- 14019-62-6.mol
H-GLY-OIPR HCL Property
- storage temp.
- Sealed in dry,Room Temperature
- Appearance
- White to off-white Solid
- Water Solubility
- Soluble in water
- CAS DataBase Reference
- 14019-62-6
Safety
- Safety Statements
- 22-24/25
- HS Code
- 2922498590
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P330Rinse mouth.
P403+P233Store in a well-ventilated place. Keep container tightly closed.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- I779015
- Product name
- Isopropyl2-AminoacetateHydrochloride
- Packaging
- 10mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- 278602
- Product name
- Glycine isopropyl ester hydrochloride
- Packaging
- 2g
- Price
- $333
- Updated
- 2021/12/16
- Product number
- AS102611
- Product name
- Glycine 1-methylethyl ester HCl
- Purity
- 95%
- Packaging
- 100g
- Price
- $473
- Updated
- 2021/12/16
- Product number
- AAA0010823
- Product name
- ISOPROPYL-2-AMINOACETATE HYDROCHLORIDE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $500.06
- Updated
- 2021/12/16
- Product number
- AAA0010823
- Product name
- ISOPROPYL-2-AMINOACETATE HYDROCHLORIDE
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $529
- Updated
- 2021/12/16
H-GLY-OIPR HCL Chemical Properties,Usage,Production
Chemical Properties
White powder
Uses
Glycine isopropyl ester hydrochloride can react with indol-3-yl-oxo-acetyl chloride to produce [2-(1H-indol-3-yl)-2-oxo-acetylamino]-acetic acid isopropyl ester. This reaction will need reagent Et3N, and the menstruum benzene.
Synthesis
67-63-0
56-40-6
14019-62-6
1. dissolve glycine (1 g, 13.3 mmol) in isopropanol (10 mL) at 0 °C. 2. sulfoxide chloride (SOCl2, 1.93 mL, 26.6 mmol) was added slowly and dropwise to the above solution. 3. the reaction mixture was heated to reflux and stirred continuously overnight. 4. Upon completion of the reaction, it was cooled to room temperature and the solvent was subsequently removed by evaporation under reduced pressure. 5. Hexane was added to the residue at 0 °C to form a suspension. 6. The suspension was filtered and the white solid product isopropyl 2-aminoacetate hydrochloride (1.76 g, 86% yield) was collected. 7. The product was characterized as follows. 7. The product was characterized as follows: - 1H NMR (300 MHz, MeOD) δ 5.13 (hept, J = 6.3 Hz, 1H, (CH3)2CHO), 3.81 (s, 2H, CH2), 1.32 (s, 3H, (CH3)2CHO), 1.30 (s, 3H, (CH3)2CHO). 13C NMR (75 MHz, MeOD) δ 1.30 (s, 3H, (CH3)2CHO). - 13C NMR (75 MHz, MeOD) δ 168.0 (C), 71.7 ((CH3)2CHO), 41.2 (CH2), 21.9 ((CH3)2CHO). - HRMS [M + H]+ C5H12NO2: calculated value 118.0858, measured value 118.0863.
References
[1] RSC Advances, 2017, vol. 7, # 17, p. 10158 - 10174
[2] ACS Medicinal Chemistry Letters, 2016, vol. 7, # 12, p. 1197 - 1201
[3] Patent: WO2015/1024, 2015, A1. Location in patent: Page/Page column 93
[4] European Journal of Organic Chemistry, 2001, # 10, p. 1971 - 1982
[5] ChemSusChem, 2011, vol. 4, # 5, p. 604 - 608
H-GLY-OIPR HCL Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from H-GLY-OIPR HCL manufacturers
- Product
- H-Gly-Oipr. HCL 14019-62-6
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1T+
- Release date
- 2024-03-24
- Product
- H-GLY-OIPR HCL 14019-62-6
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1ton
- Release date
- 2022-09-29
- Product
- H-GLY-OIPR HCL 14019-62-6
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20kg
- Release date
- 2018-08-15