Ethyl 2-methylacetoacetate

Product Name: Ethyl 2-methylacetoacetate
CAS No.: 609-14-3
Chemical Name: Ethyl 2-methylacetoacetate
Synonyms: Ethyl 2-methyl-3-oxobutanoate;Butanoic acid, 2-methyl-3-oxo-, ethyl ester;Ethyl methylacetoacetate;Acetoacetic acid, 2-methyl-, ethyl ester;NSC 1102;2-Methylacetoacetate;ETHYL 2-ACETYLPROPIONATE;Ethyl 2-acetylpropanoate;Ethyl 2-methylacetacetate;ETHYL 2-METHYL-AETACETATE
CBNumber: CB9106716
Molecular Formula: C7H12O3
Formula Weight: 144.17
MOL File: 609-14-3.mol

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Ethyl 2-methylacetoacetate Property

Melting point:: -45 °C
Boiling point:: 187 °C (lit.)
Density: 1.019 g/mL at 25 °C (lit.)
refractive index: n20/D 1.418(lit.)
Flash point:: 145 °F
storage temp.: Inert atmosphere,Room Temperature
solubility: Chloroform (Slightly), Methanol (Slightly)
pka: 11.98±0.46(Predicted)
form: Liquid
Specific Gravity: 1.019
color: Clear colorless to yellow
Water Solubility: IMMISCIBLE
BRN: 1071742
LogP: 1.063 (est)
CAS DataBase Reference: 609-14-3(CAS DataBase Reference)
NIST Chemistry Reference: Butanoic acid, 2-methyl-3-oxo-, ethyl ester(609-14-3)
EPA Substance Registry System: Butanoic acid, 2-methyl-3-oxo-, ethyl ester (609-14-3)

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Safety

Safety Statements: 24/25
RIDADR: 1993
WGK Germany: 3
TSCA: Yes
HS Code: 29182300

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word: Warning
Hazard statements: H227Combustible liquid
Precautionary statements: P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: E35400
Product name: Ethyl 2-methylacetoacetate
Purity: 90%
Packaging: 25g
Price: $49.8
Updated: 2024/03/01

Sigma-Aldrich

Product number: E35400
Product name: Ethyl 2-methylacetoacetate
Purity: 90%
Packaging: 100g
Price: $144
Updated: 2024/03/01

TCI Chemical

Product number: M0698
Product name: Ethyl 2-Methylacetoacetate
Purity: >95.0%(GC)
Packaging: 25mL
Price: $40
Updated: 2024/03/01

TCI Chemical

Product number: M0698
Product name: Ethyl 2-Methylacetoacetate
Purity: >95.0%(GC)
Packaging: 250mL
Price: $202
Updated: 2024/03/01

Alfa Aesar

Product number: A11629
Product name: Ethyl 2-methylacetoacetate, 95%
Packaging: 25g
Price: $41.65
Updated: 2024/03/01

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Ethyl 2-methylacetoacetate Chemical Properties,Usage,Production

Chemical Properties

clear colorless to yellow liquid

Uses

Ethyl 2-methylacetoacetate is used in Japp-Klingemann reaction to prepare hydrazones from beta-keto acid and aryl diazonium salts. It is used as a precursor involved in the synthesis of ethylpyruvate phenylhydrazone via reaction with benzenediazonium chloride.

Uses

Ethyl 2-methylacetoacetate is used as a substrate in the rhenium-catalyzed synthesis of multisubstituted aromatic compounds.
It can be employed in the synthesis of coumarin derivatives via Pechmann condensation.
It undergoes dehydration to yield conjugated alkynyl and allenyl esters.
It is also used in the total synthesis of chlorotonil A, yangjinhualine A, (+)- and (?)-saudin.

Ethyl 2-methylacetoacetate Preparation Products And Raw materials

Raw materials

Enamelled reactor Ethyl acetoacetate Sodium hydroxide Iodomethane Dimethyl sulfate

Preparation Products

ETHYL 5-BENZYLOXYINDOLE-2-CARBOXYLATE 3,4-DIMETHYLUMBELLIFERONE 2-AMINO-5,6-DIMETHYL-4-HYDROXYPYRIMIDINE

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Ethyl 2-methylacetoacetate Suppliers

Americas 1 Belgium 2 Canada 2 China 273 Europe 2 Germany 6 India 7 Japan 4 Switzerland 4 Ukraine 1 United Kingdom 11 United States 36 Global 349

Weifang Siyuan Chemical Co., Ltd.

