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Malonyl chloride

Product Name
Malonyl chloride
CAS No.
1663-67-8
Chemical Name
Malonyl chloride
Synonyms
MALONYL DICHLORIDE;PROPANEDIOYL CHLORIDE;Malonyl dichlorid;Malonic acid dichloride;Propanedioyl dichloride;onyL;Prodipionyl;MALONYL CHLORIDE;Malonoyl chloride;MalonylChloride>
CBNumber
CB2148430
Molecular Formula
C3H2Cl2O2
Formula Weight
140.95
MOL File
1663-67-8.mol
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Malonyl chloride Property

Boiling point:
53-55 °C/19 mmHg (lit.)
Density 
1.449 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.465(lit.)
Flash point:
117 °F
storage temp. 
2-8°C
solubility 
sol most organic solvents
form 
Liquid
pka
6.86±0.46(Predicted)
color 
Clear yellow to orange to brown
Water Solubility 
decomposes
BRN 
774044
CAS DataBase Reference
1663-67-8(CAS DataBase Reference)
NIST Chemistry Reference
Malonyl dichloride(1663-67-8)
EPA Substance Registry System
Propanedioyl dichloride (1663-67-8)
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Safety

Hazard Codes 
C
Risk Statements 
14-34-29-10
Safety Statements 
26-36/37/39-45-16
RIDADR 
UN 2920 8/PG 2
WGK Germany 
-
8-10
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
29171990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H226Flammable liquid and vapour

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
M1601
Product name
Malonyl chloride
Purity
97%
Packaging
5g
Price
$44.5
Updated
2024/03/01
Sigma-Aldrich
Product number
M1601
Product name
Malonyl chloride
Purity
97%
Packaging
25g
Price
$151
Updated
2024/03/01
TCI Chemical
Product number
M0882
Product name
Malonyl Chloride
Purity
>97.0%(T)
Packaging
10g
Price
$69
Updated
2024/03/01
TCI Chemical
Product number
M0882
Product name
Malonyl Chloride
Purity
>97.0%(T)
Packaging
25g
Price
$128
Updated
2024/03/01
Alfa Aesar
Product number
H59868
Product name
Malonyl dichloride, 97%
Packaging
25g
Price
$136
Updated
2024/03/01
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Malonyl chloride Chemical Properties,Usage,Production

Chemical Properties

clear yellow to orange to brown liquid

Uses

Malonyl Dichloride is primarily used an intermediate in the manufacture of pharmaceutical and agrochemical products.

Uses

Malonyl chloride can be used as a reactant for the synthesis of:

  • Alkaloids with tetracyclic cores such as cyclopiamide A and speradine E.
  • 6-tetrathiafulvalene(TTF)-polymer by condensation polymerization with TTF-based dihydroxy monomer.
  • N-doped TiO2 films by molecular layer deposition.
  • Alkyne-substituted 1,3-oxazines by reaction with arylpropynamides.

It can also be used as a coupling agent in the synthesis of block copolymers by anionic polymerization.

Preparation

Malonyl chloride can be prepared from Malonic Acid and Thionyl Chloride.

Reactions

reacts violently with H2O and protic solvents

storage

Malonyl chloride is unstable at rt and should be used freshly distilled in vacuo or freshly prepared; however, it can be stored in the cold for several days; lachrymatory; use in a fume hood.

Malonyl chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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Malonyl chloride Suppliers

Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Ningbo jinuo chemical co., LTD
Tel
0574-87314919 057487319282
Email
info@nbinno.com
Country
China
ProdList
7037
Advantage
58
Shandong Xinying Shun New Materials Co., Ltd
Tel
0531-13220555910 15168808500
Email
lijinbo112@163.com
Country
China
ProdList
510
Advantage
58
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12390
Advantage
60
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9976
Advantage
60
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9510
Advantage
66
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
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View Lastest Price from Malonyl chloride manufacturers

Anhui Yisheng Technology Co., LTD
Product
malonoyl chloride 1663-67-8
Price
US $150.00-100.00/kg
Min. Order
1kg
Purity
99.99%
Supply Ability
2 tons/month
Release date
2023-04-23
Weijer International Trade (Hebei) Co., Ltd
Product
malonoyl chloride 1663-67-8
Price
US $15.00/KG
Min. Order
1KG
Purity
>99%
Supply Ability
50000kg/Month
Release date
2023-03-14
Zhuozhou Wenxi import and Export Co., Ltd
Product
malonoyl chloride 1663-67-8
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27

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