ChemicalBook > CAS DataBase List > Fructone

Fructone

Product Name
Fructone
CAS No.
6413-10-1
Chemical Name
Fructone
Synonyms
APPLINAL;Ethylfruitat;ETHYL-2-METHYL-1,3-DIOXOLANE-2-ACETATE;ETHYL 2-(2-METHYL-1,3-DIOXOLAN-2-YL)ACETATE;fructone,Ethyl acetoacetate ethylene glycol ketal;1,3-Dioxolane-2-acetic acid, 2-methyl-, ethyl ester;2-(2-methyl-1,3-dioxolan-2-yl)acetic acid ethyl ester;FRUCTONE;Fragolan;Frutinal
CBNumber
CB1733752
Molecular Formula
C8H14O4
Formula Weight
174.19
MOL File
6413-10-1.mol
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Fructone Property

Boiling point:
90 °C
Density 
1.0817 (rough estimate)
vapor pressure 
1.08hPa at 20℃
FEMA 
4477 | ETHYL ACETOACETATE ETHYLENEGLYCOL KETAL
refractive index 
1.4310-1.4350
Flash point:
93.00°C
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
form 
clear liquid
color 
Colorless to Almost colorless
Odor
at 100.00 %. sweet fruity apple green tropical plum woody
Odor Type
fruity
biological source
synthetic
Water Solubility 
124.8g/L at 20℃
JECFA Number
1969
InChIKey
XWEOGMYZFCHQNT-UHFFFAOYSA-N
LogP
0.8 at 35℃
CAS DataBase Reference
6413-10-1(CAS DataBase Reference)
NIST Chemistry Reference
Ethyl acetoacetate ethylene acetal(6413-10-1)
EPA Substance Registry System
1,3-Dioxolane-2-acetic acid, 2-methyl-, ethyl ester (6413-10-1)
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Safety

Hazard Codes 
Xi
RTECS 
JH6762500
HS Code 
2932.99.9090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W447704
Product name
Ethyl 2-methyl-1,3-dioxolane-2-acetate
Purity
≥99%
Packaging
1 unit
Price
$61.7
Updated
2025/07/31
Sigma-Aldrich
Product number
W447704
Product name
Ethyl 2-methyl-1,3-dioxolane-2-acetate
Purity
≥99%
Packaging
1 unit
Price
$61.7
Updated
2025/07/31
Sigma-Aldrich
Product number
W447704
Product name
Ethyl 2-methyl-1,3-dioxolane-2-acetate
Purity
≥99%
Packaging
1KG
Price
$95
Updated
2025/07/31
Sigma-Aldrich
Product number
W447704
Product name
Ethyl 2-methyl-1,3-dioxolane-2-acetate
Purity
≥99%
Packaging
5KG
Price
$229
Updated
2025/07/31
Sigma-Aldrich
Product number
W447704
Product name
Ethyl 2-methyl-1,3-dioxolane-2-acetate
Purity
≥99%
Packaging
SAMPLE-K
Price
$59.8
Updated
2024/03/01
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Fructone Chemical Properties,Usage,Production

Chemical Properties

Ethyl (2-Methyl-[1,3]dioxolan-2-yl)-acetate is not found in nature. It is a colorless liquid, d2041.084–1.092, n20D 1.431–1.435, with a strong, fruity, apple-like, slightly green odor. It can be prepared by acetalization of ethyl acetoacetate with ethylene glycol.
Very slightly soluble in water, soluble in alcohol and Propylene glycol, miscible with most perfume oils.

Uses

flavors and fragrances

Trade name

Fructone (IFF), Jasmaprunat (Symrise)

Synthesis

141-97-9

107-21-1

6413-10-1

Ethyl acetoacetate (39.0 g, 0.3 mol), ethylene glycol (55.8 g, 0.9 mol), and toluene (200 mL) were added to a 250 mL three-necked, round-bottomed flask fitted with a mechanical stirrer, thermometer, Dean-Stark manifold, and reflux condenser tube. Subsequently, p-toluenesulfonic acid monohydrate (0.2 g, catalytic amount) was added as a catalyst. The reaction mixture was heated to reflux and the water generated during the reaction was removed via a Dean-Stark water separator. After completion of the reaction, the solvent was removed under reduced pressure by rotary evaporator. The residue was distilled under reduced pressure and the fractions with boiling points of 96-99 °C were collected to give 47.6 g of the colorless oily product malate in 91% yield. The infrared spectrum of the product (KBr pressed sheet, cm?1) showed characteristic absorption peaks: 2984, 2890, 1736, 1370, 1049.

