1,1'-FERROCENEDICARBOXALDEHYDE
- Product Name
- 1,1'-FERROCENEDICARBOXALDEHYDE
- CAS No.
- 1271-48-3
- Chemical Name
- 1,1'-FERROCENEDICARBOXALDEHYDE
- Synonyms
- 1,1μ-Diformylferrocene;1,1μ-Bisformylferrocene;1,1'-FerrocenedicarboxaL;Ferrocene, 1,1'-diformyl-;-FERROCENEDICARBOXALDEHYDE;Ferrocene-1,1'-dicarbaldehyde;Cyclopentadienecarboxaldehyde;1,1 '- ferrocene formaldehyde;1,1-Ferrocenedicarboxyaldehyde;1,1'-Ferrocene dicarboxaldhyde
- CBNumber
- CB1417090
- Molecular Formula
- C12H10FeO210*
- Formula Weight
- 242.05
- MOL File
- 1271-48-3.mol
1,1'-FERROCENEDICARBOXALDEHYDE Property
- Melting point:
- 151-156 °C(lit.)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- Powder
- Appearance
- Brown to reddish brown Solid
- Water Solubility
- Insoluble in water.
- Sensitive
- Air Sensitive
- InChI
- InChI=1S/2C6H5O.Fe/c2*7-5-6-3-1-2-4-6;/h2*1-5H;
- InChIKey
- SRAPEJKOIJWBFN-UHFFFAOYSA-N
- SMILES
- [C]1(C=O)[CH][CH][CH][CH]1.[C]1(C=O)[CH][CH][CH][CH]1.[Fe] |^1:0,3,4,5,6,7,10,11,12,13|
- CAS DataBase Reference
- 1271-48-3
Safety
- Safety Statements
- 24/25
- WGK Germany
- 3
- HS Code
- 29319090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H317May cause an allergic skin reaction
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 496391
- Product name
- 1,1′-Ferrocenedicarboxaldehyde
- Purity
- 96%
- Packaging
- 500mg
- Price
- $155
- Updated
- 2025/07/31
- Product number
- F1343
- Product name
- 1,1'-Ferrocenedicarboxaldehyde
- Packaging
- 100MG
- Price
- $126
- Updated
- 2025/07/31
- Product number
- CS-W014142
- Product name
- 1,1'-Ferrocenedicarboxaldehyde
- Packaging
- 100mg
- Price
- $63
- Updated
- 2021/12/16
- Product number
- CS-W014142
- Product name
- 1,1'-Ferrocenedicarboxaldehyde
- Packaging
- 250mg
- Price
- $105
- Updated
- 2021/12/16
- Product number
- 090556
- Product name
- 1,1'-Ferrocenedicarboxaldehyde
- Purity
- 97%
- Packaging
- 250mg
- Price
- $265
- Updated
- 2021/12/16
1,1'-FERROCENEDICARBOXALDEHYDE Chemical Properties,Usage,Production
Chemical Properties
Dark red solid
Uses
1,1'-Ferrocenedicarboxaldehyde is used as a starting material to prepare 1'-formyl-ferrocenecarboxylic acid and 1'-[(E)-3-oxo-but-1-enyl]-ferrocenecarboxylic acid by oxidation with potassium permanganate using water/acetonitrile mixture and water/acetone mixture respectively.
reaction suitability
core: iron
reagent type: catalyst
Synthesis
102-54-5
68-12-2
1271-48-3
The general procedure for the synthesis of 1,1'-ferrocenedicarboxaldehyde from ferrocene and N,N-dimethylformamide, based on a modification of the literature procedure [26b], was as follows: ferrocene (10 g, 0.054 mol) was dissolved in anhydrous hexanes (200 mL) at room temperature, n-butyllithium solution (67 mL, 1.6 M, 0.10 mol) was added slowly and dropwise, followed by the addition of tetramethylene methyl ethylenediamine (TMEDA) (14.7 g, 0.25 mol). It was shown that the addition of the reactants at -50 °C had no significant effect on the yield. After stirring the reaction mixture for 18 h at room temperature, the dilithiated ferrocene precipitated as an orange solid. The suspension was cooled to 0 °C, N,N-dimethylformamide (DMF) (7.85 g, 0.11 mol, 8.3 mL) was added and stirring was continued for 2 h at room temperature.
References
[1] Journal of Organometallic Chemistry, 1993, vol. 463, # 1-2, p. 163 - 168
[2] Journal of Organometallic Chemistry, 2013, vol. 740, p. 61 - 69
[3] Journal of Organometallic Chemistry, 2009, vol. 694, # 13, p. 2020 - 2028
[4] Journal of the Chemical Society, Perkin Transactions 1, 2000, # 10, p. 1551 - 1557
[5] European Journal of Inorganic Chemistry, 2014, vol. 2014, # 36, p. 6212 - 6219
1,1'-FERROCENEDICARBOXALDEHYDE Preparation Products And Raw materials
Raw materials
Preparation Products
1,1'-FERROCENEDICARBOXALDEHYDE Suppliers
- Tel
- 025-85760892 13376080562
- Fax
- 025-85766769
- sales@habotech.com
- Country
- China
- ProdList
- 884
- Advantage
- 60
- Tel
- 18210857532; 18210857532
- Fax
- 86-10-82849933
- jkinfo@jkchemical.com
- Country
- China
- ProdList
- 96815
- Advantage
- 76
- Tel
- 4006356688 18621169109
- Fax
- 86-21-61259102
- market03@meryer.com
- Country
- China
- ProdList
- 40228
- Advantage
- 62
- Tel
- 400-6106006
- Fax
- 021-67582001/03/05
- saleschina@alfa-asia.com
- Country
- China
- ProdList
- 30123
- Advantage
- 84
- Tel
- 18515581800 18501085097
- Fax
- 010-89508210
- sales.bj@hwrkchemical.com
- Country
- China
- ProdList
- 9400
- Advantage
- 55
- Tel
- 021-021-58432009 400-005-6266
- Fax
- 021-58436166
- sales8178@energy-chemical.com
- Country
- China
- ProdList
- 44801
- Advantage
- 61
- Tel
- 13817811078
- Fax
- 86-021-50426522,50426273
- sales@jingyan-chemical.com
- Country
- China
- ProdList
- 9976
- Advantage
- 60
- Tel
- 021-58099652-8005 13585536065
- Fax
- 021-58099609
- bin.wu@shlschem.com
- Country
- China
- ProdList
- 9883
- Advantage
- 59
- Tel
- 021-54306202 13764082696
- info@hanhongsci.com
- Country
- China
- ProdList
- 42934
- Advantage
- 64
- Tel
- 4009903999 13355009207
- Fax
- 0539-6365991
- 3007715519@qq.com
- Country
- China
- ProdList
- 18729
- Advantage
- 57
View Lastest Price from 1,1'-FERROCENEDICARBOXALDEHYDE manufacturers
- Product
- 1,1'-FERROCENEDICARBOXALDEHYDE 1271-48-3
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 mt
- Release date
- 2024-12-04
- Product
- 1,1'-Ferrocenedicarboxaldehyde 1271-48-3
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99.0%
- Supply Ability
- 10000KG
- Release date
- 2024-09-04
- Product
- 1,1'-FERROCENEDICARBOXALDEHYDE 1271-48-3
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 95%-99%
- Supply Ability
- 1000kg
- Release date
- 2019-08-26