2-Amino-6-methylbenzoic acid
- Product Name
- 2-Amino-6-methylbenzoic acid
- CAS No.
- 4389-50-8
- Chemical Name
- 2-Amino-6-methylbenzoic acid
- Synonyms
- ZR C1 BVQ;2-Amino-6-methyl;RARECHEM AL BO 2325;6-AMINO-O-TOLUIC ACID;6-Methylanthanilic acid;o-Toluic acid, 6-amino-;6-METHYLANTHRANILIC ACID;6-Methyl-2-aminobenzoic acid;2-Methyl-6-aminobenzoic acid;2-AMINO-6-METHYLBENZOIC ACID
- CBNumber
- CB2487720
- Molecular Formula
- C8H9NO2
- Formula Weight
- 151.16
- MOL File
- 4389-50-8.mol
2-Amino-6-methylbenzoic acid Property
- Melting point:
- 128-130 °C (dec.) (lit.)
- Boiling point:
- 273.17°C (rough estimate)
- Density
- 1.2023 (rough estimate)
- refractive index
- 1.5810 (estimate)
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- solubility
- Soluble in methanol.
- pka
- 1.95±0.31(Predicted)
- form
- powder to crystal
- color
- White to Light yellow to Dark green
- BRN
- 2803391
- InChI
- InChI=1S/C8H9NO2/c1-5-3-2-4-6(9)7(5)8(10)11/h2-4H,9H2,1H3,(H,10,11)
- InChIKey
- XHYVBIXKORFHFM-UHFFFAOYSA-N
- SMILES
- C(O)(=O)C1=C(C)C=CC=C1N
- CAS DataBase Reference
- 4389-50-8(CAS DataBase Reference)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36-24/25
- WGK Germany
- 3
- F
- 10
- Hazard Note
- Irritant
- HS Code
- 29224999
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 230537
- Product name
- 2-Amino-6-methylbenzoic acid
- Purity
- 99%
- Packaging
- 5g
- Price
- $29.45
- Updated
- 2025/07/31
- Product number
- A0996
- Product name
- 2-Amino-6-methylbenzoic Acid
- Purity
- >98.0%(T)
- Packaging
- 5g
- Price
- $61
- Updated
- 2025/07/31
- Product number
- A0996
- Product name
- 2-Amino-6-methylbenzoic Acid
- Purity
- >98.0%(T)
- Packaging
- 25g
- Price
- $202
- Updated
- 2025/07/31
- Product number
- A637853
- Product name
- 2-Amino-6-methylbenzoic Acid
- Packaging
- 2.5g
- Price
- $75
- Updated
- 2021/12/16
- Product number
- OR28634
- Product name
- 2-Amino-6-methylbenzoic Acid
- Purity
- 97%
- Packaging
- 5g
- Price
- $27
- Updated
- 2021/12/16
2-Amino-6-methylbenzoic acid Chemical Properties,Usage,Production
Chemical Properties
Beige to pink powder
Uses
2-Amino-6-methylbenzoic acid reacts with cyanogen bromide to prepare 2-amino-5-methyl-benzo[d][1,3]oxazin-4-one.
reaction suitability
reaction type: solution phase peptide synthesis
Synthesis
13506-76-8
4389-50-8
General procedure for the synthesis of 2-amino-6-methylbenzoic acid from 2-methyl-6-nitrobenzoic acid: Pd/C catalyst (150 mg) was added to a methanol (35 mL) solution of 2-methyl-6-nitrobenzoic acid (1.5 g, 8.29 mmol). The reaction mixture was stirred for 2 hours at room temperature under hydrogen atmosphere. Upon completion of the reaction, the mixture was filtered to remove the catalyst and the filtrate was subsequently concentrated to give 2-amino-6-methylbenzoic acid (1.2 g) in yellow solid form. The product was characterized by liquid chromatography-mass spectrometry (LCMS, ESI mode): the calculated value of C8H9NO2 [M+H]+ was 152 and the measured value was 152, as expected.
References
[1] Patent: US5753664, 1998, A
[2] Tetrahedron Letters, 1984, vol. 25, # 8, p. 839 - 842
[3] Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1982, # 8, p. 1637 - 1648
[4] Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1982, # 8, p. 1701 - 1714
[5] Journal fuer Praktische Chemie (Leipzig), 1985, vol. 327, # 5, p. 865 - 867
2-Amino-6-methylbenzoic acid Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2-Amino-6-methylbenzoic acid manufacturers
- Product
- 2-Amino-6-methylbenzoic acid 4389-50-8
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98%min
- Supply Ability
- 30tons/month
- Release date
- 2023-02-24
- Product
- 2-Amino-6-methylbenzoic acid 4389-50-8
- Price
- US $10.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20 ton
- Release date
- 2024-11-18
- Product
- 2-Amino-6-methylbenzoic acid 4389-50-8
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 500000kg
- Release date
- 2024-10-30