ChemicalBook > CAS DataBase List > 4-Chlorobenzotrichloride

4-Chlorobenzotrichloride

Product Name
4-Chlorobenzotrichloride
CAS No.
5216-25-1
Chemical Name
4-Chlorobenzotrichloride
Synonyms
PCTC;orobenzotrichL;Tetrachlorotoluene;4-Chlorobenzotrichlo;4-Chlorbenzotrichlorid;p-Chlorbenzotrichlorid;4-chlorobenzotrichlorid;Clotrimazole Impurity 5;P-CHLOROBENZOTRICHLORIDE;p-Chlorotrichlorotoluene
CBNumber
CB2146946
Molecular Formula
C7H4Cl4
Formula Weight
229.92
MOL File
5216-25-1.mol
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4-Chlorobenzotrichloride Property

Melting point:
5.8 °C
Boiling point:
245 °C(lit.)
Density 
1.495 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.572(lit.)
Flash point:
>230 °F
solubility 
Chloroform (Sparingly), DMSO (Sparingly)
form 
clear liquid
color 
Colorless to Light yellow
Water Solubility 
decomposes
Sensitive 
Moisture Sensitive
BRN 
1866549
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents.
CAS DataBase Reference
5216-25-1(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 1-chloro-4-(trichloromethyl)-(5216-25-1)
EPA Substance Registry System
4-Chlorobenzotrichloride (5216-25-1)
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Safety

Hazard Codes 
T
Risk Statements 
45-21/22-37/38-48/23-62
Safety Statements 
53-45
RIDADR 
UN 1760 8/PG 2
WGK Germany 
3
RTECS 
XT8580000
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
29039990
Toxicity
LD50 orl-rat: 820 mg/kg EPASR* 8EHQ-0281-0360
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H350May cause cancer

H361Suspected of damaging fertility or the unborn child

H372Causes damage to organs through prolonged or repeated exposure

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P201Obtain special instructions before use.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P314Get medical advice/attention if you feel unwell.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
T0072
Product name
4-Chlorobenzotrichloride
Packaging
25G
Price
$16
Updated
2023/01/07
TCI Chemical
Product number
T0072
Product name
4-Chlorobenzotrichloride
Packaging
500G
Price
$59
Updated
2021/12/16
Alfa Aesar
Product number
B23446
Product name
4-Chlorobenzotrichloride, 98+%
Packaging
25g
Price
$25.1
Updated
2021/12/16
Alfa Aesar
Product number
B23446
Product name
4-Chlorobenzotrichloride, 98+%
Packaging
100g
Price
$27.1
Updated
2021/12/16
Alfa Aesar
Product number
B23446
Product name
4-Chlorobenzotrichloride
Purity
98+%
Packaging
500g
Price
$61.3
Updated
2021/12/16
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4-Chlorobenzotrichloride Chemical Properties,Usage,Production

Description

p-Chlorobenzotrichloride, an organochloride,is a flammable, water-white liquid. Molecularweight=229.92; Specific gravity (H2O:1)=1.49; Boilingpoint=254℃; Melting/Freezing point=5-6℃; Flashpoint=.110℃; Autoignition temperature=500-505℃.Hazard Identification (based on NFPA 704 M RatingSystem): Health 3, Flammability 1, Reactivity 0.Decomposes in water.

Chemical Properties

p-Chlorobenzotrichloride, an organochloride, is a flammable, water-white liquid.

Uses

Same as o-chlorobenzotrichloride.

Uses

4-Chlorobenzotrichloride is a useful reactant in organic synthesis.

General Description

Clear colorless liquid.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Simple aromatic halogenated organic compounds, such as 4-Chlorobenzotrichloride , are very unreactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Materials in this group may be incompatible with strong oxidizing and reducing agents. Also, they may be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.

Health Hazard

ACUTE/CHRONIC HAZARDS: Corrosive; Lachrymator.

Fire Hazard

Flash point data for 4-Chlorobenzotrichloride are not available, however, 4-Chlorobenzotrichloride is probably combustible.

Flammability and Explosibility

Not classified

Safety Profile

Suspected carcinogen. A poison by inhalation. Moderately toxic by ingestion and skin contact. When heated to decomposition it emits toxic vapors of Cl-.

Potential Exposure

Used in agrochemicals manufacture as an intermediate; reaction with HF yields chlorobenzotrifluoride as a major intermediate for several pesticides; for making pharmaceuticals; UV absorbers, and dyestuffs. This chemical is manufactured in high volume (exceeds 1 million pounds per annum) in the United States.

First aid

this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek med?ical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, includ?ing resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalp-Chlorobenzotrichloride 641facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.

storage

Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Store in tightly closed containers in a refrigerator. Color Code—Red: FlammabilityHazard: Store in a flammable liquid storage area orapproved cabinet away from ignition sources and corrosiveand reactive materials. Prior to working with this chemicalyou should be trained on its proper handling and storage. Aregulated, marked area should be established where thischemical is handled, used, or stored in compliance withOSHA Standard 1910.1045.

Shipping

UN1760 Corrosive liquids, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name Required.

Incompatibilities

A halogenated aromatic compound. Hydrolyzes to hydrochloric acid and benzoic acid in all forms of moisture. Incompatible with strong oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from reducing agents, alkaline materials, strong acids, strong bases, amines, nitrides, azo/ diazo compounds, alkali metals, and epoxides.

4-Chlorobenzotrichloride Preparation Products And Raw materials

Raw materials

4-Chlorotoluene

Preparation Products

4-Chloro-3-nitrobenzoic acid Fomesafen 4-Chlorobenzotrifluoride
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4-Chlorobenzotrichloride Suppliers

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View Lastest Price from 4-Chlorobenzotrichloride manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
4-Chlorobenzotrichloride 5216-25-1
Price
US $9.80/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 tons
Release date
2024-11-14
Hebei Mojin Biotechnology Co., Ltd
Product
4-Chlorotrichlorotoluene 5216-25-1
Price
US $100.00/Kg/Drum
Min. Order
1KG
Purity
99%
Supply Ability
1000tons
Release date
2021-10-19
Career Henan Chemical Co
Product
4-Chlorobenzotrichloride 5216-25-1
Price
US $1.00/kg
Min. Order
1g
Purity
99%
Supply Ability
100KG
Release date
2018-12-19

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