1,1'-FERROCENEDICARBOXYLIC ACID

Product Name: 1,1'-FERROCENEDICARBOXYLIC ACID
CAS No.: 1293-87-4
Chemical Name: 1,1'-FERROCENEDICARBOXYLIC ACID
Synonyms: DK7513;1,1'-Dicarboxyferrocene;1,1'-FerrocenedicarboxyL;1,1′-Biscarboxylferrocene;Ferrocene, 1,1'-dicarboxy-;Ferrocene dicarboxylic acid;1,1'-FERROCENDICARBONSAEURE;1,1-Ferrpemedocarboxylic Acid;1,1-Ferrocnedocarboxylic Acid;1,1'- twocarboxyltwoferrocene
CBNumber: CB1411720
Molecular Formula: C12H10FeO410*
Formula Weight: 274.05
MOL File: 1293-87-4.mol

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1,1'-FERROCENEDICARBOXYLIC ACID Property

Melting point:: ≥300 °C(lit.)
storage temp.: Inert atmosphere,Room Temperature
solubility: DMSO, Ethyl Acetate (Very Slightly, Heated, Sonicated)
form: crystal
color: orange
Water Solubility: Insoluble
Exposure limits: ACGIH: TWA 1 mg/m3
NIOSH: TWA 1 mg/m3
Stability:: Stable. Incompatible with strong oxidizing agents.
InChI: InChI=1S/2C6H5O2.Fe/c2*7-6(8)5-3-1-2-4-5;/h2*1-4H,(H,7,8);
InChIKey: ISVVAJYTLASNEJ-UHFFFAOYSA-N
SMILES: [C]1([CH][CH][CH][CH]1)C(=O)O.[C]1([CH][CH][CH][CH]1)C(=O)O.[Fe] |^1:0,1,2,3,4,8,9,10,11,12|
CAS DataBase Reference: 1293-87-4
NIST Chemistry Reference: 1,1'-Ferrocenedicarboxylic acid(1293-87-4)

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Safety

Hazard Codes: Xi,Xn
Risk Statements: 36/37/38-22
Safety Statements: 26-36-37/39
WGK Germany: 3
HS Code: 29319090
Storage Class: 13 - Non Combustible Solids
Hazard Classifications: Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 106895
Product name: 1,1′-Ferrocenedicarboxylic acid
Purity: 96%
Packaging: 5g
Price: $246
Updated: 2023/06/20

Strem Chemicals

Product number: 26-1800
Product name: 1,1'-Ferrocene dicarboxylic acid, min. 96%
Packaging: 1g
Price: $68
Updated: 2024/03/01

Strem Chemicals

Product number: 26-1800
Product name: 1,1'-Ferrocene dicarboxylic acid, min. 96%
Packaging: 5g
Price: $249
Updated: 2024/03/01

AK Scientific

Product number: 4598AH
Product name: 1,1′-Ferrocenedicarboxylic acid
Packaging: 5g
Price: $87
Updated: 2021/12/16

Ark Pharm

Product number: AK163314
Product name: 1,1'-Dicarboxyferrocene
Purity: 95%
Packaging: 25g
Price: $116
Updated: 2021/12/16

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1,1'-FERROCENEDICARBOXYLIC ACID Chemical Properties,Usage,Production

Chemical Properties

dark brown powder

Uses

Reactant for preparation of:

Planar chiral ferrocene-based amido-phosphine ligands as catalysts for asymmetric allylic alkylation reactions
Potential antitumor agents
Isostructural ferrocenyl coordination polymer hollow microspheres with H2 storage properties
Prganometallic aromatic polyesters
Manganese-lanthanide-ferrocene clusters

reaction suitability

core: iron
reagent type: catalyst

Synthesis

1,1'-Ferrocenecarboxylic acid can be prepared by hydrolyzing its diester Fe(C5H4CO2R)2 (R = Me, Et), which in turn can be prepared by reacting the sodium salt of a cyclopentadienyl carboxylate with ferrous chloride.

