ETHOXY-IMINO-ACETIC ACID ETHYL ESTER
- Product Name
- ETHOXY-IMINO-ACETIC ACID ETHYL ESTER
- CAS No.
- 816-27-3
- Chemical Name
- ETHOXY-IMINO-ACETIC ACID ETHYL ESTER
- Synonyms
- Ethyl 2-ethoxy-2-iminoacetate;2-ethoxy-2-iminoacetate;Ethyl ethoxyiminoacetate;Ethyl 2-ethoxy-iminoacetate;Ethyl carboethoxyformidimate;Ethyl 1-carbethoxyformimidate;Ethyl ethoxycarbonylformimidate;ETHOXY-IMINO-ACETIC ACID ETHYL ESTER;Acetic acid, ethoxyimino-, ethyl ester;2-Ethoxy-2-iminoacetic acid ethyl ester
- CBNumber
- CB1351899
- Molecular Formula
- C6H11NO3
- Formula Weight
- 145.16
- MOL File
- 816-27-3.mol
ETHOXY-IMINO-ACETIC ACID ETHYL ESTER Property
- Boiling point:
- 151℃
- Density
- 1.08
- refractive index
- n20/D1.426
- Flash point:
- 45℃
- storage temp.
- -20°C
- pka
- 3.21±0.70(Predicted)
- form
- liquid
- color
- Clear, light yellow
- InChI
- InChI=1S/C6H11NO3/c1-3-9-5(7)6(8)10-4-2/h7H,3-4H2,1-2H3
- InChIKey
- DSHWMBCJDOGPTB-UHFFFAOYSA-N
- SMILES
- C(OCC)(=O)C(OCC)=N
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 790419
- Product name
- Ethyl 2-ethoxy-2-iminoacetate
- Packaging
- 500mg
- Price
- $116.2
- Updated
- 2025/07/31
- Product number
- E917918
- Product name
- Ethyl 2-ethoxy-2-iminoacetate
- Packaging
- 100mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- 4156-1-80
- Product name
- Ethyl 2-ethoxy-2-iminoacetate
- Packaging
- 500mg
- Price
- $72
- Updated
- 2021/12/16
- Product number
- 4156-1-80
- Product name
- Ethyl 2-ethoxy-2-iminoacetate
- Packaging
- 1g
- Price
- $120
- Updated
- 2021/12/16
- Product number
- 087166
- Product name
- Ethyl ethoxyiminoacetate
- Purity
- 95%
- Packaging
- 5g
- Price
- $264
- Updated
- 2021/12/16
ETHOXY-IMINO-ACETIC ACID ETHYL ESTER Chemical Properties,Usage,Production
Synthesis
64-17-5
623-49-4
816-27-3
Ethyl cyanoacetate (40 g, 404 mmol) was dissolved in dichloromethane (200 mL) and cooled to 0°C under nitrogen protection. An ethanol solution of 45 wt.% hydrochloric acid (27.3 mL, 404 mmol) was added slowly and dropwise over 15 min with stirring. The reaction mixture was stirred continuously at 0 °C for 3 h, followed by standing overnight at -5 °C to -3 °C. The following day, dichloromethane (250 mL) was added to the reaction mixture and kept at 0 °C. A solution of triethylamine (113 mL, 807 mmol) in dichloromethane (50 mL) was added dropwise over 30 minutes. After the dropwise addition, the mixture was continued to be stirred at 0°C for 30 minutes. Subsequently, water (100 mL) was added and stirred for 5 minutes. The organic layer was separated, dried over anhydrous sodium sulfate and concentrated under reduced pressure. Diethyl ether (50 mL) was added to the residue and the solid was removed by filtration. The filtrate was dried to give ethyl 2-ethoxy-2-iminoacetate as a light yellow liquid (31.0 g, 214 mmol, 52.9% yield). NMR hydrogen spectrum (400 MHz, CDCl3) δ 8.78 (s, 1H), 4.36-4.28 (m, 4H), 1.40-1.35 (m, 6H).
References
[1] Synthesis, 1997, # 3, p. 301 - 304
[2] Patent: WO2018/154520, 2018, A1. Location in patent: Page/Page column 92
[3] Helvetica Chimica Acta, 1989, vol. 72, p. 825 - 837
[4] Helvetica Chimica Acta, 1989, vol. 72, p. 825 - 837
[5] Patent: WO2009/155121, 2009, A2. Location in patent: Page/Page column 106
ETHOXY-IMINO-ACETIC ACID ETHYL ESTER Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from ETHOXY-IMINO-ACETIC ACID ETHYL ESTER manufacturers
- Product
- ETHOXY-IMINO-ACETIC ACID ETHYL ESTER 816-27-3
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98.0%
- Supply Ability
- 10000KGS
- Release date
- 2025-07-04
- Product
- ethyl 2-ethoxy-2-iminoacetate 816-27-3
- Price
- US $20.00/g
- Min. Order
- 1g
- Purity
- 98%HPLC
- Supply Ability
- 20kg
- Release date
- 2023-06-13
- Product
- ETHOXY-IMINO-ACETIC ACID ETHYL ESTER 816-27-3
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 95-99%
- Supply Ability
- 500kg/month
- Release date
- 2019-08-01