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4-(Trifluoromethoxy)nitrobenzene

Product Name
4-(Trifluoromethoxy)nitrobenzene
CAS No.
713-65-5
Chemical Name
4-(Trifluoromethoxy)nitrobenzene
Synonyms
1-NITRO-4-(TRIFLUOROMETHOXY)BENZENE;TIMTEC-BB SBB001666;4-nitrotrifluoromethoxybenzene;4-(trifluoromethoxy)nitrobebzene;4-(trifluoromrthoxy)nitrobebzene;4-(TRIFLUOROMETHOXY)NITROBENZENE;4-NITRO-1-TRIFLUOROMETHOXYBENZENE;P-NITRO (TRIFLUOROMETHOXY) BENZENE;4-(Trifluoromethoxy)nitrobenzene98%;4-nitrophenyl trifluoroMethyl ether
CBNumber
CB2229445
Molecular Formula
C7H4F3NO3
Formula Weight
207.11
MOL File
713-65-5.mol
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4-(Trifluoromethoxy)nitrobenzene Property

Melting point:
15°C
Boiling point:
87 °C
Density 
1,447 g/cm3
refractive index 
1.467
Flash point:
87-89°C/15mm
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform (Soluble), Methanol (Sparingly)
form 
clear liquid
color 
Light orange to Yellow to Green
Water Solubility 
Not miscible or difficult to mix in water.
BRN 
1966388
InChI
InChI=1S/C7H4F3NO3/c8-7(9,10)14-6-3-1-5(2-4-6)11(12)13/h1-4H
InChIKey
UBEIKVUMDBCCRW-UHFFFAOYSA-N
SMILES
C1([N+]([O-])=O)=CC=C(OC(F)(F)F)C=C1
CAS DataBase Reference
713-65-5(CAS DataBase Reference)
NIST Chemistry Reference
Alpha,alpha,alpha-trifluoro-4'-nitroanisole(713-65-5)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37-23
HazardClass 
IRRITANT
HS Code 
29093090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical
Product number
T2155
Product name
1-Nitro-4-(trifluoromethoxy)benzene
Purity
>96.0%(GC)
Packaging
5g
Price
$16
Updated
2025/07/31
TCI Chemical
Product number
T2155
Product name
1-Nitro-4-(trifluoromethoxy)benzene
Purity
>96.0%(GC)
Packaging
25g
Price
$44
Updated
2025/07/31
TRC
Product number
N596970
Product name
1-Nitro-4-(trifluoromethoxy)benzene
Packaging
500mg
Price
$75
Updated
2021/12/16
Matrix Scientific
Product number
005371
Product name
4-(Trifluoromethoxy)nitrobenzene
Purity
98%
Packaging
1g
Price
$8
Updated
2021/12/16
Matrix Scientific
Product number
005371
Product name
4-(Trifluoromethoxy)nitrobenzene
Purity
98%
Packaging
5g
Price
$9
Updated
2021/12/16
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4-(Trifluoromethoxy)nitrobenzene Chemical Properties,Usage,Production

Chemical Properties

Light yellow liquid

Uses

1-Nitro-4-(trifluoromethoxy)benzene can be used to manufacture tobacco flavor.

Synthesis Reference(s)

Journal of the American Chemical Society, 109, p. 3708, 1987 DOI: 10.1021/ja00246a030

Synthesis

1394827-04-3

713-65-5

Potassium (4-(trifluoromethoxy)phenyl)trifluoroborate (49.4 mg, 0.25 mmol), bismuth nitrate (121.3 mg, 0.25 mmol), and anhydrous toluene (2.0 mL) were sequentially added to an oven-dried reaction tube fitted with a magnetic stirrer under argon protection. The reaction tube was placed in a microwave reactor and heated at 120 °C for 20 min. After completion of the reaction, the filtrate was filtered through a bed of diatomaceous earth with ethyl acetate (50 mL) and the filtrate was collected. The product solution was analyzed using GC-MS and subsequently concentrated by rotary evaporation and finally purified by preparative thin layer chromatography (TLC). The structure of the product was confirmed by mass spectrometry (MS), hydrogen nuclear magnetic resonance (1H NMR) and carbon nuclear magnetic resonance (13C NMR).

References

[1] Tetrahedron Letters, 2014, vol. 55, # 10, p. 1726 - 1728

4-(Trifluoromethoxy)nitrobenzene Preparation Products And Raw materials

Raw materials

Carbon tetrachloride Hydrogen fluoride

Preparation Products

2-Bromo-4-nitro-1-(trifluoromethoxy)benzene 4-(Trifluoromethoxy)aniline 3-BROMO-4-(TRIFLUOROMETHOXY)PHENOL 3-BROMO-4-(TRIFLUOROMETHOXY)ANILINE
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4-(Trifluoromethoxy)nitrobenzene Suppliers

Belgium 1 China 211 Europe 2 France 2 Germany 4 India 5 Italy 1 Japan 1 Russia 1 Switzerland 1 The Netherlands 2 Ukraine 1 United Kingdom 15 United States 30 Global 277
Interchim SA
Tel
--
Fax
--
Email
him@interchim.com
Country
France
ProdList
2725
Advantage
58
Interchim S.A.
Tel
--
Fax
--
Email
interchim@interchim.com
Country
France
ProdList
6302
Advantage
76
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View Lastest Price from 4-(Trifluoromethoxy)nitrobenzene manufacturers

Shaanxi Dideu New Materials Co. Ltd
Product
4-(Trifluoromethoxy)nitrobenzene 713-65-5
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98
Supply Ability
10000KGS
Release date
2025-11-21
Hebei Chuanghai Biotechnology Co., Ltd
Product
4-(Trifluoromethoxy)nitrobenzene 713-65-5
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2024-11-29
Henan Aochuang Chemical Co.,Ltd.
Product
4-(Trifluoromethoxy)nitrobenzene 713-65-5
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1Ton
Release date
2022-10-08

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