Tris(3-methoxyphenyl)phosphine

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Tris(3-methoxyphenyl)phosphine

Product Name: Tris(3-methoxyphenyl)phosphine
CAS No.: 29949-84-6
Chemical Name: Tris(3-methoxyphenyl)phosphine
Synonyms: Tris(3-methoxyphenyl);tri(m-anisyl)phosphine;TRIS(M-ANISYL)PHOSPHINE;TRIS(3-METHOXYPHENYL)PHOSP;ris(3-methoxyphenyl)phosphane;tris(3-Methoxyphenyl)phosphane;TRIS(M-METHOXYPHENYL)PHOSPHINE;TRIS(3-METHOXYPHENYL)PHOSPHINE;Phosphine,tris(3-methoxyphenyl)-;Phosphine,tris(3-METHOXYBENZYL)-
CBNumber: CB2490360
Molecular Formula: C21H21O3P
Formula Weight: 352.36
MOL File: 29949-84-6.mol

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Tris(3-methoxyphenyl)phosphine Property

Melting point:: 113-115 °C(lit.)
Boiling point:: 476.3±40.0 °C(Predicted)
storage temp.: Inert atmosphere,Room Temperature
form: Crystalline Powder
color: White to almost white
InChI: InChI=1S/C21H21O3P/c1-22-16-7-4-10-19(13-16)25(20-11-5-8-17(14-20)23-2)21-12-6-9-18(15-21)24-3/h4-15H,1-3H3
InChIKey: CCXTYQMZVYIQRP-UHFFFAOYSA-N
SMILES: P(C1=CC=CC(OC)=C1)(C1=CC=CC(OC)=C1)C1=CC=CC(OC)=C1
CAS DataBase Reference: 29949-84-6(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-37/39
WGK Germany: 3
TSCA: No
HS Code: 29310099

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical

Product number: T2946
Product name: Tris(3-methoxyphenyl)phosphine
Packaging: 5G
Price: $69
Updated: 2024/03/01

TCI Chemical

Product number: T2946
Product name: Tris(3-methoxyphenyl)phosphine
Packaging: 25G
Price: $206
Updated: 2024/03/01

Alfa Aesar

Product number: A17949
Product name: Tris(3-methoxyphenyl)phosphine
Purity: 98%
Packaging: 1g
Price: $66.65
Updated: 2024/03/01

Alfa Aesar

Product number: A17949
Product name: Tris(3-methoxyphenyl)phosphine
Purity: 98%
Packaging: 5g
Price: $262.65
Updated: 2024/03/01

Strem Chemicals

Product number: 15-7975
Product name: Tris(m-methoxyphenyl)phosphine, 97+%
Packaging: 1g
Price: $103
Updated: 2024/03/01

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Tris(3-methoxyphenyl)phosphine Chemical Properties,Usage,Production

Chemical Properties

White to almost white crystalline powder

Uses

suzuki reaction

Synthesis

1-iodo-3-methoxybenzene could be used to synthesize Tri(o-anisole)phosphine (Tris(3-methoxyphenyl)phosphine). Reactions performed using 0.1?mmol NaPH2, 2?mol?% PF6, 11?equiv 1-iodo-3-methoxybenzene, 15?equiv Et3N in 2.0?mL MeCN under blue LED irradiation and N2 atmosphere for 24?h[1].

References

[1]"Photocatalytic Arylation of P4 and PH3: Reaction Development Through Mechanistic Insight." Angewandte Chemie (2021).

Tris(3-methoxyphenyl)phosphine Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Tris(3-methoxyphenyl)phosphine manufacturers

Hebei Chuanghai Biotechnology Co., Ltd

Product: TRIS(3-METHOXYPHENYL)PHOSPHINE 29949-84-6
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 mt
Release date: 2024-11-22

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Tris(3-Methoxyphenyl)Phosphine 29949-84-6
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-01-17

Shaanxi Dideu Medichem Co. Ltd

Product: Tris(3-Methoxyphenyl)phosphine 29949-84-6
Price: US $1.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 Tons
Release date: 2020-01-14

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