References

[1] Journal of Chemical Research - Part S, 1997, # 1, p. 26 - 27
[2] Journal of Organic Chemistry, 1989, vol. 54, # 15, p. 3625 - 3634
[3] Journal of Catalysis, 2000, vol. 196, # 2, p. 345 - 351
[4] Tetrahedron Letters, 2011, vol. 52, # 51, p. 7004 - 7007
[5] RSC Advances, 2016, vol. 6, # 47, p. 41404 - 41409

Fructone Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Fructone manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Fructone 6413-10-1
Price
US $0.00/KG
Min. Order
25KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-01-14
Hebei Chuanghai Biotechnology Co., Ltd
Product
Fructone 6413-10-1
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100 mt
Release date
2024-11-13
Hebei Zhuanglai Chemical Trading Co Ltd
Product
Fructone 6413-10-1
Price
US $150.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
500kg
Release date
2024-11-20

6413-10-1, FructoneRelated Search:

Bromocyclopentane Ethyl 4-bromoacetoacetate 1,3-Dioxolane Ethyl 4-chloroacetoacetate Cyclopentane Ethyl 4,4,4-trifluoroacetoacetate Ethyl acetoacetate Ethyl 2-methylacetoacetate Ethyl acetate Methyl acetoacetate Ammonium acetate Ethyl 2-chloroacetoacetate Cyclopentyl chloride Tocopheryl acetate Methylcyclopentane Acetoxyacetic acid Glatiramer acetate Vinyl acetate

  • 2-(2-methyl-1,3-dioxolan-2-yl)acetic acid ethyl ester
  • fructone,Ethyl acetoacetate ethylene glycol ketal
  • Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)
  • ethyl 2-(2-methyl-1,3-dioxolan-2-yl)ethanoate
  • APPLINAL
  • ETHYLACETOACETATEETHYLENEGLYCOL-ACETAL
  • ETHYLACETOACETATE ETHYLENE GLYCOL KETAL
  • ETHYLACETOACETATE ETHYLENE KETAL
  • ETHYL METHYL DIOXOLANE ACETATE
  • ETHYL-2-METHYL-1,3-DIOXOLANE-2-ACETATE
  • ETHYL 2-(2-METHYL-1,3-DIOXOLAN-2-YL)ACETATE
  • KETOPOMMAL
  • FRUCTONE
  • 1,3-Dioxolane-2-acetic acid, 2-methyl-, ethyl ester
  • 1,3-Dioxolane-2-aceticacid,2-methyl-,ethylester
  • Ethyl acetoacetate ethyleneglycol ketal // fructone
  • Ethyl-2-Methyl-1
  • 2-methyl-1,3-dioxolane-2-aceticacidethylester
  • 3-dioxolane-2-aceticacid,2-methyl-ethylester
  • Ethyl (2-methyl-1,3-dioxolan-2-yl)acetate
  • Ethyl acetoacetate 3-ethylene acetal
  • Ethyl acetoacetate ethylene acetal
  • ethyl3-oxobutyrateethyleneketal
  • KETOPOMMAL (ETHYL METHYL DIOXALAN ACETATE)
  • METHYL DIOXALAN (FRUCTON)
  • FRUCTONE 95%
  • Ethyl-2-methyl-1,3-dioxolan-2-acetat
  • Ethylfruitat
  • Fragolan
  • Frutinal
  • Jasmaprunat
  • Methyldioxolan
  • (2-Methyl-1,3-dioxolane-2-yl)acetic acid ethyl ester
  • Apple ester
  • Ethyl2-(2-Methyl-1,3-dioxolan-2-yl)acetate&gt
  • 2-(2-MethyL
  • Fructone with hot sale
  • 6413-10-1
  • 6431-10-1
  • 6413-10-01
  • organic chemical
  • 6413-10-1