ChemicalBook > CAS DataBase List > (S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE

(S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE

Product Name
(S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE
CAS No.
63126-47-6
Chemical Name
(S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE
Synonyms
SMP;H-PRO-OL(ME);H-S-PYR-MEOME;L-Prolinol-OMe;O-METHYL-D-PROLINOL;O-METHYL-L-PROLINOL;PROLINOL-METHYL-ETHER;L-PROLINOL METHYL ETHER;O-Methyl-L-prolinol, SMP;(S)-2-(METHOXYMETHYL)PYRROLIDINE
CBNumber
CB2124340
Molecular Formula
C6H13NO
Formula Weight
115.17
MOL File
63126-47-6.mol
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(S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE Property

Boiling point:
62 °C40 mm Hg(lit.)
Density 
0.933 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.446
Flash point:
114 °F
storage temp. 
Keep in dark place,Inert atmosphere,2-8°C
form 
Liquid
pka
10.01±0.10(Predicted)
color 
Clear colorless to yellow
optical activity
[α]20/D +2.4°, c = 2 in benzene
Sensitive 
Air Sensitive
BRN 
3587324
CAS DataBase Reference
63126-47-6(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
10-36/37/38
Safety Statements 
26-36
RIDADR 
UN 1993 3/PG 3
WGK Germany 
3
F 
3-9-34
HazardClass 
3
PackingGroup 
III
HS Code 
29339900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
277053
Product name
(S)-(+)-2-(Methoxymethyl)pyrrolidine
Purity
99%
Packaging
500mg
Price
$92.6
Updated
2023/06/20
Sigma-Aldrich
Product number
277053
Product name
(S)-(+)-2-(Methoxymethyl)pyrrolidine
Purity
99%
Packaging
5g
Price
$249
Updated
2023/06/20
TCI Chemical
Product number
M1161
Product name
(S)-2-(Methoxymethyl)pyrrolidine
Purity
>98.0%(GC)
Packaging
1g
Price
$72
Updated
2024/03/01
TCI Chemical
Product number
M1161
Product name
(S)-2-(Methoxymethyl)pyrrolidine
Purity
>98.0%(GC)
Packaging
5g
Price
$242
Updated
2024/03/01
Alfa Aesar
Product number
L09608
Product name
(S)-(+)-2-(Methoxymethyl)pyrrolidine, 98%
Packaging
1g
Price
$107.65
Updated
2024/03/01
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(S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE Chemical Properties,Usage,Production

Chemical Properties

clear colorless to yellow liquid

Uses

(S)-(+)-2-(Methoxymethyl)pyrrolidine may be used to prepare planar chiral 2-phospha[3]ferrocenophanes. It may also be used as an organocatalyst in the cross-aldol reaction of dihydroxyacetone with p-nitrobenzaldehyde to form the corresponding polyol. SMP reacts with benzoylformic acid to form (S)-N-benzoylformyl-2-(methoxymethyl)-pyrrolidine.

Definition

ChEBI: (S)-2-(methoxymethyl)pyrrolidine is a member of the class of pyrrolidines in which the only substituent is a methoxymethyl group at position 2 (the S-enantiomer0. It is a member of pyrrolidines and an ether.

(S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

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(S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE Suppliers

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View Lastest Price from (S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE manufacturers

Career Henan Chemical Co
Product
(S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE 63126-47-6
Price
US $1.00/kg
Min. Order
1kg
Purity
95%-99%
Supply Ability
as request
Release date
2018-12-24

63126-47-6, (S)-(+)-2-(METHOXYMETHYL)PYRROLIDINERelated Search:

(S)-(-)-1-AMINO-2-(METHOXYMETHYL)PYRROLIDINE Methyl pyrrolidine-2-carboxylate hydrochloride Ethyl D-(-)-pyroglutamate (R)-(+)-1-AMINO-2-(METHOXYMETHYL)PYRROLIDINE L-PYROGLUTAMIC ACID PENTACHLOROPHENYL ESTER DIHYDROERGOTAMINE MESYLATE Z-HYP-OME Methyl L-prolinate hydrochloride DIHYDROERGOTAMINE TARTRATE H-PRO-OTBU N-CBZ-L-PROLINE TERT-BUTYL ESTER (S)-(-)-2-(METHOXYMETHYL)-1-PYRROLIDINECARBOXALDEHYDE L-Proline benzyl ester hydrochloride Ethyl L-pyroglutamate (S,S)-(+)-2,5-BIS(METHOXYMETHYL)PYRROLIDINE N-METHYL-D-PROLINOL (R)-(+)-1-FORMYL-2-(METHOXYMETHYL)PYRROLIDINE (S)-(+)-2-[HYDROXY(DIPHENYL)METHYL]-1-METHYLPYRROLIDINE

  • L-PROLINOL METHYL ETHER
  • H-PRO-OL(ME)
  • H-S-PYR-MEOME
  • PROLINOL-METHYL-ETHER
  • O-METHYL-L-PROLINOL
  • O-METHYL-D-PROLINOL
  • (S)-2-PYRROLIDINEMETHYL-METHYL ETHER
  • (S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE
  • (S)-2-(METHOXYMETHYL)PYRROLIDINE
  • (S)-2-(METHOXYMETHYL)-PYRROLIDINEMETHYL
  • SMP
  • (S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE, 99 %
  • (S)-(+)-2-(Methoxymethyl)pyrrplidine
  • PROLINOL-METHYL-ETHER, (S)-2-PYRROLIDINEMETHYL-METHYL ETHER, (S)-2-(METHOXYMETHYL)-PYRROLIDINEMETHYL
  • (S)-2-Pyrrolidinemethyl-methyl ether, (S)-2-(Methoxymethyl)-pyrrolidinemethyl
  • L-Prolinol-OMe
  • O-Methyl-L-prolinol, SMP
  • (S)-2-Methoxymethylpyrrolidine[SMP]
  • (S)-(+)-2-(Methoxymethyl)pyrrolidine,O-Methyl-L-prolinol, SMP
  • (2S)-2-(Methoxymethyl)pyrrolidine
  • (S)-(+)-2-(Methoxymethyl)pyrolidine
  • H-Pro-Ol-Me, O-Methyl-L-prolinol
  • (S)-(+)-2-(MethoxyMethyl)pyrrolidine, 99% 2.5GR
  • (S)-(+)-2-(MethoxyMethyl)pyrrolidine, 99% 500MG
  • (S)-(+)-2-(MethoxyMethyl)pyrrolidine puruM, >=98.0% (suM of enantioMers, GC)
  • SMP, O-Methyl-L-prolinol, L-Prolinol methyl ether
  • (S)-2-(Methoxymethyl)-pyrrolidine HCl
  • Pyrrolidine,2-(methoxymethyl)-, (2S)-
  • (S)-(+)-2-(Methoxymethyl)pyrrolidine, 98.5%
  • (S)-2-Methoxymethyl-pyrrolidine hydrochloride
  • (S)-2-(Methoxymethyl)pyrrolidine&gt
  • (+)-(S)-2-(Methoxymethyl)pyrrolidine
  • 63126-47-6
  • 631260-47-6
  • AMINE
  • Chiral Catalysts, Ligands, and Reagents
  • Proline-Based Organocatalysts
  • Asymmetric Synthesis
  • Imidazoles, Pyrroles, Pyrazoles, Pyrrolidines
  • Asymmetric Synthesis
  • Synthetic Organic Chemistry
  • Chiral Compound