H-ASP(OTBU)-OTBU HCL
- Product Name
- H-ASP(OTBU)-OTBU HCL
- CAS No.
- 1791-13-5
- Chemical Name
- H-ASP(OTBU)-OTBU HCL
- Synonyms
- Asp(OtBu)2.Hcl;H-Asp(OtBu)-OtBu;H-ASP(OBUT)-OBUT·HCL;H-Asp(Obut)-Otbu HCl;L-Asp(OtBu)-OtBu·HCl;H-ASP(OBUT)-OBUT HCL;H-ASP(OTBU)-OTBU HCL;H-L-Asp(tBu)-OtBu*HCl;H-L-Asp(OtBu)-OtBu·HCl;ASPARTIC ACID(OTBU)-OTBU HCL
- CBNumber
- CB0663816
- Molecular Formula
- C12H24ClNO4
- Formula Weight
- 281.78
- MOL File
- 1791-13-5.mol
H-ASP(OTBU)-OTBU HCL Property
- Melting point:
- 152-155 °C
- storage temp.
- Inert atmosphere,Store in freezer, under -20°C
- solubility
- soluble in Methanol
- form
- Solid
- color
- White to Almost white
- optical activity
- 10.6596°(C=1.0045g/100ml ETOH)
- BRN
- 5652807
- InChIKey
- GVLZIMQSYQDAHB-QRPNPIFTSA-N
- CAS DataBase Reference
- 1791-13-5
Safety
- WGK Germany
- 3
- F
- 10-21
- HS Code
- 29224999
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- D4422
- Product name
- Di-tert-butyl L-Aspartate Hydrochloride
- Purity
- >98.0%(HPLC)(T)
- Packaging
- 5g
- Price
- $60
- Updated
- 2025/07/31
- Product number
- D4422
- Product name
- Di-tert-butyl L-Aspartate Hydrochloride
- Purity
- >98.0%(HPLC)(T)
- Packaging
- 25g
- Price
- $205
- Updated
- 2025/07/31
- Product number
- A788870
- Product name
- L-Aspartic acid di-tert-butyl ester hydrochloride
- Packaging
- 10g
- Price
- $305
- Updated
- 2021/12/16
- Product number
- 260430
- Product name
- L-Aspartic acid di-tert-butyl ester hydrochloride
- Packaging
- 1g
- Price
- $326
- Updated
- 2021/12/16
- Product number
- A788870
- Product name
- L-Aspartic acid di-tert-butyl ester hydrochloride
- Packaging
- 250mg
- Price
- $45
- Updated
- 2021/12/16
H-ASP(OTBU)-OTBU HCL Chemical Properties,Usage,Production
Chemical Properties
White powder
Uses
L-Aspartic acid di-tert-butyl ester hydrochloride may be used in neurological comparison studies with structurally similar compounds such as L-Glutamic acid di-tert-butyl ester.
Biochem/physiol Actions
L-Aspartic acid di-tert-butyl ester hydrochloride may be used in neurological comparison studies with structurally similar compounds such as L-Glutamic acid di-tert-butyl ester (G7501).
Synthesis
42417-76-5
1791-13-5
General procedure for the synthesis of di-tert-butyl (S)-2-aminosuccinate hydrochloride from Cbz-Asp(OtBu)-OtBu 18: Pd/C (10%, 830 mg, 10% w/w) was added to an ethanol solution of Cbz-Asp(OtBu)-OtBu 18 (8.25 g, 21.8 mmol) and ammonium formate (34.3 g, 0.54 mol). ) in an ethanol solution (20 mL). The suspension was stirred overnight at room temperature. Upon completion of the reaction, the suspension was filtered through diatomaceous earth and the solvent was removed under reduced pressure. The resulting residue was dissolved in ethyl acetate and the solution was cooled to 0°C. Subsequently, an ethyl acetate solution saturated with HCl was added dropwise and stirred for 15 minutes. The precipitated solid was filtered, washed with cold ethyl acetate and dried under vacuum to afford NH2-Asp(OtBu)-OtBu hydrochloride 16 (4.28 g, 17.4 mmol, 80% yield) as a white solid, which can be used in subsequent reactions without further purification.
References
[1] Tetrahedron, 2014, vol. 70, # 44, p. 8343 - 8347
H-ASP(OTBU)-OTBU HCL Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from H-ASP(OTBU)-OTBU HCL manufacturers
- Product
- H-L-Asp(OtBu)-OtBu·HCl 1791-13-5
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1T+
- Release date
- 2024-02-23
- Product
- H-ASP(OTBU)-OTBU HCL 1791-13-5
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20kg
- Release date
- 2018-08-22