ChemicalBook > CAS DataBase List > Fmoc-Orn(Boc)-OH

Fmoc-Orn(Boc)-OH

Product Name
Fmoc-Orn(Boc)-OH
CAS No.
109425-55-0
Chemical Name
Fmoc-Orn(Boc)-OH
Synonyms
FMOC-ORN(BOC)-OH;FMOC-ORN(BOC);FMOC-L-ORN(BOC);FMOC-L-ORN(BOC)-OH;(S)-2-((((9H-fluoren-9-yl)Methoxy)carbonyl)aMino)-5-((tert-butoxycarbonyl)aMino)pentanoic acid;Ndelta L;FMOC-ORN(BOT)-OH;RARECHEM EM WB 0176;FMOC-L-ORN(TBOC)-OH;FMoc-Ornithine(Boc)
CBNumber
CB2489395
Molecular Formula
C25H30N2O6
Formula Weight
454.52
MOL File
109425-55-0.mol
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Fmoc-Orn(Boc)-OH Property

Melting point:
111-115℃
Boiling point:
679.0±55.0 °C(Predicted)
Density 
1.226±0.06 g/cm3(Predicted)
storage temp. 
2-8°C
solubility 
soluble in Methanol
form 
powder to crystal
pka
3.85±0.21(Predicted)
color 
White to Almost white
BRN 
4772025
InChIKey
JOOIZTMAHNLNHE-NRFANRHFSA-N
SMILES
C(O)(=O)[C@H](CCCNC(OC(C)(C)C)=O)NC(OCC1C2=C(C=CC=C2)C2=C1C=CC=C2)=O
CAS DataBase Reference
109425-55-0(CAS DataBase Reference)
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Safety

Safety Statements 
22-24/25
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
29242990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.52015
Product name
Fmoc-Orn(Boc)-OH
Purity
Novabiochem?
Packaging
5G
Price
$107
Updated
2024/03/01
Sigma-Aldrich
Product number
8.52015
Product name
Fmoc-Orn(Boc)-OH
Purity
Novabiochem?
Packaging
25G
Price
$407
Updated
2024/03/01
Sigma-Aldrich
Product number
47560
Product name
Fmoc-Orn(Boc)-OH
Purity
≥96.0% (HPLC)
Packaging
5G
Price
$209
Updated
2024/03/01
TCI Chemical
Product number
B4184
Product name
Nδ-(tert-Butoxycarbonyl)-Nα-[(9H-fluoren-9-ylmethoxy)carbonyl]-L-ornithine
Purity
>98.0%(HPLC)(T)
Packaging
5g
Price
$80
Updated
2024/03/01
Alfa Aesar
Product number
H62814
Product name
Ndelta-Boc-Nalpha-Fmoc-L-ornithine, 96%
Packaging
5g
Price
$101
Updated
2024/03/01
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Fmoc-Orn(Boc)-OH Chemical Properties,Usage,Production

Description

Fmoc-Orn(Boc)-OH is an ornithine-containing amino acid building block. It has been used to conjugate ornithine to GFP-labeled peptides, enhancing cell permeability when compared to unconjugated GFP-labeled peptides. This compound is useful in preparing cyclic peptides and special arginine derivates.

Chemical Properties

White powder

Uses

Fmoc-Orn(Boc)-OH is a biochemical reagent. It can be used as a biomaterial or organic compound in life science-related research.

Preparation

2 mmol L-Orn was weighted and dissolved in 15 ml of acetonitrile; 16 mmol Boc2O was dissolved in acetonitrile and added dropwise to an acetonitrile solution of ornithine, to react and generate a complex; 10 ml 20% sodium bicarbonate aqueous solution was added, and 2 g of anhydrous sodium carbonate and an appropriate amount of 8-hydroxyquinoline were added in batches; the mixture was stirred and reacted at room temperature for 4 hours to remove copper ions in the complex; then 2 mmol Fmoc-OSu was added to the aforesaid solution, followed by stirring at room temperature for 2 hours; the resultant was recrystallized with an ethyl acetate/petroleum ether mixed solvent, to obtain a peptide head intermediate Fmoc-Orn(Boc)-OH.

reaction suitability

Reaction type: Fmoc solid-phase peptide synthesis

Solubility in organics

DMF: 20 mg/ml, DMF:PBS (pH 7.2) (1:5): 0.16 mg/ml, DMSO: 10 mg/ml, Ethanol: 10 mg/ml

Fmoc-Orn(Boc)-OH Preparation Products And Raw materials

Raw materials

Preparation Products

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Fmoc-Orn(Boc)-OH Suppliers

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View Lastest Price from Fmoc-Orn(Boc)-OH manufacturers

Sichuan HongRi Pharma-Tech Co.,Ltd
Product
Fmoc-L-Orn(Boc)-OH 109425-55-0
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1T+
Release date
2023-09-27
Career Henan Chemical Co
Product
Nalpha-Fmoc-Ndelta-Boc-L-ornithine 109425-55-0
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20kg
Release date
2018-08-15

109425-55-0, Fmoc-Orn(Boc)-OHRelated Search:

Nalpha-Fmoc-Ndelta-trityl-L-glutamine Fmoc-Lys(Boc)-OH N-(tert-Butoxycarbonyl)-L-alanine 9-Fluorenylmethyl chloroformate Fmoc-O-trityl-L-serine Boc-Aib-OH L-Fmoc-Aspartic acid alpha-tert-butyl ester N-(9-Fluorenylmethoxycarbonyloxy)succinimide L(+)-Ornithine hydrochloride L-Ornithine Fmoc-Asp(OtBu)-OH Fmoc-Phe-OH N-Boc-N'-nitro-L-arginine 1,1'-Carbonyldiimidazole Fmoc-OrnMe(Alloc)-OH FMOC-ORN(ALOC)-OH FMOC-ORN(BOC)-OPFP Fmoc

