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ChemicalBook > CAS DataBase List > (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a

(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a

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Product Name
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
CAS No.
252288-04-3
Chemical Name
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
Synonyms
3,4-a']dinaphthalen-4-yl)diethylamine;3,4-a'']dinaphthalen-4-yl)diethylamine;3,4-a']dinaphthalen-4-yl)diethylamine,97%;3,4-a']dinaphthalen-4-yl)diethylamine,97%;3,4-a']dinaphthalen-4-yl)diethylamine,min.97%;3,4-a']dinaphthalen-4-yl)diethylamine, min. 97%;(S)-N,N-Diethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine;(S)-N,N-Diethyldinaphtho[2,1-d:1',2'-f][1,3,2]-dioxaphosphepin-4-amine;(11bS)-N,N-Diethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine;(11bS)-N,N-Diethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
CBNumber
CB21180996
Molecular Formula
C24H22NO2P
Formula Weight
387.41
MOL File
252288-04-3.mol
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(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Property

Boiling point:
566.4±33.0 °C(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
1.71±0.20(Predicted)
form 
Powder
color 
white
Sensitive 
moisture sensitive
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Strem Chemicals
Product number
15-1231
Product name
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)diethylamine, min. 97%
Packaging
250mg
Price
$68
Updated
2024/03/01
Strem Chemicals
Product number
15-1231
Product name
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)diethylamine, min. 97%
Packaging
1g
Price
$200
Updated
2024/03/01
Matrix Scientific
Product number
093081
Product name
(S)-N,N-Diethyldinaphtho[2,1-d:1',2'-f][1,3,2]-dioxaphosphepin-4-amine
Purity
95+%
Packaging
250mg
Price
$167
Updated
2021/12/16
Matrix Scientific
Product number
093081
Product name
(S)-N,N-Diethyldinaphtho[2,1-d:1',2'-f][1,3,2]-dioxaphosphepin-4-amine
Purity
95+%
Packaging
1g
Price
$370
Updated
2021/12/16
Matrix Scientific
Product number
093081
Product name
(S)-N,N-Diethyldinaphtho[2,1-d:1',2'-f][1,3,2]-dioxaphosphepin-4-amine
Purity
95+%
Packaging
5g
Price
$1229
Updated
2021/12/16
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(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Chemical Properties,Usage,Production

Reaction

  1. Ligand used in the enantioselective rhodium catalyzed low pressure high activity hydrogenation of α–dehydroaminoesters, enamides, and dimethylitaconate.
  2. Ligand used in enantioselective rhodium-catalyzed allylic C–H activation for addition to conjugated dienes.

(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Preparation Products And Raw materials

Raw materials

Preparation Products

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(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Suppliers

China 38 United States 5 Global 43
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Strem Chemicals, Inc.
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Alfa Chemistry
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252288-04-3, (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-aRelated Search:

3,4-a']dinaphthalen-4-yl)dipropylaMine (11bS)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine (11bS)-8,9,10,11,12,13,14,15-octahydro-N,N-bis[(1S)-1-phenylethyl]-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-aMine N,N-diisopropyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a (+)-N,N-BIS[(1R)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)

  • 3,4-a']dinaphthalen-4-yl)diethylamine,min.97%
  • (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A'']DINAPHTHALEN-4-YL)DIETHYLAMINE, MIN. 97%
  • (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)diethylamine
  • 3,4-a']dinaphthalen-4-yl)diethylamine
  • 3,4-a']dinaphthalen-4-yl)diethylamine, min. 97%
  • (S)-N,N-Diethyldinaphtho[2,1-d:1',2'-f][1,3,2]-dioxaphosphepin-4-amine
  • (11bS)-N,N-Diethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
  • (11bS)-N,N-Diethyl-dinaphtho[2,1-d:1',2'-f][1,3,2] dioxaphosphepin-4-amine,99%e.e.
  • 3,4-a']dinaphthalen-4-yl)diethylamine,97%
  • (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A;3,4-A']DINAPHTHALEN-4-YL)DIETHYLAMINE,MIN.97%
  • Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N,N-diethyl-, (11bS)-
  • 3,4-a'']dinaphthalen-4-yl)diethylamine
  • (11bS)-N,N-Diethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
  • (S)-N,N-Diethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
  • 3,4-a']dinaphthalen-4-yl)diethylamine,97%
  • 252288-04-3
  • Chiral Phosphine
  • CPN