(-)-Taddol

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Product Name: (-)-Taddol
CAS No.: 93379-48-7
Chemical Name: (-)-Taddol
Synonyms: 5R)-2;TADDOL;(-)-TADDOL;(R,R)-TADDOL;SEEBACH REAGENT;(-)-TADDOL 98%, (99% E.E.);(R,R)-(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-;(2R,3R)-(-)-4,5-BIS(DIPHENYLHYDROXYMETHY;(4R,5R)-4,5-BIS(DIPHENYLHYDROXYMETHYL)2, 2-DIMETHYL;(-)-2,3-O-Isopropylidene-1,1,4,4-tetrphenyl-L-threitol
CBNumber: CB1399332
Molecular Formula: C31H30O4
Formula Weight: 466.58
MOL File: 93379-48-7.mol

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(-)-Taddol Property

Melting point:: 193-195 °C(lit.)
alpha: -65.5 º (c=1, CHCl3)
Boiling point:: 489.39°C (rough estimate)
Density: 1.0864 (rough estimate)
refractive index: -69 ° (C=1, CHCl3)
storage temp.: Inert atmosphere,Room Temperature
pka: 12.28±0.29(Predicted)
form: Powder
color: white
optical activity: [α]19/D 62.6°, c = 1 in chloroform
BRN: 3657855
InChIKey: RNSJHECWLNVNFE-KYJUHHDHSA-N
CAS DataBase Reference: 93379-48-7(CAS DataBase Reference)

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Safety

Hazard Codes: Xi,Xn
Risk Statements: 36/38-36/37/38-20/21/22
Safety Statements: 24/25-36-26
WGK Germany: 3
HS Code: 29329970

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 265004
Product name: (4R,5R)-2,2-Dimethyl-α,α,α′,α′-tetraphenyldioxolane-4,5-dimethanol
Purity: 97%
Packaging: 1g
Price: $64.2
Updated: 2024/03/01

TCI Chemical

Product number: B1614
Product name: (-)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane
Purity: >97.0%(HPLC)
Packaging: 1g
Price: $49
Updated: 2024/03/01

TCI Chemical

Product number: B1614
Product name: (-)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane
Purity: >97.0%(HPLC)
Packaging: 5g
Price: $146
Updated: 2024/03/01

Strem Chemicals

Product number: 08-2008
Product name: (4R,5R)-(-)-2,2-Dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanol (R,R)-TADDOL
Packaging: 500mg
Price: $88
Updated: 2024/03/01

Strem Chemicals

Product number: 08-2008
Product name: (4R,5R)-(-)-2,2-Dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanol (R,R)-TADDOL
Packaging: 2g
Price: $262
Updated: 2024/03/01

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(-)-Taddol Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powde

Uses

Hydrogen-bonding organocatalyst examined in terms of acidity, deprotonation enthalpies and hydrogen bonding

Catalyst involved in synthesis of cyclopropylamines via addition reactions of Grignard reagents to amides

Reactant or reagent involved in:

Enantioswitching of catalytic asymmetric hydroboration
Synthesis of derivative ligands for asymmetric hydroformylation of alkenes
Amide-directed catalytic asymmetric hydroboration of trisubstituted alkenes
Addition of deactivated alkyl Grignard reagents to aldehydes

(-)-Taddol Preparation Products And Raw materials

Raw materials

p-Toluenesulfonic acid D-(-)-Tartaric Acid Bromobenzene Tetrahydrofuran Ethyl acetate Dichloromethane Methanol

Preparation Products

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View Lastest Price from (-)-Taddol manufacturers

Career Henan Chemical Co

Product: (-)-Taddol 93379-48-7
Price: US $2.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2018-12-23

93379-48-7, (-)-TaddolRelated Search:

1,4-Dioxane N,N-Dimethylformamide Dimethyl sulfide Dimethyl fumarate Chlorodimethylphenylsilane Selenium dioxide Dimethyl sulfoxide ETHANE Dimethyl phthalate Dimethyl ether DIOXOPROMETHAZINE HCL DIOXOPROMETHAZINE (4R,5R)-(-)-2,2-DIMETHYL-ALPHA,ALPHA,ALPHA',ALPHA'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOL (3AR,8AR)-(-)-(2,2-DIMETHYL-4,4,8,8-TETRAPHENYL-TETRAHYDRO-[1,3]DIOXOLO[4,5-E][1,3,2]DIOXAPHOSPHEPIN-6-YL)DIMETHYLAMINE (+)-Taddol,(+)-TADDOL,(+)-Taddol,(+)-TADDOL 1,3-Dioxolane 2,2-DIMETHYL-1,3-DIOXOLANE (+)-4,5-BIS[HYDROXY(DIPHENYL)METHYL]-2-METHYL-2-PHENYL-1,3-DIOXOLANE

(4R,5R)-4,5-BIS(DIPHENYLHYDROXYMETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE

(4R,5R)-4,5-BIS(DIPHENYLHYDROXYMETHYL)-2,2-DIMETHYL-DIOXOLANE

(-)-4,5-BIS[HYDROXY(DIPHENYL)METHYL]-2,2-DIMETHYL-1,3-DIOXOLANE

(R,R)-TADDOL

(R,R)-(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRAPHENYL-L-THREITOL

(-)-TADDOL

TADDOL

SEEBACH REAGENT

(4R,5R)-2,2-DIMETHYL-ALPHA, ALPHA, ALPHA', ALPHA'-TETRAPHENYLDIOXOLANE-4,5-DIMETHANOL

(4R,5R)-(-)-2,2-DIMETHYL-TETRAPHENYL-1,3-DIOXOLANE-4,5-DIMETHANOL

TADDOL, (4R,5R)-4,5-Bis(diphenylhydroxymethyl)-2,2-dimethyldioxolane, 1,1,4,4-Tetraphenyl-2,3-O-isopropylidene-L-threitol, (-)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-L-threitol