  • N(α)-fmoc-N(delta)-boc-L-ornithine
  • N-DELTA-BOC-N-ALPHA-FMOC-L-ORNITHINE
  • RARECHEM EM WB 0176
  • N-ALPHA-(9-FLUORENYLMETHYLOXYCARBONYL)-N-GAMMA-T-BUTYL-OXYCARBONYL-L-ORNITHINE
  • N-ALPHA-(9-FLUORENYLMETHYLOXYCARBONYL)-N-DELTA-TERT-BUTYLOXYCARBONYL-L-ORNITHINE
  • N-ALPHA-(9-FLUORENYLMETHOXYCARBONYL)-N-DELTA-T-BUTOXYCARBONYL-L-ORNITHINE
  • N-ALPHA-FMOC-N-DELTA-BOC-L-ORNITHINE
  • N-ALPHA-FMOC-N-DELTA-T-BOC-L-ORNITHINE
  • N-ALPHA-FMOC-N-DELTA-T-BUTYLOXYCARBONYL-L-ORNITHINE
  • N-ALPHA-FMOC-N-DELTA-TERT-BOC-L-ORNITHINE
  • (2S)-2-(9H-Fluoren-9-ylmethoxycarbonylamino)-5-[(2-methylpropan-2-yl)oxycarbonylamino]pentanoic acid
  • FMOC-L-ORN(BOC)-OH
  • FMOC-L-ORN(TBOC)-OH
  • FMOC-L-ORN(BOC)
  • FMOC-(N-DELTA-BOC)-L-ORNITHINE
  • FMOC-N-BOC-L-ORNITHINE
  • FMOC-ORN(BOC)-OH
  • FMOC-ORNITHINE(BOC)-OH
  • N-tert-Butoxycarbonyl-N-9-fluorenylmethoxycarbonyl-L-ornithine
  • N-α-Boc-N-δ-Boc-L-ornithine
  • FMOC-ORN(BOC)-OH 98+%
  • nα-fmoc-nδ-boc-l-ornithine
  • FMOC-ORN(BOC)
  • FMOC-ORN(BOT)-OH
  • Fmoc-Orn(Boc)-OH [109425-55-0]
  • (2S)-5-{[(tert-butoxy)carbonyl]amino}-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)pentanoic acid
  • NEPSILON-tert-Butoxycarbonyl-NALPHA-9-fluorenylmethoxycarbonyl-L-ornithine
  • L-ORNITHINE, N5-[(1,1-DIMETHYLETHOXY)CARBONYL]-N2-[(9H-FLUOREN-9-YLMETHOXY)CARBONYL]-
  • FMoc-Orn(Boc)-OH N-α-Boc-N-δ-Boc-L-ornithine
  • Nδ-Boc-Nα-Fmoc-L-ornithine, Nα-Fmoc-Nδ-Boc-L-ornithine
  • N-ALPHA-FMOC-N-GAMMA-BOC-L-ORNITHINE
  • Nalpha-Fmoc-Ndelta-B
  • N-DELTA-Boc-N-ALFA-Fmoc-L-ornithine
  • Na-Fmoc-Nγ-Boc-L-ornithine ,98%
  • n-delta-boc-n--fmoc-l-ornithine
  • Fmoc-(Nd-Boc)-L-ornithine
  • (S)-2-((((9H-fluoren-9-yl)Methoxy)carbonyl)aMino)-5-((tert-butoxycarbonyl)aMino)pentanoic acid
  • N^d-Boc-N^a-FMoc-L-ornithine, 96%
  • FMoc-Ornithine(Boc)
  • Ndelta-(tert-Butoxycarbonyl)-Nalpha-[(9H-fluoren-9-ylmethoxy)carbonyl]-L-ornithine
  • Fmoc-Orn(Boc)-OH >=96.0% (HPLC)
  • Nδ-(tert-Butoxycarbonyl)-Nα-[(9H-fluoren-9-ylmethoxy)carbonyl]-L-ornithine
  • Nα-Fmoc-Nδ-Boc-L-ornithine≥ 99.5% (HPLC, Chiral purity)
  • (9H-Fluoren-9-yl)MethOxy]Carbonyl Orn(Boc)-OH
  • Nδ-(tert-Butoxycarbonyl)-Nα-[(9H-fluoren-9-ylmethoxy)carbonyl]-L-ornithine &gt
  • Ndelta L
  • (2S)-2-(9H-fluoren-9-ylmethoxycarbonylamino)-5-[(2-methylpropan-2-yl)oxycarbonylamino]pentanoicaci
  • Nalpha-Fmoc-Ndelta-Boc-L-ornithine USP/EP/BP
  • N5-Boc-N2-Fmoc-L-ornithine
  • Nδ-(tert-Butoxycarbonyl)-Nα-[(9H-fluoren-9-ylmethoxy)carbonyl]-L-ornithine
  • Nα-Fmoc-Nδ-Boc-L-ornithine
  • N-α-Boc-N-δ-Boc-L-ornithine
  • Fmoc-Orn(Boc)-OH,96%
  • 109425-55-0
  • Ornithine
  • Peptide Synthesis
  • Specialty Synthesis
  • Unnatural Amino Acid Derivatives