Tetrakis(triphenylphosphine)nickel

Product Name: Tetrakis(triphenylphosphine)nickel
CAS No.: 15133-82-1
Chemical Name: Tetrakis(triphenylphosphine)nickel
Synonyms: Ni(PPh3)4;Nickel - triphenylphosphine (1:4);Tetrakis(triphenylphosphine)nickel;NICKEL-TETRAKIS(TRIPHENYLPHOSPHINE);Tetrakis-(triphenylphosphino)-nickel;TETRAKIS(TRIPHENYLPHOSPHINE)NICKEL(O);TETRAKIS(TRIPHENYLPHOSPHINE)NICKEL(0);Tetrakis(triphenylphosphine)nickel,95%;Tetrakis(triphenylphosphine)nickel(0),95%;Nickel, tetrakis(triphenylphosphine)-, (T-4)-
CBNumber: CB1346679
Molecular Formula: C72H60NiP4
Formula Weight: 1107.84
MOL File: 15133-82-1.mol

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Tetrakis(triphenylphosphine)nickel Property

Melting point:: 123-128°C
storage temp.: Inert atmosphere,Room Temperature
solubility: sol DMF, DMA, THF, acetonitrile, benzene; slightly sol Et2O; very slightly sol n-heptane, EtOH
form: Fine Powder
color: Rust-brown to brown
Water Solubility: Insoluble in water.
Sensitive: Air Sensitive
Exposure limits: NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
CAS DataBase Reference: 15133-82-1

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Safety

Hazard Codes: Xn,F
Risk Statements: 40-43-11
Safety Statements: 36/37-36-22
RIDADR: UN 1325 4.1/PG 2
WGK Germany: 3
F: 1-10
HazardClass: 4.2
PackingGroup: II
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H228Flammable solid

H317May cause an allergic skin reaction

H351Suspected of causing cancer

Precautionary statements

P201Obtain special instructions before use.

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 244996
Product name: Tetrakis(triphenylphosphine)nickel(0)
Purity: Ni 4-7 % (approx.)
Packaging: 1g
Price: $147
Updated: 2024/03/01

Sigma-Aldrich

Product number: 244996
Product name: Tetrakis(triphenylphosphine)nickel(0)
Purity: Ni 4-7 % (approx.)
Packaging: 5g
Price: $249.6
Updated: 2024/03/01

Alfa Aesar

Product number: 032101
Product name: Tetrakis(triphenylphosphine)nickel(0)
Packaging: 1g
Price: $139.65
Updated: 2024/03/01

ChemScene

Product number: CS-0042298
Product name: Ni(PPh3)4
Purity: >97.0%
Packaging: 1g
Price: $98
Updated: 2021/12/16

ChemScene

Product number: CS-0042298
Product name: Ni(PPh3)4
Purity: >97.0%
Packaging: 250mg
Price: $50
Updated: 2021/12/16

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Tetrakis(triphenylphosphine)nickel Chemical Properties,Usage,Production

Chemical Properties

rust-brown to brown fine powder

Uses

Tetrakis(triphenylphosphine)nickel(0) is a catalyst for coupling reactions of organic halides, organometallic compounds and also for the cyclooligomerization of cumulenes.

Uses

Catalyst for coupling reactions of organic halides, organometallic Compounds and also for the cyclooligomerization of cumulenes;.

Preparation

The standard preparation of Tetrakis(triphenylphosphine)nickel involves the reduction of Nickel(II) Acetylacetonate with Triethylaluminum in the presence of Triphenylphosphine. To 21.3 g of anhydrous Ni(acac)2 and 125 g PPh3 in 800 mL of Et2O under N2 at 0°C is slowly added 28.0 g Et3Al. The reddish-brown precipitate is collected, washed with Et2O, and twice dissolved in benzene and reprecipitated by the addition of n-heptane to give about 50 g (55%) of Ni(PPh3)4.

reaction suitability

core: nickel
reagent type: catalyst

storage

Tetrakis(triphenylphosphine)nickel is highly oxygen sensitive. Special inert-atmosphere techniques must be used. Should be stored at 0 °C. Cancer suspect agent.

Tetrakis(triphenylphosphine)nickel Preparation Products And Raw materials

Raw materials

Preparation Products

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Tetrakis(triphenylphosphine)nickel Suppliers

Belgium 1 China 104 Germany 4 India 3 Japan 1 Russia 1 Switzerland 1 Ukraine 1 United Kingdom 1 United States 13 Global 130

Fujian Wolfa Biotechnology Co., Ltd

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J & K SCIENTIFIC LTD.

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Beijing Donghualituo Techonlogy Development Co.,Ltd.

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INTATRADE GmbH

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Alfa Aesar

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Energy Chemical

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Shandong Xiya Chemical Co., Ltd

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Email: 3007715519@qq.com
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View Lastest Price from Tetrakis(triphenylphosphine)nickel manufacturers

Career Henan Chemical Co

Product: Nickel - triphenylphosphine (1:4) 15133-82-1
Price: US $3.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 1kg,5kg,50kg
Release date: 2020-01-18

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Tetrakis(triphenylphosphine)nickel

Nickel - triphenylphosphine (1:4)

TETRAKIS(TRIPHENYLPHOSPHINE)NICKEL(0)

TETRAKIS(TRIPHENYLPHOSPHINE)NICKEL(O)

NICKEL-TETRAKIS(TRIPHENYLPHOSPHINE)

Tetrakis(triphenylphosphine)nickel(0), approx. 4-7% Ni

Nickel, tetrakis(triphenylphosphine)-, (T-4)-

Tetrakis-(triphenylphosphino)-nickel

Tetrakis(triphenylphosphine)nickel(0),95%

Tetrakis(triphenylphosphine)nickel,95%

Tetrakis(triphenylphosphine)nickel(0) Ni 4-7 % (approx.)

Ni(PPh3)4

Tetrakis(triphenylphosphine)nickel(0), 95%, for synthesis

Tetrakis(triphenylphosphine)nickel ISO 9001：2015 REACH

15133-82-1

4C18H15PNi

NiPC6H534

4C18H15PNiC72H60NiP4

C6H53P4Ni

C72H60NiP4

Catalysis and Inorganic Chemistry

Ni