ChemicalBook > CAS DataBase List > 1,1'-FERROCENEDICARBOXYLIC ACID

1,1'-FERROCENEDICARBOXYLIC ACID

Product Name
1,1'-FERROCENEDICARBOXYLIC ACID
CAS No.
1293-87-4
Chemical Name
1,1'-FERROCENEDICARBOXYLIC ACID
Synonyms
DK7513;1,1'-DICARBOXYFERROCENE;1,1'-Dicarboxyferrocene;1,1'-FerrocenedicarboxyL;1,1′-Biscarboxylferrocene;Ferrocene, 1,1'-dicarboxy-;1,1'-FERROCENDICARBONSAEURE;Ferrocene dicarboxylic acid;1,1-Ferrpemedocarboxylic Acid;1,1-Ferrocnedocarboxylic Acid
CBNumber
CB1411720
Molecular Formula
C12H10FeO410*
Formula Weight
274.05
MOL File
1293-87-4.mol
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1,1'-FERROCENEDICARBOXYLIC ACID Property

Melting point:
≥300 °C(lit.)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
DMSO, Ethyl Acetate (Very Slightly, Heated, Sonicated)
form 
crystal
color 
orange
Water Solubility 
Insoluble
Exposure limits
ACGIH: TWA 1 mg/m3
NIOSH: TWA 1 mg/m3
Stability:
Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference
1293-87-4
NIST Chemistry Reference
1,1'-Ferrocenedicarboxylic acid(1293-87-4)
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-22
Safety Statements 
26-36-37/39
WGK Germany 
3
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
106895
Product name
1,1′-Ferrocenedicarboxylic acid
Purity
96%
Packaging
5g
Price
$246
Updated
2023/06/20
Alfa Aesar
Product number
A16691
Product name
1,1'-Ferrocenedicarboxylic acid, 98%
Packaging
1g
Price
$63.8
Updated
2023/06/20
Alfa Aesar
Product number
A16691
Product name
1,1'-Ferrocenedicarboxylic acid, 98%
Packaging
5g
Price
$215
Updated
2023/06/20
Strem Chemicals
Product number
26-1800
Product name
1,1'-Ferrocene dicarboxylic acid, min. 96%
Packaging
1g
Price
$68
Updated
2024/03/01
Strem Chemicals
Product number
26-1800
Product name
1,1'-Ferrocene dicarboxylic acid, min. 96%
Packaging
5g
Price
$249
Updated
2024/03/01
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1,1'-FERROCENEDICARBOXYLIC ACID Chemical Properties,Usage,Production

Chemical Properties

dark brown powder

Uses

Reactant for preparation of:

  • Planar chiral ferrocene-based amido-phosphine ligands as catalysts for asymmetric allylic alkylation reactions
  • Potential antitumor agents
  • Isostructural ferrocenyl coordination polymer hollow microspheres with H2 storage properties
  • Prganometallic aromatic polyesters
  • Manganese-lanthanide-ferrocene clusters

Purification Methods

It crystallises in orange-yellow crystals from AcOH and sublimes above 230o. The monomethyl ester has m 147-149o [Nesmeyanov & Reutov Dokl Acad Nauk USSS 115 518 1957]. The dimethyl ester has m 114-115o [Woodward et al. J Am Chem Soc 74, 3458 1953]. The diacid chloride has m 92-93o when recrystallised from pet ether. [Nesmeyanov & Reutov Dokl Acad Nauk SSSR 120 1267 1958, Kazitsyna et al. Dokl Acad Nauk SSSR 127 333 1959, Beilstein 16 IV 1811.]

1,1'-FERROCENEDICARBOXYLIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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1,1'-FERROCENEDICARBOXYLIC ACID Suppliers

Belgium 1 China 125 Europe 2 France 1 Germany 3 India 2 Japan 3 Russia 1 South Korea 1 Switzerland 1 The Netherlands 1 Ukraine 1 United Kingdom 6 United States 16 Global 164
TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28398
Advantage
80
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View Lastest Price from 1,1'-FERROCENEDICARBOXYLIC ACID manufacturers

Career Henan Chemical Co
Product
1,1'-FERROCENEDICARBOXYLIC ACID 1293-87-4
Price
US $8.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10TON
Release date
2018-12-18

1293-87-4, 1,1'-FERROCENEDICARBOXYLIC ACIDRelated Search:

1-Hexanol Cyclopentanecarbaldehyde Cyclopentanemethanol Ferrocenecarboxylic acid 2-Methyl butyric acid 2-METHYLVALERIC ACID 1,1'-FERROCENEDIMETHANOL 1,1'-FERROCENEDICARBOXALDEHYDE Cyclopentanecarboxylic acid Ferrocene Ferrocenecarboxaldehyde 2-Ethylbutyric acid Hexanoic acid 2-ETHYL-1-BUTANOL 1,1'-FERROCENEDICARBOXYLIC ACID 2-ETHYLBUTYRALDEHYDE 1,1'-DIMETHYLFERROCENE Valeric acid

  • 1,1'-FERROCENEDICARBOXYLIC ACID
  • 1,1'-DICARBOXYFERROCENE
  • 1,1-Ferrocnedocarboxylic Acid
  • 1,1-Ferrpemedocarboxylic Acid
  • FERROCENE-1,1'-DICARBOXYLIC ACID
  • BIS(CARBOXYCYCLOPENTADIENYL)IRON
  • Ferrocene dicarboxylic acid
  • Ferrocene, 1,1'-dicarboxy-
  • 1,1'-FERROCENDICARBONSAEURE
  • 1,1'-Ferrocenedicarboxylicacid,min.96%
  • 1,1''-FERROCENE DICARBOXYLIC ACID, MIN. 96%
  • 1,1'-Ferrocenedicarboxylic acid, 96+%
  • Bis(carboxycyclopentadienyl) Iron 1,1'-Dicarboxyferrocene
  • 1,1'- twocarboxyltwoferrocene
  • 1,1′-Biscarboxylferrocene
  • 1,1′-Ferrocenedicarboxylic acid, >=98%
  • 1,1'-FerrocenediCarbocylic acid
  • 1,1'-Ferrocenedicarboxylic acid ,97%
  • 1,1′-Ferrocenedicarboxylic acid 96%
  • 1,1'-FerrocenedicarboxyL
  • 1,1'-FerrocenedicarboxylicAcid&gt
  • DK7513
  • 1,1'-Ferrocenedicarboxylic Acid
  • 1,1'-Dicarboxyferrocene
  • 1293-87-4
  • 1293-48-1
  • HOOCC5H42Fe
  • C12H10FeO4
  • 2C6H5O2Fe
  • Catalysis and Inorganic Chemistry
  • Ferrocenes
  • Fe (Iron) Compounds
  • Transition Metal Compounds
  • Metallocenes
  • Classes of Metal Compounds
  • Classes of Metal Compounds
  • Fe (Iron) Compounds
  • Ferrocenes
  • Metallocenes
  • Transition Metal Compounds
  • Miscellaneous
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • Industrial/Fine Chemicals