Fructone
- Product Name
- Fructone
- CAS No.
- 6413-10-1
- Chemical Name
- Fructone
- Synonyms
- APPLINAL;Ethylfruitat;ETHYL-2-METHYL-1,3-DIOXOLANE-2-ACETATE;ETHYL 2-(2-METHYL-1,3-DIOXOLAN-2-YL)ACETATE;fructone,Ethyl acetoacetate ethylene glycol ketal;1,3-Dioxolane-2-acetic acid, 2-methyl-, ethyl ester;2-(2-methyl-1,3-dioxolan-2-yl)acetic acid ethyl ester;FRUCTONE;Fragolan;Frutinal
- CBNumber
- CB1733752
- Molecular Formula
- C8H14O4
- Formula Weight
- 174.19
- MOL File
- 6413-10-1.mol
Fructone Property
- Boiling point:
- 90 °C
- Density
- 1.0817 (rough estimate)
- vapor pressure
- 1.08hPa at 20℃
- FEMA
- 4477 | ETHYL ACETOACETATE ETHYLENEGLYCOL KETAL
- refractive index
- 1.4310-1.4350
- Flash point:
- 93.00°C
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- form
- clear liquid
- color
- Colorless to Almost colorless
- Odor
- at 100.00 %. sweet fruity apple green tropical plum woody
- Odor Type
- fruity
- biological source
- synthetic
- Water Solubility
- 124.8g/L at 20℃
- JECFA Number
- 1969
- InChIKey
- XWEOGMYZFCHQNT-UHFFFAOYSA-N
- LogP
- 0.8 at 35℃
- CAS DataBase Reference
- 6413-10-1(CAS DataBase Reference)
- NIST Chemistry Reference
- Ethyl acetoacetate ethylene acetal(6413-10-1)
- EPA Substance Registry System
- 1,3-Dioxolane-2-acetic acid, 2-methyl-, ethyl ester (6413-10-1)
Safety
- Hazard Codes
- Xi
- RTECS
- JH6762500
- HS Code
- 2932.99.9090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H227Combustible liquid
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P370+P378In case of fire: Use … for extinction.
P403+P235Store in a well-ventilated place. Keep cool.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- W447704
- Product name
- Ethyl 2-methyl-1,3-dioxolane-2-acetate
- Purity
- ≥99%
- Packaging
- 1 unit
- Price
- $61.7
- Updated
- 2025/07/31
- Product number
- W447704
- Product name
- Ethyl 2-methyl-1,3-dioxolane-2-acetate
- Purity
- ≥99%
- Packaging
- 1 unit
- Price
- $61.7
- Updated
- 2025/07/31
- Product number
- W447704
- Product name
- Ethyl 2-methyl-1,3-dioxolane-2-acetate
- Purity
- ≥99%
- Packaging
- 1KG
- Price
- $95
- Updated
- 2025/07/31
- Product number
- W447704
- Product name
- Ethyl 2-methyl-1,3-dioxolane-2-acetate
- Purity
- ≥99%
- Packaging
- 5KG
- Price
- $229
- Updated
- 2025/07/31
- Product number
- W447704
- Product name
- Ethyl 2-methyl-1,3-dioxolane-2-acetate
- Purity
- ≥99%
- Packaging
- SAMPLE-K
- Price
- $59.8
- Updated
- 2024/03/01
Fructone Chemical Properties,Usage,Production
Chemical Properties
Ethyl (2-Methyl-[1,3]dioxolan-2-yl)-acetate is not found in nature. It is a colorless liquid, d2041.084–1.092, n20D 1.431–1.435, with a strong, fruity, apple-like, slightly green
odor. It can be prepared by acetalization of ethyl acetoacetate with ethylene
glycol.
Very slightly soluble in water, soluble in alcohol and Propylene glycol, miscible with most perfume oils.
Uses
flavors and fragrances
Trade name
Fructone (IFF), Jasmaprunat (Symrise)
Synthesis
141-97-9
107-21-1
6413-10-1
Ethyl acetoacetate (39.0 g, 0.3 mol), ethylene glycol (55.8 g, 0.9 mol), and toluene (200 mL) were added to a 250 mL three-necked, round-bottomed flask fitted with a mechanical stirrer, thermometer, Dean-Stark manifold, and reflux condenser tube. Subsequently, p-toluenesulfonic acid monohydrate (0.2 g, catalytic amount) was added as a catalyst. The reaction mixture was heated to reflux and the water generated during the reaction was removed via a Dean-Stark water separator. After completion of the reaction, the solvent was removed under reduced pressure by rotary evaporator. The residue was distilled under reduced pressure and the fractions with boiling points of 96-99 °C were collected to give 47.6 g of the colorless oily product malate in 91% yield. The infrared spectrum of the product (KBr pressed sheet, cm?1) showed characteristic absorption peaks: 2984, 2890, 1736, 1370, 1049.
References
[1] Journal of Chemical Research - Part S, 1997, # 1, p. 26 - 27
[2] Journal of Organic Chemistry, 1989, vol. 54, # 15, p. 3625 - 3634
[3] Journal of Catalysis, 2000, vol. 196, # 2, p. 345 - 351
[4] Tetrahedron Letters, 2011, vol. 52, # 51, p. 7004 - 7007
[5] RSC Advances, 2016, vol. 6, # 47, p. 41404 - 41409
Fructone Preparation Products And Raw materials
Raw materials
Preparation Products
Fructone Suppliers
- Tel
- 03-36680489
- Fax
- 03-3668-0520
- Sales-JP@TCIchemicals.com
- Country
- Japan
- ProdList
- 28387
- Advantage
- 80
View Lastest Price from Fructone manufacturers
- Product
- Fructone 6413-10-1
- Price
- US $0.00/KG
- Min. Order
- 25KG
- Purity
- 98%min
- Supply Ability
- 30tons/month
- Release date
- 2023-01-14
- Product
- Fructone 6413-10-1
- Price
- US $10.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 100 mt
- Release date
- 2024-11-13
- Product
- Fructone 6413-10-1
- Price
- US $150.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 500kg
- Release date
- 2024-11-20