TADDOL, (4R,5R)-4,5-Bis(diphenylhydroxymethyl)-2,2-dimethyldioxolane, 1,1,4,4-Tetraphenyl-2,3-O-isopropylidene-L-threitol, (-)-trans-α,αμ-(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol), (-)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-L-threitol

(-)-trans-a,a'-(Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol)

[(4R,5R)-5-(hydroxy-diphenyl-methyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-diphenyl-methanol

1,3-Dioxolane-4,5-dimethanol, 2,2-dimethyl-a,a,a',a'-tetraphenyl-, (4R,5R)-

(4R)-α,α,α',α'-Tetraphenyl-2,2-dimethyl-1,3-dioxolane-4β,5α-bismethanol

(4R,5R)-2,2-Dimethyl-4,5-bis(hydroxydiphenylmethyl)-1,3-dioxolane

(4R,5R)-4,5-Bis(hydroxydiphenylmethyl)-2,2-dimethyl-1,3-dioxolane

(4R,5R)-α,α,α',α'-Tetraphenyl-2,2-dimethyl-1,3-dioxolane-4,5-bismethanol

α,α'-[(4R,5R)-2,2-Dimethyl-1,3-dioxolane-4β,5α-diyl]bis(diphenylmethanol)

(4R,5R)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetraphenyldioxolane-4,5-dimethanol(-TADDOL)

(-)-2,3-O-Isopropylidene-1,1,4,4-tetrphenyl-L-threitol, TADDOL

(4R,5R)-2,2-Dimethyl-α,α,α′,α′-tetraphenyldioxolane-4,5-dimethanol ,97%

(4R,5R)-(-)-2,2-Dimethyl-a,a,a',a'-tetraphenyl-1,3-dioxolane-4,5-dimethanol (R,R)-TADDOL

(4R,5R)-2,2-Dimethyl-α,α,α',α'-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanol

(-)-TRANS-4,5-BIS-(DIPHENYL-HYDROXYMETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE

(-)-TRANS-ALPHA,ALPHA'-(2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DIYL)BIS(DIPHENYLMETHANOL)

(-)-TRANS-ALPHA,ALPHA'-(DIMETHYL-1,3-DIOXOLANE-4,5-DIYL)BIS(DIPHENYLMETHANOL)

(-)-2,3-O-Isopropylidene-1,1,4,4-Tetraphenyl-L-Threitol(4R,5R)-2,2-Dimethyl-Alpha,Alpha,Alpha',Alpha'-Tetraphenyldioxolane-4,5-Dimethanol

(4R,5R)-2,2-Dimethyl-a,a,a',a'-tetraphenyldioxolane-4,5-dimethanol

( - )-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl- L-threitol [(4R,5R)-2,2-Dimethyl-a,a,a’, a’-tetraphenyldioxolane-4,5-dimethanol

(-)-2,3-O-Isopropylidene-1,1,4,4-tetrphenyl-L-threitol

(-)-TRANS-A,A'-(2,2-DIMETHYL-1,3-DIOXOLA NE -4,5-DIYL)BIS(DIPHENYLMETHANOL)

(4R,5R)-4,5-BIS(DIPHENYLHYDROXYMETHYL)2, 2-DIMETHYL

(4R,5R)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetraphenyldioxolane-4,5-dimethan

(-)-Trans-A,A'-(2,2-Dimethyl-1,3-Dioxolane-4,5-Diyl)Bis(Diphenylmethanol),ChemAbs

(-)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-L-threitol[(4R,5R)-2,2-<br>Dimethyl-a,a,aatetraphenyldioxolane-4,5-dimethanol

(4R,5R)-(-)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetraphenyl-1,3-dioxolane-4,5-dimethanol(R,R)-TADDOL

(4r,5r)-2,2-dimethyl-α,α,α',α'-tetraphenyldioxolane-4,5-dimethanol

(-)-TADDOL 98%, (99% E.E.)

(2R,3R)-(-)-1,1,4,4-TETRAPHENYL-2,3-(2-PROPYLIDENEDIOXY)-BUTANE-1,4-DIOL

(2R,3R)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRAPHENYL-1,2,3,4-BUTANETETROL

(2R,3R)-(-)-4,5-BIS(DIPHENYLHYDROXYMETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE

(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRAPHENYL-L-THREITOL

(-)-(4R,5R)-2,2-DIMETHYL-ALPHA,ALPHA,ALPHA',ALPHA'-TETRAPHENYL-1,3-DIOXOLANE-4,5-DIMETHANOL

(-)-trans-alpha,alpha'-(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol) (2R,3R)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-1,2,3,4-butanetetrol (-)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-L-threitol

(2R,3R)-(-)-4,5-BIS(DIPHENYLHYDROXYMETHY

(-)-Taddol (-)-trans-alpha,alpha'-(Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol)

(4R,5R)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetraphenyldioxolane-4,5-dimethanol 97%

5R)-2

(R,R)-(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-

(4R,5R)-(-)-2,2-Dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanol (R,R)-TADDOL

'-tetraphenyl-1,3-dioxolane-4,5-dimethanol (R,R)-TADDOL

(-)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane &gt

(-)-trans-α,α'-(2,2-Dimethyl-1,3-dioxane-4,5-diyl)bis(diphenylmethanol)

1,3-Dioxolane-4,5-dimethanol, 2,2-dimethyl-α4,α4,α5,α5-tetraphenyl-, (4R,5R)-

(4R,5R)-(-)-2,2-Dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanol

(-)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxol...