ChemicalBook > CAS DataBase List > N-(Hydroxymethyl)phthalimide

N-(Hydroxymethyl)phthalimide

Product Name
N-(Hydroxymethyl)phthalimide
CAS No.
118-29-6
Chemical Name
N-(Hydroxymethyl)phthalimide
Synonyms
AURORA KA-454;N-(HydroxymethyL;AKOS BBS-00004724;PHTHALIMIDOMETHANOL;IFLAB-BB F0777-0575;N-(Hydroxymethyl)ph;oxymethylphthalimide;Phthalimidylmethanol;N-Methylolphthalimide;Oxymethyl phthalimide
CBNumber
CB1392676
Molecular Formula
C9H7NO3
Formula Weight
177.16
MOL File
118-29-6.mol
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N-(Hydroxymethyl)phthalimide Property

Melting point:
147-149 °C (lit.)
Boiling point:
309.06°C (rough estimate)
Density 
1.3312 (rough estimate)
refractive index 
1.5200 (estimate)
storage temp. 
Store below +30°C.
pka
13.17±0.10(Predicted)
form 
Fine Crystalline Powder
color 
White
BRN 
140946
InChIKey
MNSGOOCAMMSKGI-UHFFFAOYSA-N
CAS DataBase Reference
118-29-6(CAS DataBase Reference)
NIST Chemistry Reference
1H-isoindole-1,3(2h)-dione, 2-(hydroxymethyl)-(118-29-6)
EPA Substance Registry System
N-(Hydroxymethyl)phthalimide (118-29-6)
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Safety

Safety Statements 
22-24/25
WGK Germany 
3
RTECS 
TI5270000
TSCA 
Yes
HS Code 
29251995
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.14422
Product name
N-(Hydroxymethyl)-phthalimide
Purity
for synthesis
Packaging
100 g
Price
$46.8
Updated
2021/03/22
Sigma-Aldrich
Product number
8.14422
Product name
N-(Hydroxymethyl)-phthalimide for synthesis. CAS 118-29-6, molar mass 177.16 g/mol., for synthesis
Packaging
8144220100
Price
$48.9
Updated
2020/08/18
Sigma-Aldrich
Product number
H41803
Product name
N-(Hydroxymethyl)phthalimide
Purity
97%
Packaging
100g
Price
$114
Updated
2021/03/22
TCI Chemical
Product number
H0648
Product name
N-Hydroxymethylphthalimide
Purity
>98.0%(HPLC)(N)
Packaging
25g
Price
$30
Updated
2021/03/22
TCI Chemical
Product number
H0648
Product name
N-Hydroxymethylphthalimide
Purity
>98.0%(HPLC)(N)
Packaging
250g
Price
$113
Updated
2021/03/22
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N-(Hydroxymethyl)phthalimide Chemical Properties,Usage,Production

Chemical Properties

white crystalline powder

Definition

ChEBI: A primary alcohol comprising phthalimide carrying an N-hydroxymethyl substituent.

Preparation

To a flask equipped with a mechanical stirrer and condenser is added 511 gm (3.47 moles) of phthalimide, 260 ml of 40% formalin (3.47 moles), and 1750 ml of water. The mixture is refluxed for about 5-10 min or until a clear solution results (if any insoluble material remains, it is first filtered). Then the mixture is cooled for several hours. The resulting product is filtered with suction, washed with cold water, and air-dried to afford 594 gm (96%), m.p. 137-141°C.
NOTE: The product should not be oven-dried since it decomposes with the loss of formaldehyde. Recrystallization of the product from ethanol affords 94% recovery of the original material with the same melting point range.

Synthesis Reference(s)

Journal of the American Chemical Society, 77, p. 1913, 1955 DOI: 10.1021/ja01612a068

N-(Hydroxymethyl)phthalimide Preparation Products And Raw materials

Raw materials

Preparation Products

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N-(Hydroxymethyl)phthalimide Suppliers

Xi'an Veda Chemical Co.,Ltd
Tel
029-88665278- ;29-88665278-
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QQ: 3080115965
Email
sales@vedachem.com;msales@vedachem.com
Country
China
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Dongyang Baihang Chemical Co., Ltd.
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0579-86886233-
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QQ:355093164
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355093164@qq.com
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China
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Jiangsu lianrun chemical co. LTD
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0517-85322222-
Email
sales@lianrunchem.com
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China
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Nanjing Taihehua Electronics Co., Ltd
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Email
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China
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J & K SCIENTIFIC LTD.
Tel
010-82848833- ;010-82848833-
Fax
86-10-82849933
Email
jkinfo@jkchemical.com;market6@jkchemical.com
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China
ProdList
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Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
21-61259100-
Fax
86-21-61259102
Email
sh@meryer.com
Country
China
ProdList
40264
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62
Alfa Aesar
Tel
400-610-6006; 021-67582000
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
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TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386 / 800-988-0390
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
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Beijing dtftchem Technology Co., Ltd.
Tel
010-60275820-
Fax
010-60270825
Email
elainezt@sina.com
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China
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Energy Chemical
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021-58432009-
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
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View Lastest Price from N-(Hydroxymethyl)phthalimide manufacturers

Hebei Crovell Biotech Co Ltd
Product
N-(Hydroxymethyl)phthalimide 118-29-6
Price
US $5.60/KG
Min. Order
1KG
Purity
99%
Supply Ability
5000kg
Release date
2021-07-05
Zhuozhou Wenxi import and Export Co., Ltd
Product
N-(Hydroxymethyl)phthalimide 118-29-6
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-26
Hebei Miaobian Biotechnology Co., Ltd
Product
N-(Hydroxymethyl)phthalimide 118-29-6
Price
US $10.00/KG
Min. Order
1KG
Purity
99.99
Supply Ability
10Ton
Release date
2021-02-18

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