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Shandong Vantage Specialty Chemicals Biotechnology Co., Ltd.

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Weifang Weimeng Chemical Co., Ltd.

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J & K SCIENTIFIC LTD.

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future industrial shanghai co., ltd

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Alfa Aesar

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Chemexcel (Zhangjiakou) Fine Chemicals Co., Ltd

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TCI (Shanghai) Development Co., Ltd.

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View Lastest Price from Ethyl 2-methylacetoacetate manufacturers

Hebei Chuanghai Biotechnology Co,.LTD

Product: Ethyl 2-Methylacetoacetate 609-14-3
Price: US $5.00-2.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000kg
Release date: 2024-08-14

Zhuozhou Wenxi import and Export Co., Ltd

Product: Ethyl 2-methylacetoacetate 609-14-3
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-11

Zhuozhou Wenxi import and Export Co., Ltd

Product: Ethyl 2-methylacetoacetate 609-14-3
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-09

609-14-3, Ethyl 2-methylacetoacetateRelated Search:

Diethyl methylmalonate Ethyl 2-ethylacetoacetate Tris(trimethylsilyl)phosphate Methyl acrylate Ethyl acrylate Ethyl 2-chloroacetoacetate Ethyl cyanoacetate Trinexapac-ethyl ISOXADIFEN-ETHYL Ethanol Ethyl propiolate Ethylparaben Ethyl acetate Ethyl acetoacetate Ethyl 4,4,4-trifluoroacetoacetate 2-Hydroxyethyl methacrylate Ethyl 4-chloroacetoacetate Ethyl 4-bromoacetoacetate

2-methyl-3-oxo-butanoicaciethylester

Acetoacetic acid, 2-methyl-, ethyl ester

alpha-Methylacetoacetic ester

Ethyl 2-methyl-3-oxobutanoate

Ethyl 2-methyl-3-oxobutyrate

Ethyl alpha-acetylpropionate

Ethyl alpha-methylacetoacetate

Ethyl alpha-methylacetylacetate

Ethyl ester of 2-methyl-3-oxobutanoic acid

Ethyl methylacetoacetate

2-METHYLACETOACETIC ACID ETHYL ESTER

2-ACETYLPROPIONIC ACID ETHYL ESTER

Alpha-(Aminomethyl)-4-Hydroxy-1,3-Benzenedimethanol

Ethyl 2-methylacetacetate

ETHYL 2-METHYLACETOACETATE

ETHYL 2-ACETYLPROPIONATE

ETHYL 2-METHYL-AETACETATE

(R,S)-2-Methyl-3-oxo-butyric acid ethyl ester

2-methyl-3-oxo-butanoic acid ethyl ester

Butanoic acid, 2-methyl-3-oxo-, ethyl ester

methylacetoacetic acid ethyl ester

Ethl-2-methyl--acetoacetate

Ethyl 2-acetylpropanoate

2-Acetylpropanoic acid ethyl ester

Ethyl 2-methylacetoacetate,95%

Ethyl 2-methylacetoacetate,98%

Ethyl-2-methylacetoacetate 1g [609-14-3]

2-Methyl-3-oxo-butyricacidethylester

2 - Methyl ethyl acetoacetate

Ethyl 2-methylacetoacetate 90%

2-Methylacetoacetate

Ethyl 2-Methylacetoacetate, 95% 100GR

Ethyl 2-Methylacetoacetate, 95% 25GR

NSC 1102

2-Acetylpropionic Acid Ethyl Ester Ethyl 2-Acetylpropionate 2-Methylacetoacetic Acid Ethyl Ester

Ethyl 2-methylacetoacetate in stock Factory

(2R)-2-methyl-3-oxobutanoic acid ethyl ester

Ethyl2-Methylacetoacetate&gt

609-14-3

604-14-3

CH3COCHCH3COOC2H5

CH3COCHCH3CO2C2H5

C7H1203

KETONE

Carbonyl Compounds

C6 to C7

Building Blocks

Organic Building Blocks

Esters

Building Blocks

C6 to C7

Carbonyl Compounds

Chemical Synthesis

Organic Building Blocks

Miscellaneous Reagents

C6 to C7

Carbonyl Compounds

Esters