Purification Methods

It crystallises in orange-yellow crystals from AcOH and sublimes above 230o. The monomethyl ester has m 147-149o [Nesmeyanov & Reutov Dokl Acad Nauk USSS 115 518 1957]. The dimethyl ester has m 114-115o [Woodward et al. J Am Chem Soc 74, 3458 1953]. The diacid chloride has m 92-93o when recrystallised from pet ether. [Nesmeyanov & Reutov Dokl Acad Nauk SSSR 120 1267 1958, Kazitsyna et al. Dokl Acad Nauk SSSR 127 333 1959, Beilstein 16 IV 1811.]

1,1'-FERROCENEDICARBOXYLIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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1,1'-FERROCENEDICARBOXYLIC ACID Suppliers

Belgium 1 China 148 Europe 2 France 1 Germany 3 India 2 Japan 3 Russia 1 South Korea 1 Switzerland 1 The Netherlands 1 Ukraine 1 United Kingdom 6 United States 16 Global 187

Qingzhou dafeng import and export Co. LTD

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View Lastest Price from 1,1'-FERROCENEDICARBOXYLIC ACID manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: 1,1'-FERROCENEDICARBOXYLIC ACID 1293-87-4
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 10000KGS
Release date: 2025-03-01

Shaanxi Dideu Medichem Co. Ltd

Product: 1,1'-Ferrocenedicarboxylic Acid 1293-87-4
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 10000KG
Release date: 2024-09-02

Career Henan Chemical Co

Product: 1,1'-FERROCENEDICARBOXYLIC ACID 1293-87-4
Price: US $8.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 10TON
Release date: 2018-12-18

1293-87-4, 1,1'-FERROCENEDICARBOXYLIC ACIDRelated Search:

1-Hexanol Cyclopentanecarbaldehyde Cyclopentanemethanol Ferrocenecarboxylic acid 2-Methyl butyric acid 2-METHYLVALERIC ACID 1,1'-FERROCENEDIMETHANOL 1,1'-FERROCENEDICARBOXALDEHYDE Cyclopentanecarboxylic acid Ferrocene Ferrocenecarboxaldehyde 2-Ethylbutyric acid Hexanoic acid 2-ETHYL-1-BUTANOL 1,1'-FERROCENEDICARBOXYLIC ACID 2-ETHYLBUTYRALDEHYDE 1,1'-DIMETHYLFERROCENE Valeric acid

1,1-Ferrocnedocarboxylic Acid

1,1-Ferrpemedocarboxylic Acid

FERROCENE-1,1'-DICARBOXYLIC ACID

BIS(CARBOXYCYCLOPENTADIENYL)IRON

Ferrocene dicarboxylic acid

Ferrocene, 1,1'-dicarboxy-

1,1'-FERROCENDICARBONSAEURE

1,1'-Ferrocenedicarboxylicacid,min.96%

1,1''-FERROCENE DICARBOXYLIC ACID, MIN. 96%

1,1'-Ferrocenedicarboxylic acid, 96+%

Bis(carboxycyclopentadienyl) Iron 1,1'-Dicarboxyferrocene

1,1'- twocarboxyltwoferrocene

1,1′-Biscarboxylferrocene

1,1′-Ferrocenedicarboxylic acid, >=98%

1,1'-FerrocenediCarbocylic acid

1,1'-Ferrocenedicarboxylic acid ,97%

1,1′-Ferrocenedicarboxylic acid 96%

1,1'-FerrocenedicarboxyL

1,1'-FerrocenedicarboxylicAcid&gt

DK7513

1,1'-Ferrocenedicarboxylic Acid

1,1'-Dicarboxyferrocene

1,1''-Ferrocenedicarboxylic Acid

Bis(5-carboxy-1,3-cyclopentadien-1-yl)iron

1,1'-FERROCENEDICARBOXYLIC ACID

1293-87-4

1293-48-1

HOOCC5H42Fe

C12H10FeO4

2C6H5O2Fe

Catalysis and Inorganic Chemistry

Ferrocenes

Fe (Iron) Compounds

Transition Metal Compounds

Metallocenes

Classes of Metal Compounds

Fe (Iron) Compounds

Ferrocenes

Metallocenes

Transition Metal Compounds

Miscellaneous

Catalysis and Inorganic Chemistry

Chemical Synthesis

Industrial/Fine Chemicals