ChemicalBook > CAS DataBase List > Ethyl (3-fluorobenzoyl)acetate

Ethyl (3-fluorobenzoyl)acetate

Product Name
Ethyl (3-fluorobenzoyl)acetate
CAS No.
33166-77-7
Chemical Name
Ethyl (3-fluorobenzoyl)acetate
Synonyms
Ethyl m-fluorobenzoyl acetate;Ethyl 2-3-fluorobenzoylacetate;ETHYL (3-FLUOROBENZOYL)ACETATE;Ethyl 3-fluoro-β-oxobenzenepropanoate;(m-Fluorobenzoyl)acetic acid ethyl ester;ETHYL 3-(3-FLUOROPHENYL)-3-OXOPROPANOATE;3-(3-Fluorophenyl)-3-oxopropanoic acid ethyl ester;Benzenepropanoic acid, 3-fluoro-β-oxo-, ethyl ester;Benzenepropanoic acid, 3-fluoro-β-oxo-, ethyl ester;3-（3-Fluoro-phenyl）-3-oxo-propionic acid ethyl bster
CBNumber
CB2148920
Molecular Formula
C11H11FO3
Formula Weight
210.2
MOL File
33166-77-7.mol
More
Less

Ethyl (3-fluorobenzoyl)acetate Property

Boiling point:
262-263 °C(lit.)
Density 
1.166 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.5172(lit.)
Flash point:
>230 °F
storage temp. 
Sealed in dry,Room Temperature
form 
Liquid
pka
10.10±0.46(Predicted)
color 
Colorless to orange
CAS DataBase Reference
33166-77-7(CAS DataBase Reference)
More
Less

Safety

WGK Germany 
3
TSCA 
Yes
HS Code 
2916399090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
559237
Product name
Ethyl (3-fluorobenzoyl)acetate
Packaging
1g
Price
$96.1
Updated
2023/06/20
Sigma-Aldrich
Product number
559237
Product name
Ethyl (3-fluorobenzoyl)acetate
Packaging
5g
Price
$230
Updated
2023/01/07
Alfa Aesar
Product number
H61315
Product name
Ethyl (3-fluorobenzoyl)acetate, 98%
Packaging
1g
Price
$80.65
Updated
2024/03/01
Alfa Aesar
Product number
H61315
Product name
Ethyl (3-fluorobenzoyl)acetate, 98%
Packaging
5g
Price
$274.65
Updated
2024/03/01
Alfa Aesar
Product number
H61315
Product name
Ethyl (3-fluorobenzoyl)acetate, 98%
Packaging
250mg
Price
$26.65
Updated
2024/03/01
More
Less

Ethyl (3-fluorobenzoyl)acetate Chemical Properties,Usage,Production

Uses

Reactant for:

  • Preparation of biologically active molecules

Synthesis

To a stirring suspension of NaH and CO(OEt)2 in toluene was added dropwise a solution of substituted acetophenone in toluene under reflux. The mixture was allowed to reflux and was stirred for 20 min after the addition was complete. When cooled to room temperature, the mixture was acidified with glacial HOAc. After ice-cold water was added, the mixture was extracted with toluene. The extract was then dried over anhydrous MgS04. After the toluene was evaporated in vacuo to give the corresponding substituted Ethyl (3-fluorobenzoyl)acetate.

Ethyl (3-fluorobenzoyl)acetate Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

Ethyl (3-fluorobenzoyl)acetate Suppliers

Canada 1 China 117 Germany 2 India 2 Switzerland 1 Ukraine 1 United Kingdom 4 United States 17 Global 145
SiChuang NanBu Honesty Technology Co., Ltd.
Tel
0838-5675166 15883665058
Fax
0838-5675535
Email
nbcxkj@126.com
Country
China
ProdList
667
Advantage
55
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12438
Advantage
60
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9976
Advantage
60
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Syntechem Co.,Ltd
Tel
Fax
E-Mail Inquiry
Email
info@syntechem.com
Country
China
ProdList
12984
Advantage
57
Hangzhou Yuhao Chemical Technology Co., Ltd
Tel
0571-82693216
Fax
+86-571-82880190
Email
info@yuhaochemical.com
Country
China
ProdList
9387
Advantage
52
Shanghai Sphchem Co., Ltd.
Tel
21-21-56491756 13512199871
Fax
021-5649-1756
Email
sales@panhongchem.com
Country
China
ProdList
3999
Advantage
55
More
Less

