ChemicalBook > CAS DataBase List > (S)-(+)-alpha-Methoxyphenylacetic acid

(S)-(+)-alpha-Methoxyphenylacetic acid

Product Name
(S)-(+)-alpha-Methoxyphenylacetic acid
CAS No.
26164-26-1
Chemical Name
(S)-(+)-alpha-Methoxyphenylacetic acid
Synonyms
O-METHYL-L-MANDELIC ACID;O-Methyl-(S)-mandelicacid;L-α-Methoxyphenylacetic Acid;(+)-Methoxyphenylacetic acid;(S)-(+)-O-MethylMandelic Acid;(S)-α-Methoxybenzeneacetic acid;(S)-(+)-METHOXYPHENYLACETIC ACID;(αS)-α-Methoxybenzeneacetic acid;Acetic acid, Methoxyphenyl-, (S)-;(s)-(+)-à-methoxyphenylacetic acid
CBNumber
CB1742293
Molecular Formula
C9H10O3
Formula Weight
166.17
MOL File
26164-26-1.mol
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(S)-(+)-alpha-Methoxyphenylacetic acid Property

Melting point:
64-66 °C(lit.)
Boiling point:
164-166°C 18mm
alpha 
160 º (C=1, MEOH)
Density 
1.1708 (rough estimate)
refractive index 
147 ° (C=0.5, EtOH)
Flash point:
164-166°C/18mm
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform (Slightly), Ethanol (Slightly)
form 
Fine Crystalline Powder or Crystals
pka
3.10±0.10(Predicted)
color 
White
optical activity
[α]17/D +150°, c = 1 in ethanol
Water Solubility 
Soluble
BRN 
2361718
CAS DataBase Reference
26164-26-1(CAS DataBase Reference)
NIST Chemistry Reference
Benzeneacetic acid, «alpha»-methoxy-, (s)-(26164-26-1)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
29189900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
248983
Product name
(S)-(+)-α-Methoxyphenylacetic acid
Purity
99%
Packaging
1g
Price
$296
Updated
2024/03/01
TCI Chemical
Product number
M0829
Product name
(S)-(+)-α-Methoxyphenylacetic Acid
Purity
>98.0%(GC)(T)
Packaging
1g
Price
$102
Updated
2024/03/01
TCI Chemical
Product number
M0829
Product name
(S)-(+)-α-Methoxyphenylacetic Acid
Purity
>98.0%(GC)(T)
Packaging
5g
Price
$309
Updated
2024/03/01
Alfa Aesar
Product number
L08748
Product name
(S)-(+)-alpha-Methoxyphenylacetic acid, 99%
Packaging
250mg
Price
$42.65
Updated
2024/03/01
Alfa Aesar
Product number
L08748
Product name
(S)-(+)-alpha-Methoxyphenylacetic acid, 99%
Packaging
1g
Price
$104.65
Updated
2024/03/01
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(S)-(+)-alpha-Methoxyphenylacetic acid Chemical Properties,Usage,Production

Chemical Properties

White Solid

Uses

(S)-(+)-α-Methoxyphenylacetic Acid (cas# 26164-26-1) is a compound useful in organic synthesis.

Uses

Reactant involved in the synthesis of biologically active molecules including:

  • Acyclonucleoside phosphonates structural analogs of adefovir
  • Labeled discodermolide for studying binding to tubulin
  • 10-Isocyano-4-cadinene used for antifouling activity

Reactant involved in studies of immunostimulating chromanones gonytolides A-C

Reactant involved in:
  • Hydroxylations and epoxidations
  • Hydrogenations

Purification Methods

Purify the acids by recrystallising from *C6H6/pet ether (b 80-100o). [Neilson & Peters J Chem Soc 1519 1962, Weizmann et al. J Am Chem Soc 70 1153 1948, Pirie & Smith J Chem Soc 338 1932, NMR: Dale & Mosher J Am Chem Soc 9 5 512 1973, for resolution: Roy & Deslongchamps Can J Chem 63 651 1985, Trost et al. J Am Chem Soc 1 0 8 4974 1986.] The racemic mixture has m 72o, b 121-122o/0.4mm, 165o/18mm (from pet ether) [Braun et al. Chem Ber 6 3 2847 1930]. [Beilstein 10 IV 566.]

(S)-(+)-alpha-Methoxyphenylacetic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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(S)-(+)-alpha-Methoxyphenylacetic acid Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
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96815
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Meryer (Shanghai) Chemical Technology Co., Ltd.
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4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
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China
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3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
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China
ProdList
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Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
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TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
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Sales-CN@TCIchemicals.com
Country
China
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24539
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Beijing Ouhe Technology Co., Ltd
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010-82967028 13552068683
Fax
+86-10-82967029
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2355560935@qq.com
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China
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Jia Xing Isenchem Co.,Ltd
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0573-85285100 18627885956
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0573-85285100
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isenchem@163.com
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China
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Accela ChemBio Co.,Ltd.
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021-50795510 4000665055
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021-50795055
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sales@accelachem.com
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China
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11660
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64
Shanghai Longsheng chemical Co.,Ltd.
Tel
021-58099652-8005 13585536065
Fax
021-58099609
Email
bin.wu@shlschem.com
Country
China
ProdList
9816
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59
Nanjing Chemlin Chemical Co., Ltd
Tel
025-83697070
Fax
+86-25-83453306
Email
info@chemlin.com.cn
Country
China
ProdList
17988
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64
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View Lastest Price from (S)-(+)-alpha-Methoxyphenylacetic acid manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
(S)-(+)-alpha-Methoxyphenylacetic acid 26164-26-1
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-09-27
Career Henan Chemical Co
Product
(S)-(+)-alpha-Methoxyphenylacetic acid 26164-26-1
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kgs
Release date
2020-01-29

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