ChemicalBook > CAS DataBase List > Ethyl 2-methylacetoacetate

Ethyl 2-methylacetoacetate

Product Name
Ethyl 2-methylacetoacetate
CAS No.
609-14-3
Chemical Name
Ethyl 2-methylacetoacetate
Synonyms
Ethyl 2-methyl-3-oxobutanoate;Butanoic acid, 2-methyl-3-oxo-, ethyl ester;Ethyl methylacetoacetate;Acetoacetic acid, 2-methyl-, ethyl ester;NSC 1102;2-Methylacetoacetate;ETHYL 2-ACETYLPROPIONATE;Ethyl 2-acetylpropanoate;Ethyl 2-methylacetacetate;ETHYL 2-METHYL-AETACETATE
CBNumber
CB9106716
Molecular Formula
C7H12O3
Formula Weight
144.17
MOL File
609-14-3.mol
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Ethyl 2-methylacetoacetate Property

Melting point:
-45 °C
Boiling point:
187 °C (lit.)
Density 
1.019 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.418(lit.)
Flash point:
145 °F
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Chloroform (Slightly), Methanol (Slightly)
pka
11.98±0.46(Predicted)
form 
Liquid
Specific Gravity
1.019
color 
Clear colorless to yellow
Water Solubility 
IMMISCIBLE
BRN 
1071742
LogP
1.063 (est)
CAS DataBase Reference
609-14-3(CAS DataBase Reference)
NIST Chemistry Reference
Butanoic acid, 2-methyl-3-oxo-, ethyl ester(609-14-3)
EPA Substance Registry System
Butanoic acid, 2-methyl-3-oxo-, ethyl ester (609-14-3)
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Safety

Safety Statements 
24/25
RIDADR 
1993
WGK Germany 
3
TSCA 
Yes
HS Code 
29182300
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

Precautionary statements

P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
E35400
Product name
Ethyl 2-methylacetoacetate
Purity
90%
Packaging
25g
Price
$49.8
Updated
2024/03/01
Sigma-Aldrich
Product number
E35400
Product name
Ethyl 2-methylacetoacetate
Purity
90%
Packaging
100g
Price
$144
Updated
2024/03/01
TCI Chemical
Product number
M0698
Product name
Ethyl 2-Methylacetoacetate
Purity
>95.0%(GC)
Packaging
25mL
Price
$40
Updated
2024/03/01
TCI Chemical
Product number
M0698
Product name
Ethyl 2-Methylacetoacetate
Purity
>95.0%(GC)
Packaging
250mL
Price
$202
Updated
2024/03/01
Alfa Aesar
Product number
A11629
Product name
Ethyl 2-methylacetoacetate, 95%
Packaging
25g
Price
$41.65
Updated
2024/03/01
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Ethyl 2-methylacetoacetate Chemical Properties,Usage,Production

Chemical Properties

clear colorless to yellow liquid

Uses

Ethyl 2-methylacetoacetate is used in Japp-Klingemann reaction to prepare hydrazones from beta-keto acid and aryl diazonium salts. It is used as a precursor involved in the synthesis of ethylpyruvate phenylhydrazone via reaction with benzenediazonium chloride.

Uses

  • Ethyl 2-methylacetoacetate is used as a substrate in the rhenium-catalyzed synthesis of multisubstituted aromatic compounds.
  • It can be employed in the synthesis of coumarin derivatives via Pechmann condensation.
  • It undergoes dehydration to yield conjugated alkynyl and allenyl esters.
  • It is also used in the total synthesis of chlorotonil A, yangjinhualine A, (+)- and (?)-saudin.

Ethyl 2-methylacetoacetate Preparation Products And Raw materials

Raw materials

Enamelled reactor Ethyl acetoacetate Sodium hydroxide Iodomethane Dimethyl sulfate

Preparation Products

ETHYL 5-BENZYLOXYINDOLE-2-CARBOXYLATE 3,4-DIMETHYLUMBELLIFERONE 2-AMINO-5,6-DIMETHYL-4-HYDROXYPYRIMIDINE
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View Lastest Price from Ethyl 2-methylacetoacetate manufacturers

Hebei Guanlang Biotechnology Co,.LTD
Product
Ethyl 2-Methylacetoacetate 609-14-3
Price
US $5.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2023-04-13
Zhuozhou Wenxi import and Export Co., Ltd
Product
Ethyl 2-methylacetoacetate 609-14-3
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-11
Zhuozhou Wenxi import and Export Co., Ltd
Product
Ethyl 2-methylacetoacetate 609-14-3
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-09

609-14-3, Ethyl 2-methylacetoacetateRelated Search:

Diethyl methylmalonate Ethyl 2-ethylacetoacetate Tris(trimethylsilyl)phosphate Methyl acrylate Ethyl acrylate Ethyl 2-chloroacetoacetate Ethyl cyanoacetate Trinexapac-ethyl ISOXADIFEN-ETHYL Ethanol Ethyl propiolate Ethylparaben Ethyl acetate Ethyl acetoacetate Ethyl 4,4,4-trifluoroacetoacetate 2-Hydroxyethyl methacrylate Ethyl 4-chloroacetoacetate Ethyl 4-bromoacetoacetate

  • 2-methyl-3-oxo-butanoicaciethylester
  • Acetoacetic acid, 2-methyl-, ethyl ester
  • alpha-Methylacetoacetic ester
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  • (R,S)-2-Methyl-3-oxo-butyric acid ethyl ester
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  • Ethl-2-methyl--acetoacetate
  • Ethyl 2-acetylpropanoate
  • 2-Acetylpropanoic acid ethyl ester
  • Ethyl 2-methylacetoacetate,95%
  • Ethyl 2-methylacetoacetate,98%
  • Ethyl-2-methylacetoacetate 1g [609-14-3]
  • 2-Methyl-3-oxo-butyricacidethylester
  • 2 - Methyl ethyl acetoacetate
  • Ethyl 2-methylacetoacetate 90%
  • 2-Methylacetoacetate
  • Ethyl 2-Methylacetoacetate, 95% 100GR
  • Ethyl 2-Methylacetoacetate, 95% 25GR
  • NSC 1102
  • 2-Acetylpropionic Acid Ethyl Ester Ethyl 2-Acetylpropionate 2-Methylacetoacetic Acid Ethyl Ester
  • Ethyl 2-methylacetoacetate in stock Factory
  • (2R)-2-methyl-3-oxobutanoic acid ethyl ester
  • Ethyl2-Methylacetoacetate&gt
  • 609-14-3
  • 604-14-3
  • CH3COCHCH3COOC2H5
  • CH3COCHCH3CO2C2H5
  • C7H1203
  • KETONE
  • Carbonyl Compounds
  • C6 to C7
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  • C6 to C7
  • Carbonyl Compounds
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