View Lastest Price from Ethyl (3-fluorobenzoyl)acetate manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
3-(3-FLUORO-PHENYL)-3-OXO-PROPIONIC ACID ETHYL ESTER 33166-77-7
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2023-02-08
Hebei Mojin Biotechnology Co., Ltd
Product
3-(3-FLUORO-PHENYL)-3-OXO-PROPIONIC ACID ETHYL ESTER 33166-77-7
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-07-28
Career Henan Chemical Co
Product
3-(3-FLUORO-PHENYL)-3-OXO-PROPIONIC ACID ETHYL ESTER 33166-77-7
Price
US $1.00/g
Min. Order
100EA
Purity
98%min
Supply Ability
G/KG/T
Release date
2019-12-23

33166-77-7, Ethyl (3-fluorobenzoyl)acetateRelated Search:

Ethyl 1-ethyl-6,7,8-trifluoro-1,4-dihydro-4-oxoquinoline-3-carboxylate 3-(4-FLUORO-PHENYL)-3-OXO-PROPIONIC ACID ETHYL ESTER ETHYL 1,4-DIHYDRO-8-FLUORO-4-OXOQUINOLINE-3-CARBOXYLATE 3-(3,4-DIFLUOROPHENYL)-3-OXO-PROPIONIC ACID ETHYL ESTER Ethyl 2,4,5-trifluorobenzoylacetate Ethyl 2,3,4,5-tetrafluorobenzoyl acetate 3-(2,4-DICHLORO-5-FLUORO-PHENYL)-3-OXO-PROPIONIC ACID ETHYL ESTER Ethyl (pentafluorobenzoyl)acetate 3-(2-FLUORO-PHENYL)-3-OXO-PROPIONIC ACID ETHYL ESTER 5,8-DIFLUORO-4-OXO-1,4-DIHYDRO-QUINOLINE-3-CARBOXYLIC ACID ETHYL ESTER 2-(2,4-DICHLORO-5-FLUORO-BENZOYL)-MALONIC ACID DIETHYL ESTER Ethyl 6,7,8-trifluoro-4-oxo-1,4-dihydroquinoline-3-carboxylate (Z)-3-CYCLOPROPYLAMINO-2-(2,4-DICHLORO-5-FLUORO-BENZOYL)-ACRYLIC ACID ETHYL ESTER 7-CHLORO-1-CYCLOPROPYL-6-FLUORO-4-OXO-1,4-DIHYDRO-QUINOLINE-3-CARBOXYLIC ACID ETHYL ESTER 2-CYANO-3-(2-FLUORO-PHENYL)-3-OXO-PROPIONIC ACID ETHYL ESTER AKOS 90576 5,6,7,8-TETRAFLUORO-2-METHYL-4-OXO-4H-CHROMENE-3-CARBOXYLIC ACID ETHYL ESTER AKOS 92524

  • 3-(3-FLUORO-PHENYL)-3-OXO-PROPIONIC ACID ETHYL ESTER
  • ETHYL 3-(3-FLUOROPHENYL)-3-OXOPROPANOATE
  • ETHYL (3-FLUOROBENZOYL)ACETATE
  • (m-Fluorobenzoyl)acetic acid ethyl ester
  • 3-(3-Fluorophenyl)-3-oxopropanoic acid ethyl ester
  • Ethyl 2-3-fluorobenzoylacetate
  • Ethyl 3-fluoro-β-oxobenzenepropanoate
  • Ethyl m-fluorobenzoyl acetate
  • Benzenepropanoic acid, 3-fluoro-β-oxo-, ethyl ester
  • 3-（3-Fluoro-phenyl）-3-oxo-propionic acid ethyl bster
  • Benzenepropanoic acid, 3-fluoro-β-oxo-, ethyl ester
  • 33166-77-7
  • FC6H4COCH2CO2C2H5
  • Esters
  • Organic Building Blocks
  • C10 to C11
  • Carbonyl Compounds
  • Building Blocks
  • C10 to C11
  • Carbonyl Compounds
  • Esters