2-Bromo-6-phenylpyridine
- Product Name
- 2-Bromo-6-phenylpyridine
- CAS No.
- 39774-26-0
- Chemical Name
- 2-Bromo-6-phenylpyridine
- Synonyms
- 2-brom-6-phenylpyridin;2-BROMO-6-PHENYLPYRIDINE;6-Bromo-2-phenylpyridine;2-bromine-6-phenypyridine;Pyridine, 2-bromo-6-phenyl-;2-bromo-6-phenylpyridine(SALTDATA: FREE)
- CBNumber
- CB2305480
- Molecular Formula
- C11H8BrN
- Formula Weight
- 234.09
- MOL File
- 39774-26-0.mol
2-Bromo-6-phenylpyridine Property
- Melting point:
- 50.0 to 54.0 °C
- Boiling point:
- 315.1±22.0 °C(Predicted)
- Density
- 1.426±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Inert atmosphere,2-8°C
- pka
- 0.00±0.10(Predicted)
- form
- powder to lump
- color
- White to Yellow
- CAS DataBase Reference
- 39774-26-0(CAS DataBase Reference)
Safety
- HS Code
- 2933399990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
N-Bromosuccinimide Price
- Product number
- B5150
- Product name
- 2-Bromo-6-phenylpyridine
- Purity
- >98.0%(GC)
- Packaging
- 200mg
- Price
- $58
- Updated
- 2025/07/31
- Product number
- B5150
- Product name
- 2-Bromo-6-phenylpyridine
- Purity
- >98.0%(GC)
- Packaging
- 1g
- Price
- $171
- Updated
- 2025/07/31
- Product number
- B698565
- Product name
- 2-Bromo-6-phenylpyridine
- Packaging
- 500mg
- Price
- $155
- Updated
- 2021/12/16
- Product number
- B698565
- Product name
- 2-Bromo-6-phenylpyridine
- Packaging
- 1g
- Price
- $220
- Updated
- 2021/12/16
- Product number
- 114764
- Product name
- 2-Bromo-6-phenylpyridine
- Purity
- 97%
- Packaging
- 1g
- Price
- $291
- Updated
- 2021/12/16
2-Bromo-6-phenylpyridine Chemical Properties,Usage,Production
Synthesis
626-05-1
98-80-6
39774-26-0
General procedure for the synthesis of 2-bromo-6-phenylpyridine from 2,6-dibromopyridine and phenylboronic acid: 2,6-dibromopyridine (2 g, 8.44 mmol), phenylboronic acid (1.03 g, 8.44 mmol), potassium carbonate (4.67 g, 33.77 mmol), and tetrabutylammonium bromide (TBAB, 271 mg, 0.84 mmol) were mixed in a 1 ,4-dioxane (16 ml) and water (4 ml) in a solvent mixture. The reaction mixture was degassed by blowing in nitrogen for 30 min, followed by addition of dichlorobis(triphenylphosphine)palladium(II) (PdCl2(dppf), 62 mg, 0.084 mmol). The reaction mixture was stirred at 40 °C for 1 h. After completion of the reaction, the reaction was filtered through diatomaceous earth. The filtrate was collected and the solvent was removed by distillation under reduced pressure. The crude product was purified by column chromatography using 100% petroleum ether as eluent to afford the target compound 2-bromo-6-phenylpyridine as a colorless solid (1.85 g, 93% yield).1H NMR (400 MHz, DMSO) δ 8.56 (dd, J = 6.3,2.4 Hz, 1H), 8.36-8.18 (m, 2H). 8.16-8.00 (m, 2H), 7.61-7.53 (m, 2H), 7.53-7.45 (m, 1H).
References
[1] Patent: WO2015/172196, 2015, A1. Location in patent: Paragraph 0033; 00179; 00200
[2] Patent: WO2009/111299, 2009, A2. Location in patent: Page/Page column 23
[3] Patent: JP5832992, 2015, B2. Location in patent: Paragraph 0139; 0140
[4] Patent: KR2015/137230, 2015, A. Location in patent: Paragraph 0113; 0114; 0115
[5] Patent: US2004/171614, 2004, A1
2-Bromo-6-phenylpyridine Preparation Products And Raw materials
Raw materials
Preparation Products
2-Bromo-6-phenylpyridine Suppliers
- Tel
- 03-36680489
- Fax
- 03-3668-0520
- Sales-JP@TCIchemicals.com
- Country
- Japan
- ProdList
- 28387
- Advantage
- 80
View Lastest Price from 2-Bromo-6-phenylpyridine manufacturers
- Product
- 2-Bromo-6-phenylpyridine 39774-26-0
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 200kg
- Release date
- 2018-12-20